Literature DB >> 26898532

Beyond ketonization: selective conversion of carboxylic acids to olefins over balanced Lewis acid-base pairs.

Rebecca A L Baylon1, Junming Sun1, Kevin J Martin2, Padmesh Venkitasubramanian2, Yong Wang3.   

Abstract

We report the direct conversion of mixed carboxylic acids to C-C olefins with up to 60 mol% carbon yield through cascade (cross) ketonization, (cross) aldolization and self-deoxygenation reactions. Co-feeding hydrogen provides an additional ketone hydrogenation/dehydration pathway to a wider range of olefins.

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Year:  2016        PMID: 26898532     DOI: 10.1039/c5cc10528e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Anchoring Effect of Organosilanes on Hierarchical ZSM-5 Zeolite for Catalytic Fast Pyrolysis of Cellulose to Aromatics.

Authors:  Huan Zhou; Wenwen Lin; Chao Chen; Chuang Liu; Jianghua Wu; Jianghao Wang; Jie Fu
Journal:  ACS Omega       Date:  2022-04-25

2.  Acetic Acid Ketonization over Fe3O4/SiO2 for Pyrolysis Bio-Oil Upgrading.

Authors:  James A Bennett; Christopher M A Parlett; Mark A Isaacs; Lee J Durndell; Luca Olivi; Adam F Lee; Karen Wilson
Journal:  ChemCatChem       Date:  2017-01-18       Impact factor: 5.686

  2 in total

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