Chemical Vapor Deposition Synthesis of Ultrathin Hexagonal ReSe2 Flakes for Anisotropic Raman Property and Optoelectronic Application.

Hexagonal crystalline ultrathin ReSe2 flakes are synthesized for the first time by a chemical vapor deposition (CVD) method. The as-synthesized ReSe2 flake is revealed as a novel structure, which has mirror-symmetric single-crystal domains inside, by polarization incident Raman and HRTEM. The successful development of the CVD method will facilitate research on the novel anisotropic electronic/optoelectronic properties of ReSe2 in the future.