| Literature DB >> 27328914 |
Ke-Yin Ye1, Gerald Kehr1, Constantin G Daniliuc1, Lei Liu2, Stefan Grimme2, Gerhard Erker3.
Abstract
Coupling of carbon monoxide with nitrogen monoxide was achieved at a frustrated Lewis pair template. This unique reaction uses hydride as an auxiliary, which reductively activates carbon monoxide at the frustrated Lewis pair. The CO/NO coupling reaction then takes place through a pathway involving a radical reaction in which the hydrogen atom auxiliary is eventually removed again.Entities:
Keywords: boron; carbon monoxide; frustrated Lewis pairs; nitric oxide; phosphorus
Year: 2016 PMID： 27328914 DOI： 10.1002/anie.201603760
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336