| Literature DB >> 26870532 |
B R Anitha1, A Thomas Gunaseelan2, M Vinduvahini3, H D Kavitha4, H C Devarajegowda1.
Abstract
In the title compound, C15H14FNO3S2, the 2H-chromene ring system is close to being planar (r.m.s. deviation = 0.024 Å) and the morpholine ring adopts a chair conformation. The dihedral angle between the 2H-chromene ring system and the morpholine ring (all atoms) is 88.21 (11)°. In the crystal, inversion dimers linked by pairs of very weak C-H⋯F hydrogen bonds generate R 2 (2)(8) loops; C-H⋯O hydrogen bonds connect the dimers into [010] chains. Weak aromatic π-π stacking inter-actions between the pyran rings of the chromene systems [centroid-centroid distance = 3.6940 (16) Å] are also observed.Entities:
Keywords: 2H-chromene; coumarin; crystal structure; ester; hydrogen bonding; morpholine-4-carbodithioate
Year: 2015 PMID: 26870532 PMCID: PMC4719885 DOI: 10.1107/S2056989015021179
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun