| Literature DB >> 27181497 |
Yuanyuan Zhou1, Joonsuh Kwun, Hector F Garces, Shuping Pang, Nitin P Padture.
Abstract
The α→δ phase transition, which occurs favorably in planar films of a black α-HC(NH2)2PbI3 (α-FAPbI3) perovskite in the amibent, is retarded when α-FAPbI3 is deposited upon mesoporous TiO2 scaffolds. It is hypothesized that this is due to the synergistic effect of the partial encapsulation of α-FAPbI3 by the mesoporous TiO2 and the elevated activation energy for the transition reaction associated with the substantial increase of the TiO2/α-FAPbI3 interfacial area in the mesoscopic system.Entities:
Year: 2016 PMID: 27181497 DOI: 10.1039/c6cc02086k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222