Literature DB >> 27095021

Manganese(I)-Catalyzed Substitutive C-H Allylation.

Weiping Liu1, Sven C Richter1, Yujiao Zhang1, Lutz Ackermann2.   

Abstract

The first manganese(I)-catalyzed C-H allylations with ample scope were achieved by carboxylate assistance. The highly selective C-H/C-O functionalizations proved viable with densely substituted allyl carbonates, and the organometallic C-H allylation strategy set the stage for expedient late-stage diversification with excellent levels of positional selectivity.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; electrophiles; heteroarenes; manganese; reaction mechanisms

Year:  2016        PMID： 27095021     DOI： 10.1002/anie.201601560

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  15 in total

1.  Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation.

Authors:  Sarah Yunmi Lee; John F Hartwig
Journal:  J Am Chem Soc       Date:  2016-11-14       Impact factor: 15.419

2.  Rhodium(iii)-catalyzed C-H allylation of indoles with allyl alcohols via β-hydroxide elimination.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  Org Biomol Chem       Date:  2018-08-08       Impact factor: 3.876

3.  Direct Assembly of Prenylated Heteroarenes through a Cascade Minisci Reaction/Dehydration Sequence.

Authors:  Dong-Hang Tan; Yao-Fu Zeng; Yao Liu; Wen-Xin Lv; Qingjiang Li; Honggen Wang
Journal:  ChemistryOpen       Date:  2016-10-11       Impact factor: 2.911

4.  Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors:  Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

5.  Dual vicinal functionalisation of heterocycles via an interrupted Pummerer coupling/[3,3]-sigmatropic rearrangement cascade.

Authors:  Mindaugas Šiaučiulis; Selma Sapmaz; Alexander P Pulis; David J Procter
Journal:  Chem Sci       Date:  2017-11-17       Impact factor: 9.825

Review 6.  C4-H indole functionalisation: precedent and prospects.

Authors:  Jagadeesh Kalepu; Parthasarathy Gandeepan; Lutz Ackermann; Lukasz T Pilarski
Journal:  Chem Sci       Date:  2018-04-20       Impact factor: 9.825

7.  Manganese(I)-Catalyzed C-H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination.

Authors:  Nasiru P Yahaya; Kate M Appleby; Magdalene Teh; Conrad Wagner; Erik Troschke; Joshua T W Bray; Simon B Duckett; L Anders Hammarback; Jonathan S Ward; Jessica Milani; Natalie E Pridmore; Adrian C Whitwood; Jason M Lynam; Ian J S Fairlamb
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-07       Impact factor: 15.336

8.  Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.

Authors:  Soham Maity; Pravas Dolui; Rajesh Kancherla; Debabrata Maiti
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825

9.  Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Mattes Holsten; Kathrin Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-06-12       Impact factor: 9.825

10.  Aromatic C-H addition of ketones to imines enabled by manganese catalysis.

Authors:  Bingwei Zhou; Yuanyuan Hu; Ting Liu; Congyang Wang
Journal:  Nat Commun       Date:  2017-10-27       Impact factor: 14.919
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.