High-Yield Production of Boron Nitride Nanosheets and Its Uses as a Catalyst Support for Hydrogenation of Nitroaromatics.

Single- or few-layered h-BN nanosheets (BNNSs) are analogous to graphene and possess unique properties. However, their technological applications were severely hindered by the low production efficiency of BNNSs. We reported here a study in which BNNSs were efficiently produced by exfoliating bulk h-BN powder in thionyl chloride without using any dispersion agents. The BNNSs yield was as high as 20%, and it could be doubled through the second round of exfoliation of the h-BN precipitate. Microscopic results revealed that the BNNSs generally consisted of 3-20 layers. Pd nanoparticles were successfully immobilized and uniformly distributed on BNNS surfaces through the deposition-precipitation method. The resultant Pd-BNNS catalyst exhibited high catalytic activity and recyclability for the hydrogenation of nitro aromatics, demonstrating that BNNSs served as a promising platform to fabricate heterogeneous catalysts.