Literature DB >> 27172371

High Conductivity in Molecularly p-Doped Diketopyrrolopyrrole-Based Polymer: The Impact of a High Dopant Strength and Good Structural Order.

Yevhen Karpov1, Tim Erdmann1,2, Ivan Raguzin1, Mahmoud Al-Hussein3, Marcus Binner1, Uwe Lappan1, Manfred Stamm1,2, Kirill L Gerasimov4, Tetyana Beryozkina5, Vasiliy Bakulev5, Denis V Anokhin4,6, Dimitri A Ivanov4,7, Florian Günther2,8, Sibylle Gemming2,8, Gotthard Seifert2,9, Brigitte Voit1,2, Riccardo Di Pietro10, Anton Kiriy1,2.   

Abstract

[3]-Radialene-based dopant CN6-CP studied herein, with its reduction potential of +0.8 versus Fc/Fc+ and the lowest unoccupied molecular orbital level of -5.87 eV, is the strongest molecular p-dopant reported in the open literature, so far. The efficient p-doping of the donor-acceptor dithienyl-diketopyrrolopyrrole-based copolymer having the highest unoccupied molecular orbital level of -5.49 eV is achieved. The doped films exhibit electrical conductivities up to 70 S cm(-1) .
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  conjugated polymers; electrical conductivity; organic electronics p-dopant

Year:  2016        PMID: 27172371     DOI: 10.1002/adma.201506295

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  5 in total

1.  Controlling n-Type Molecular Doping via Regiochemistry and Polarity of Pendant Groups on Low Band Gap Donor-Acceptor Copolymers.

Authors:  Gang Ye; Jian Liu; Xinkai Qiu; Sebastian Stäter; Li Qiu; Yuru Liu; Xuwen Yang; Richard Hildner; L Jan Anton Koster; Ryan C Chiechi
Journal:  Macromolecules       Date:  2021-04-08       Impact factor: 5.985

2.  Elementary steps in electrical doping of organic semiconductors.

Authors:  Max L Tietze; Johannes Benduhn; Paul Pahner; Bernhard Nell; Martin Schwarze; Hans Kleemann; Markus Krammer; Karin Zojer; Koen Vandewal; Karl Leo
Journal:  Nat Commun       Date:  2018-03-21       Impact factor: 14.919

3.  Strong and Atmospherically Stable Dicationic Oxidative Dopant.

Authors:  Tadanori Kurosawa; Toshihiro Okamoto; Yu Yamashita; Shohei Kumagai; Shun Watanabe; Jun Takeya
Journal:  Adv Sci (Weinh)       Date:  2021-10-28       Impact factor: 16.806

4.  Optimization of the thermoelectric performance of layer-by-layer structured copper-phthalocyanine (CuPc) thin films doped with hexacyano-trimethylene-cyclopropane (CN6-CP).

Authors:  Weilong Xing; Jie Chen; Yingying Liang; Ye Zou; Yimeng Sun; Wei Xu; Daoben Zhu
Journal:  RSC Adv       Date:  2019-10-07       Impact factor: 3.361

5.  MOF-derived (MoS2, γ-Fe2O3)/graphene Z-scheme photocatalysts with excellent activity for oxygen evolution under visible light irradiation.

Authors:  Ang Li; Yuxiang Liu; Xuejun Xu; Yuanyuan Zhang; Zhichun Si; Xiaodong Wu; Rui Ran; Duan Weng
Journal:  RSC Adv       Date:  2020-05-01       Impact factor: 4.036

  5 in total

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