Literature DB >> 27015356

Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes.

Daria Kurandina1, Vladimir Gevorgyan1.   

Abstract

The rhodium-catalyzed transannulation reaction between 1,2,3-thiadiazoles and alkynes, proceeding via intermediacy of the previously unknown Rh thiavinyl carbene, toward a highly efficient and regioselective synthesis of up to fully substituted thiophenes is described.

Entities:  

Year:  2016        PMID: 27015356     DOI: 10.1021/acs.orglett.6b00541

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.

Authors:  Kuiyong Dong; Mengting Liu; Xinfang Xu
Journal:  Molecules       Date:  2022-05-11       Impact factor: 4.927

Review 2.  Recent strategies in the synthesis of thiophene derivatives: highlights from the 2012-2020 literature.

Authors:  Fahimeh Abedinifar; Elham Babazadeh Rezaei; Mahmood Biglar; Bagher Larijani; Halleh Hamedifar; Samira Ansari; Mohammad Mahdavi
Journal:  Mol Divers       Date:  2020-07-30       Impact factor: 2.943

  2 in total

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