| Literature DB >> 27049637 |
Walther Caminati1, Luca Evangelisti, Gang Feng, Barbara M Giuliano, Qian Gou, Sonia Melandri, Jens-Uwe Grabow.
Abstract
The rotational spectra of two isotopologues (CF3(35)Cl-CO and CF3(37)Cl-CO) of the CF3Cl-CO adduct have been investigated and analyzed using supersonic-jet Fourier transform microwave spectroscopy, and found to have the features of a symmetric top. Rotational, centrifugal distortion, and nuclear quadrupole ((35)Cl and (37)Cl) coupling constants have been precisely obtained from high-resolution measurements. The two subunits of the complex are held together via a ClC halogen bond interaction. Information on the internal dynamics and the dissociation energy of the complex is provided.Entities:
Year: 2016 PMID： 27049637 DOI： 10.1039/c6cp01059h
Source DB: PubMed Journal: Phys Chem Chem Phys ISSN： 1463-9076 Impact factor: 3.676