Crystal structure of [1-(3-eth-oxy-2-oxido-benzyl-idene-κO (2))-4-phenyl-thio-semicarbazidato-κ(2) N (1),S](tri-phenylphosphane-κP)nickel(II).

In the title complex, [Ni(C16H15N3O2S)(C18H15P)], the Ni(II) atom has a distorted tetra-hedral coordination geometry, comprised of N, S, O and P atoms of the tridentate thiosemicarbazide ligand and the P atom of the triphenylphosphane ligand. The benzene ring makes a dihedral angle of 53.08 (11)° with the phenyl ring of the phenyl-thio-semicarbazide moiety and dihedral angles of 73.69 (11), 20.38 (11) and 71.30 (11)° with the phenyl rings of tri-phenyl-phosphane ligand. A pair of N-H⋯N hydrogen bonds generates an R 2 (2)(8) ring graph-set motif. The eth-oxy group is disordered over two positions, with site occupancies of 0.631 (9) and 0.369 (9). The mol-ecular structure is stabilized by a weak intra-molecular C-H⋯O hydrogen bond. In the crystal, weak N-H⋯N and C-H⋯π inter-actions connect the mol-ecules, forming a three-dimensional network.

Related literature

For biological activities of thio­semicarbazones and their transition pan class="Chemical">metal compn>lexes, see: Hu et al. (2006 ▸); Banerjee et al. (2011 ▸); pan class="Chemical">Pitucha et al. (2010 ▸). For reported similar structures, see: Islam et al. (2014 ▸); Zhang et al. (2004 ▸).

Experimental

Crystal data

[pan class="Chemical">Ni(C16H15N3O2S)(pan class="Chemical">C18H15P)]

M = 634.35

Triclinic,

a = 9.7290 (2) Å

b = 12.9770 (3) Å

c = 14.0120 (2) Å

α = 62.958 (1)°

β = 73.756 (2)°

γ = 71.654 (1)°

V = 1475.91 (5) Å3

Z = 2

Mo Kα radiation

μ = 0.82 mm−1

T = 295 K

0.28 × 0.24 × 0.20 mm

Data collection

Bruker Kappa Apan class="Chemical">PEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▸) T min = 0.803, T max = 0.853

32169 measured reflections

7289 independent reflections

6002 reflections with I > 2σ(I)

R int = 0.030

Refinement

R[F 2 > 2σ(F 2)] = 0.030

wR(F 2) = 0.081

S = 1.03

7289 reflections

411 parameters

7 restraints

pan class="Disease">H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.30 e Å−3

Δρmin = −0.25 e Å−3

Data collection: APEX2 (Bruker, 2004 ▸); cell refinement: SAINT (Bruker, 2004 ▸); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▸); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▸); molecular grapn>hics: PLATON (Spek, 2009 ▸); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S2056989015021660/ff2143sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015021660/ff2143Isup2.hkl

Click here for additional data file.

. DOI: 10.1107/S2056989015021660/ff2143fig1.tif

The mol­ecular structure of (I), with atom labels and 30% probability displacement ellipsoids for non-pan class="Disease">H atoms.

Click here for additional data file.

a . DOI: 10.1107/S2056989015021660/ff2143fig2.tif

The crystal packing of the title compound, viewed along the a axis. The pan class="Chemical">hydrogen bonds are shown as dashed lines (see Table 1). pan class="Disease">H atoms not involved in these inter­actions have been omitted for clarity.

Click here for additional data file.

b . DOI: 10.1107/S2056989015021660/ff2143fig3.tif

The partial crystal packing of the title compound, showing the ring set-motif viewed along the b axis. The pan class="Chemical">hydrogen bonds are shown as dashed lines.

CCDC reference: 964626

Additional supporting information: crystallographic information; 3D view; checkCIF report

[Ni(C16H15N3O2S)(C18H15P)]	Z = 2
Mr = 634.35	F(000) = 660
Triclinic, P1	Dx = 1.427 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.7290 (2) Å	Cell parameters from 2018 reflections
b = 12.9770 (3) Å	θ = 2.2–28.3°
c = 14.0120 (2) Å	µ = 0.82 mm−1
α = 62.958 (1)°	T = 295 K
β = 73.756 (2)°	Block, red
γ = 71.654 (1)°	0.28 × 0.24 × 0.20 mm
V = 1475.91 (5) Å3

Bruker Kappa APEXII CCD diffractometer	7289 independent reflections
Radiation source: fine-focus sealed tube	6002 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.030
ω and φ scan	θmax = 28.3°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −12→12
Tmin = 0.803, Tmax = 0.853	k = −17→17
32169 measured reflections	l = −18→18

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.081	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ2(Fo2) + (0.0392P)2 + 0.3532P] where P = (Fo2 + 2Fc2)/3
7289 reflections	(Δ/σ)max < 0.001
411 parameters	Δρmax = 0.30 e Å−3
7 restraints	Δρmin = −0.25 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.75160 (16)	0.24179 (14)	−0.08641 (12)	0.0334 (3)
C2	0.75713 (19)	0.35814 (16)	−0.15930 (14)	0.0447 (4)
H2	0.7284	0.4181	−0.1342	0.054*
C3	0.8053 (2)	0.38465 (19)	−0.26897 (15)	0.0558 (5)
H3	0.8074	0.4626	−0.3174	0.067*
C4	0.8499 (2)	0.2962 (2)	−0.30648 (15)	0.0571 (5)
H4	0.8817	0.3143	−0.3802	0.068*
C5	0.8475 (2)	0.18102 (19)	−0.23501 (15)	0.0517 (5)
H5	0.8792	0.1211	−0.2604	0.062*
C6	0.79814 (18)	0.15360 (15)	−0.12535 (13)	0.0400 (4)
H6	0.7962	0.0754	−0.0775	0.048*
C7	0.85493 (17)	0.19942 (14)	0.10147 (13)	0.0356 (3)
C8	0.98860 (19)	0.20072 (18)	0.03254 (15)	0.0494 (4)
H8	0.9925	0.2149	−0.0394	0.059*
C9	1.1160 (2)	0.18122 (19)	0.06923 (18)	0.0564 (5)
H9	1.2049	0.1821	0.0221	0.068*
C10	1.1116 (2)	0.16066 (18)	0.17405 (18)	0.0556 (5)
H10	1.1977	0.1462	0.1991	0.067*
C11	0.9801 (2)	0.1613 (2)	0.24270 (19)	0.0672 (6)
H11	0.9772	0.1484	0.3141	0.081*
C12	0.8509 (2)	0.1808 (2)	0.20701 (16)	0.0551 (5)
H12	0.7620	0.1813	0.2542	0.066*
C13	0.66787 (17)	0.05795 (14)	0.11644 (12)	0.0343 (3)
C14	0.77810 (19)	−0.03890 (15)	0.15956 (14)	0.0432 (4)
H14	0.8666	−0.0271	0.1615	0.052*
C15	0.7578 (2)	−0.15257 (16)	0.19954 (15)	0.0526 (5)
H15	0.8328	−0.2169	0.2278	0.063*
C16	0.6282 (3)	−0.17131 (18)	0.19790 (17)	0.0588 (5)
H16	0.6145	−0.2481	0.2256	0.071*
C17	0.5187 (3)	−0.0763 (2)	0.1552 (2)	0.0688 (6)
H17	0.4307	−0.0888	0.1532	0.083*
C18	0.5376 (2)	0.03834 (17)	0.11517 (18)	0.0549 (5)
H18	0.4620	0.1023	0.0873	0.066*
C19	0.1463 (2)	0.46798 (16)	−0.26655 (15)	0.0473 (4)
H19	0.0689	0.4312	−0.2248	0.057*
C20	0.1925 (3)	0.4802 (2)	−0.37291 (18)	0.0632 (6)
H20	0.1456	0.4523	−0.4028	0.076*
C21	0.3073 (3)	0.5336 (2)	−0.43442 (17)	0.0679 (6)
H21	0.3388	0.5416	−0.5060	0.081*
C22	0.3756 (2)	0.5751 (2)	−0.39001 (16)	0.0631 (6)
H22	0.4543	0.6104	−0.4316	0.076*
C23	0.3288 (2)	0.56516 (17)	−0.28433 (14)	0.0491 (4)
H23	0.3739	0.5954	−0.2553	0.059*
C24	0.21437 (17)	0.50998 (14)	−0.22197 (13)	0.0386 (4)
C25	0.24291 (16)	0.44610 (14)	−0.03268 (12)	0.0359 (3)
C26	0.20003 (18)	0.34640 (15)	0.23944 (13)	0.0424 (4)
H26	0.0987	0.3739	0.2478	0.051*
C27	0.2624 (2)	0.28071 (16)	0.33618 (13)	0.0454 (4)
C28	0.41423 (18)	0.23648 (15)	0.33456 (12)	0.0390 (4)
C29	0.4640 (2)	0.17511 (18)	0.43723 (14)	0.0511 (4)
C30	0.3662 (3)	0.1579 (2)	0.53196 (16)	0.0761 (7)
H30	0.4005	0.1163	0.5980	0.091*
C31	0.2168 (3)	0.2014 (3)	0.53072 (17)	0.0930 (10)
H31	0.1518	0.1890	0.5958	0.112*
C32	0.1649 (2)	0.2618 (2)	0.43560 (16)	0.0752 (7)
H32	0.0645	0.2910	0.4355	0.090*
N1	0.26909 (13)	0.37212 (11)	0.14090 (10)	0.0336 (3)
N2	0.17568 (14)	0.43889 (12)	0.06343 (10)	0.0379 (3)
N3	0.16198 (15)	0.49892 (14)	−0.11384 (11)	0.0455 (4)
O2	0.50937 (12)	0.24802 (10)	0.24580 (8)	0.0406 (3)
P1	0.68938 (4)	0.21048 (3)	0.05755 (3)	0.03082 (9)
Ni1	0.46961 (2)	0.312000 (17)	0.104547 (14)	0.03154 (7)
S1	0.42853 (4)	0.38465 (4)	−0.05808 (3)	0.04352 (11)
O1	0.6109 (6)	0.1463 (8)	0.4341 (6)	0.0517 (16)	0.631 (9)
C33	0.6533 (5)	0.0936 (6)	0.5392 (4)	0.0681 (16)	0.631 (9)
H33A	0.6287	0.0165	0.5813	0.082*	0.631 (9)
H33B	0.6046	0.1438	0.5786	0.082*	0.631 (9)
C34	0.8162 (6)	0.0818 (6)	0.5175 (4)	0.107 (2)	0.631 (9)
H34A	0.8521	0.0475	0.5851	0.161*	0.631 (9)
H34B	0.8385	0.1587	0.4747	0.161*	0.631 (9)
H34C	0.8624	0.0316	0.4787	0.161*	0.631 (9)
O1A	0.6128 (11)	0.1203 (14)	0.4277 (10)	0.057 (3)	0.369 (9)
C33A	0.6898 (11)	0.0516 (7)	0.5191 (7)	0.060 (2)	0.369 (9)
H33C	0.7794	0.0018	0.4978	0.072*	0.369 (9)
H33D	0.6296	−0.0003	0.5770	0.072*	0.369 (9)
C34A	0.7290 (13)	0.1242 (7)	0.5628 (7)	0.087 (3)	0.369 (9)
H34D	0.7741	0.0722	0.6261	0.130*	0.369 (9)
H34E	0.6416	0.1761	0.5817	0.130*	0.369 (9)
H34F	0.7962	0.1705	0.5083	0.130*	0.369 (9)
H3A	0.0681 (11)	0.5085 (18)	−0.0919 (16)	0.057 (6)*

	U11	U22	U33	U12	U13	U23
C1	0.0238 (7)	0.0430 (8)	0.0337 (7)	−0.0043 (6)	−0.0051 (6)	−0.0172 (6)
C2	0.0395 (9)	0.0455 (9)	0.0439 (9)	−0.0078 (7)	−0.0038 (7)	−0.0164 (7)
C3	0.0497 (11)	0.0589 (11)	0.0420 (10)	−0.0141 (9)	−0.0041 (8)	−0.0066 (8)
C4	0.0474 (11)	0.0840 (14)	0.0335 (9)	−0.0116 (10)	−0.0029 (8)	−0.0222 (9)
C5	0.0455 (10)	0.0719 (13)	0.0458 (10)	−0.0077 (9)	−0.0050 (8)	−0.0353 (10)
C6	0.0343 (8)	0.0480 (9)	0.0399 (8)	−0.0059 (7)	−0.0067 (7)	−0.0212 (7)
C7	0.0288 (8)	0.0389 (8)	0.0429 (8)	−0.0033 (6)	−0.0097 (6)	−0.0200 (7)
C8	0.0319 (9)	0.0725 (12)	0.0460 (10)	−0.0156 (8)	−0.0056 (7)	−0.0235 (9)
C9	0.0309 (9)	0.0746 (13)	0.0663 (12)	−0.0147 (9)	−0.0067 (8)	−0.0290 (11)
C10	0.0381 (10)	0.0664 (12)	0.0773 (14)	−0.0041 (9)	−0.0240 (9)	−0.0378 (11)
C11	0.0471 (12)	0.1075 (18)	0.0641 (13)	−0.0034 (11)	−0.0207 (10)	−0.0510 (13)
C12	0.0348 (9)	0.0864 (14)	0.0531 (11)	−0.0015 (9)	−0.0105 (8)	−0.0412 (11)
C13	0.0309 (8)	0.0397 (8)	0.0312 (7)	−0.0064 (6)	−0.0040 (6)	−0.0148 (6)
C14	0.0361 (9)	0.0445 (9)	0.0463 (9)	−0.0049 (7)	−0.0116 (7)	−0.0156 (7)
C15	0.0587 (12)	0.0414 (9)	0.0512 (10)	−0.0034 (8)	−0.0156 (9)	−0.0142 (8)
C16	0.0711 (14)	0.0466 (10)	0.0579 (12)	−0.0218 (10)	−0.0081 (10)	−0.0158 (9)
C17	0.0556 (13)	0.0652 (13)	0.0933 (17)	−0.0274 (11)	−0.0178 (12)	−0.0259 (12)
C18	0.0357 (10)	0.0527 (10)	0.0757 (13)	−0.0089 (8)	−0.0180 (9)	−0.0206 (10)
C19	0.0393 (9)	0.0474 (9)	0.0520 (10)	0.0008 (7)	−0.0124 (8)	−0.0212 (8)
C20	0.0630 (14)	0.0726 (14)	0.0646 (13)	0.0086 (11)	−0.0259 (11)	−0.0430 (11)
C21	0.0651 (14)	0.0838 (15)	0.0405 (10)	0.0083 (12)	−0.0080 (10)	−0.0293 (11)
C22	0.0523 (12)	0.0723 (14)	0.0430 (10)	−0.0078 (10)	0.0011 (9)	−0.0138 (10)
C23	0.0444 (10)	0.0543 (10)	0.0421 (9)	−0.0076 (8)	−0.0074 (8)	−0.0157 (8)
C24	0.0307 (8)	0.0403 (8)	0.0354 (8)	0.0055 (6)	−0.0098 (6)	−0.0133 (6)
C25	0.0272 (7)	0.0390 (8)	0.0362 (8)	0.0001 (6)	−0.0079 (6)	−0.0139 (6)
C26	0.0307 (8)	0.0497 (9)	0.0385 (8)	0.0036 (7)	−0.0039 (6)	−0.0199 (7)
C27	0.0404 (9)	0.0537 (10)	0.0322 (8)	−0.0009 (7)	−0.0029 (7)	−0.0167 (7)
C28	0.0400 (9)	0.0438 (9)	0.0316 (8)	−0.0042 (7)	−0.0070 (6)	−0.0163 (7)
C29	0.0499 (11)	0.0627 (11)	0.0359 (9)	−0.0055 (9)	−0.0121 (8)	−0.0175 (8)
C30	0.0683 (15)	0.1077 (19)	0.0312 (9)	−0.0042 (13)	−0.0108 (9)	−0.0184 (11)
C31	0.0641 (15)	0.142 (3)	0.0324 (10)	−0.0011 (15)	0.0044 (10)	−0.0219 (13)
C32	0.0480 (12)	0.1078 (19)	0.0403 (10)	0.0043 (12)	0.0015 (9)	−0.0239 (11)
N1	0.0260 (6)	0.0373 (6)	0.0337 (6)	0.0022 (5)	−0.0076 (5)	−0.0155 (5)
N2	0.0270 (6)	0.0443 (7)	0.0340 (7)	0.0042 (5)	−0.0079 (5)	−0.0149 (6)
N3	0.0255 (7)	0.0641 (9)	0.0348 (7)	0.0038 (6)	−0.0075 (6)	−0.0171 (7)
O2	0.0304 (6)	0.0562 (7)	0.0309 (5)	−0.0018 (5)	−0.0072 (4)	−0.0176 (5)
P1	0.02285 (18)	0.0374 (2)	0.03196 (19)	−0.00183 (14)	−0.00561 (14)	−0.01614 (15)
Ni1	0.02392 (10)	0.03883 (11)	0.02941 (10)	0.00097 (7)	−0.00641 (7)	−0.01555 (8)
S1	0.02623 (19)	0.0627 (3)	0.03223 (19)	0.00587 (17)	−0.00726 (15)	−0.01987 (18)
O1	0.0459 (19)	0.071 (4)	0.0370 (16)	−0.0052 (15)	−0.0166 (13)	−0.0200 (17)
C33	0.063 (3)	0.095 (4)	0.040 (2)	−0.002 (3)	−0.024 (2)	−0.022 (2)
C34	0.071 (3)	0.164 (6)	0.070 (3)	0.011 (3)	−0.042 (3)	−0.039 (3)
O1A	0.060 (4)	0.067 (6)	0.044 (3)	−0.006 (3)	−0.031 (3)	−0.016 (3)
C33A	0.067 (5)	0.063 (5)	0.043 (4)	0.001 (3)	−0.025 (4)	−0.015 (3)
C34A	0.098 (8)	0.093 (6)	0.071 (5)	−0.023 (5)	−0.038 (5)	−0.020 (4)

C1—C6	1.384 (2)	C22—C23	1.379 (3)
C1—C2	1.394 (2)	C22—H22	0.9300
C1—P1	1.8240 (15)	C23—C24	1.380 (2)
C2—C3	1.385 (3)	C23—H23	0.9300
C2—H2	0.9300	C24—N3	1.411 (2)
C3—C4	1.375 (3)	C25—N2	1.297 (2)
C3—H3	0.9300	C25—N3	1.355 (2)
C4—C5	1.373 (3)	C25—S1	1.7367 (15)
C4—H4	0.9300	C26—N1	1.293 (2)
C5—C6	1.384 (2)	C26—C27	1.420 (2)
C5—H5	0.9300	C26—H26	0.9300
C6—H6	0.9300	C27—C28	1.404 (2)
C7—C12	1.377 (2)	C27—C32	1.413 (3)
C7—C8	1.386 (2)	C28—O2	1.3038 (19)
C7—P1	1.8227 (16)	C28—C29	1.430 (2)
C8—C9	1.380 (2)	C29—O1	1.351 (6)
C8—H8	0.9300	C29—C30	1.370 (3)
C9—C10	1.359 (3)	C29—O1A	1.396 (9)
C9—H9	0.9300	C30—C31	1.386 (3)
C10—C11	1.369 (3)	C30—H30	0.9300
C10—H10	0.9300	C31—C32	1.350 (3)
C11—C12	1.389 (3)	C31—H31	0.9300
C11—H11	0.9300	C32—H32	0.9300
C12—H12	0.9300	N1—N2	1.3986 (17)
C13—C18	1.375 (2)	N1—Ni1	1.8766 (12)
C13—C14	1.385 (2)	N3—H3A	0.867 (9)
C13—P1	1.8226 (16)	O2—Ni1	1.8676 (10)
C14—C15	1.378 (3)	P1—Ni1	2.2291 (4)
C14—H14	0.9300	Ni1—S1	2.1355 (4)
C15—C16	1.365 (3)	O1—C33	1.433 (6)
C15—H15	0.9300	C33—C34	1.499 (6)
C16—C17	1.368 (3)	C33—H33A	0.9700
C16—H16	0.9300	C33—H33B	0.9700
C17—C18	1.384 (3)	C34—H34A	0.9600
C17—H17	0.9300	C34—H34B	0.9600
C18—H18	0.9300	C34—H34C	0.9600
C19—C24	1.376 (2)	O1A—C33A	1.440 (8)
C19—C20	1.380 (3)	C33A—C34A	1.514 (8)
C19—H19	0.9300	C33A—H33C	0.9700
C20—C21	1.370 (3)	C33A—H33D	0.9700
C20—H20	0.9300	C34A—H34D	0.9600
C21—C22	1.371 (3)	C34A—H34E	0.9600
C21—H21	0.9300	C34A—H34F	0.9600
C6—C1—C2	118.85 (15)	N2—C25—S1	122.28 (12)
C6—C1—P1	122.34 (12)	N3—C25—S1	119.85 (12)
C2—C1—P1	118.77 (12)	N1—C26—C27	126.96 (15)
C3—C2—C1	120.20 (17)	N1—C26—H26	116.5
C3—C2—H2	119.9	C27—C26—H26	116.5
C1—C2—H2	119.9	C28—C27—C32	120.72 (17)
C4—C3—C2	120.22 (18)	C28—C27—C26	122.12 (15)
C4—C3—H3	119.9	C32—C27—C26	117.16 (17)
C2—C3—H3	119.9	O2—C28—C27	123.68 (14)
C5—C4—C3	119.97 (17)	O2—C28—C29	119.47 (15)
C5—C4—H4	120.0	C27—C28—C29	116.85 (15)
C3—C4—H4	120.0	O1—C29—C30	122.8 (3)
C4—C5—C6	120.34 (18)	C30—C29—O1A	126.1 (6)
C4—C5—H5	119.8	O1—C29—C28	116.2 (3)
C6—C5—H5	119.8	C30—C29—C28	120.74 (18)
C1—C6—C5	120.41 (17)	O1A—C29—C28	112.1 (5)
C1—C6—H6	119.8	C29—C30—C31	120.92 (19)
C5—C6—H6	119.8	C29—C30—H30	119.5
C12—C7—C8	118.72 (16)	C31—C30—H30	119.5
C12—C7—P1	120.03 (13)	C32—C31—C30	120.4 (2)
C8—C7—P1	121.08 (13)	C32—C31—H31	119.8
C9—C8—C7	120.85 (17)	C30—C31—H31	119.8
C9—C8—H8	119.6	C31—C32—C27	120.4 (2)
C7—C8—H8	119.6	C31—C32—H32	119.8
C10—C9—C8	120.13 (18)	C27—C32—H32	119.8
C10—C9—H9	119.9	C26—N1—N2	112.89 (13)
C8—C9—H9	119.9	C26—N1—Ni1	124.00 (11)
C9—C10—C11	119.76 (18)	N2—N1—Ni1	122.73 (10)
C9—C10—H10	120.1	C25—N2—N1	111.59 (12)
C11—C10—H10	120.1	C25—N3—C24	125.84 (14)
C10—C11—C12	120.80 (19)	C25—N3—H3A	114.2 (14)
C10—C11—H11	119.6	C24—N3—H3A	117.7 (14)
C12—C11—H11	119.6	C28—O2—Ni1	127.12 (10)
C7—C12—C11	119.71 (18)	C13—P1—C7	104.13 (7)
C7—C12—H12	120.1	C13—P1—C1	103.46 (7)
C11—C12—H12	120.1	C7—P1—C1	102.25 (7)
C18—C13—C14	118.68 (16)	C13—P1—Ni1	104.28 (5)
C18—C13—P1	118.34 (13)	C7—P1—Ni1	122.93 (5)
C14—C13—P1	122.96 (12)	C1—P1—Ni1	117.52 (5)
C15—C14—C13	120.54 (17)	O2—Ni1—N1	94.98 (5)
C15—C14—H14	119.7	O2—Ni1—S1	178.91 (4)
C13—C14—H14	119.7	N1—Ni1—S1	86.08 (4)
C16—C15—C14	120.43 (18)	O2—Ni1—P1	88.98 (4)
C16—C15—H15	119.8	N1—Ni1—P1	166.97 (4)
C14—C15—H15	119.8	S1—Ni1—P1	90.029 (15)
C15—C16—C17	119.51 (18)	C25—S1—Ni1	97.19 (5)
C15—C16—H16	120.2	C29—O1—C33	113.5 (5)
C17—C16—H16	120.2	O1—C33—C34	105.1 (4)
C16—C17—C18	120.6 (2)	O1—C33—H33A	110.7
C16—C17—H17	119.7	C34—C33—H33A	110.7
C18—C17—H17	119.7	O1—C33—H33B	110.7
C13—C18—C17	120.25 (18)	C34—C33—H33B	110.7
C13—C18—H18	119.9	H33A—C33—H33B	108.8
C17—C18—H18	119.9	C33—C34—H34A	109.5
C24—C19—C20	120.34 (19)	C33—C34—H34B	109.5
C24—C19—H19	119.8	H34A—C34—H34B	109.5
C20—C19—H19	119.8	C33—C34—H34C	109.5
C21—C20—C19	120.0 (2)	H34A—C34—H34C	109.5
C21—C20—H20	120.0	H34B—C34—H34C	109.5
C19—C20—H20	120.0	C29—O1A—C33A	123.3 (10)
C20—C21—C22	119.76 (19)	O1A—C33A—C34A	114.7 (9)
C20—C21—H21	120.1	O1A—C33A—H33C	108.6
C22—C21—H21	120.1	C34A—C33A—H33C	108.6
C21—C22—C23	120.7 (2)	O1A—C33A—H33D	108.6
C21—C22—H22	119.6	C34A—C33A—H33D	108.6
C23—C22—H22	119.6	H33C—C33A—H33D	107.6
C22—C23—C24	119.45 (19)	C33A—C34A—H34D	109.5
C22—C23—H23	120.3	C33A—C34A—H34E	109.5
C24—C23—H23	120.3	H34D—C34A—H34E	109.5
C19—C24—C23	119.70 (16)	C33A—C34A—H34F	109.5
C19—C24—N3	118.93 (16)	H34D—C34A—H34F	109.5
C23—C24—N3	121.33 (16)	H34E—C34A—H34F	109.5
N2—C25—N3	117.79 (14)
C6—C1—C2—C3	1.5 (3)	C26—N1—N2—C25	−168.96 (15)
P1—C1—C2—C3	179.34 (14)	Ni1—N1—N2—C25	4.26 (19)
C1—C2—C3—C4	−0.9 (3)	N2—C25—N3—C24	−176.89 (16)
C2—C3—C4—C5	−0.3 (3)	S1—C25—N3—C24	0.0 (3)
C3—C4—C5—C6	1.0 (3)	C19—C24—N3—C25	124.94 (19)
C2—C1—C6—C5	−0.8 (2)	C23—C24—N3—C25	−57.1 (3)
P1—C1—C6—C5	−178.58 (13)	C27—C28—O2—Ni1	−5.5 (3)
C4—C5—C6—C1	−0.4 (3)	C29—C28—O2—Ni1	174.13 (13)
C12—C7—C8—C9	1.4 (3)	C18—C13—P1—C7	168.08 (15)
P1—C7—C8—C9	−173.88 (16)	C14—C13—P1—C7	−13.76 (16)
C7—C8—C9—C10	−0.2 (3)	C18—C13—P1—C1	−85.35 (15)
C8—C9—C10—C11	−1.1 (3)	C14—C13—P1—C1	92.81 (14)
C9—C10—C11—C12	1.0 (4)	C18—C13—P1—Ni1	38.09 (15)
C8—C7—C12—C11	−1.4 (3)	C14—C13—P1—Ni1	−143.74 (13)
P1—C7—C12—C11	173.92 (17)	C12—C7—P1—C13	−75.24 (16)
C10—C11—C12—C7	0.2 (4)	C8—C7—P1—C13	99.97 (15)
C18—C13—C14—C15	0.5 (3)	C12—C7—P1—C1	177.28 (15)
P1—C13—C14—C15	−177.64 (14)	C8—C7—P1—C1	−7.50 (16)
C13—C14—C15—C16	−0.5 (3)	C12—C7—P1—Ni1	42.54 (17)
C14—C15—C16—C17	0.6 (3)	C8—C7—P1—Ni1	−142.24 (13)
C15—C16—C17—C18	−0.8 (4)	C6—C1—P1—C13	−12.23 (15)
C14—C13—C18—C17	−0.7 (3)	C2—C1—P1—C13	169.99 (13)
P1—C13—C18—C17	177.52 (17)	C6—C1—P1—C7	95.76 (14)
C16—C17—C18—C13	0.9 (4)	C2—C1—P1—C7	−82.02 (14)
C24—C19—C20—C21	0.5 (3)	C6—C1—P1—Ni1	−126.48 (12)
C19—C20—C21—C22	−0.3 (3)	C2—C1—P1—Ni1	55.74 (14)
C20—C21—C22—C23	−0.8 (3)	C28—O2—Ni1—N1	10.45 (14)
C21—C22—C23—C24	1.7 (3)	C28—O2—Ni1—P1	−157.11 (14)
C20—C19—C24—C23	0.4 (3)	C26—N1—Ni1—O2	−11.00 (15)
C20—C19—C24—N3	178.31 (16)	N2—N1—Ni1—O2	176.53 (12)
C22—C23—C24—C19	−1.4 (3)	C26—N1—Ni1—S1	169.23 (14)
C22—C23—C24—N3	−179.34 (17)	N2—N1—Ni1—S1	−3.23 (11)
N1—C26—C27—C28	1.4 (3)	C26—N1—Ni1—P1	96.3 (2)
N1—C26—C27—C32	−179.0 (2)	N2—N1—Ni1—P1	−76.2 (2)
C32—C27—C28—O2	178.0 (2)	C13—P1—Ni1—O2	74.61 (6)
C26—C27—C28—O2	−2.4 (3)	C7—P1—Ni1—O2	−43.10 (7)
C32—C27—C28—C29	−1.6 (3)	C1—P1—Ni1—O2	−171.60 (7)
C26—C27—C28—C29	177.97 (17)	C13—P1—Ni1—N1	−33.36 (18)
O2—C28—C29—O1	8.5 (5)	C7—P1—Ni1—N1	−151.07 (18)
C27—C28—C29—O1	−171.9 (5)	C1—P1—Ni1—N1	80.43 (19)
O2—C28—C29—C30	−177.6 (2)	C13—P1—Ni1—S1	−105.85 (5)
C27—C28—C29—C30	2.0 (3)	C7—P1—Ni1—S1	136.44 (7)
O2—C28—C29—O1A	−8.3 (8)	C1—P1—Ni1—S1	7.95 (6)
C27—C28—C29—O1A	171.3 (8)	N2—C25—S1—Ni1	0.68 (15)
O1—C29—C30—C31	172.2 (6)	N3—C25—S1—Ni1	−176.12 (13)
O1A—C29—C30—C31	−169.0 (9)	N1—Ni1—S1—C25	1.20 (7)
C28—C29—C30—C31	−1.3 (4)	P1—Ni1—S1—C25	168.75 (6)
C29—C30—C31—C32	0.1 (5)	C30—C29—O1—C33	1.5 (9)
C30—C31—C32—C27	0.3 (5)	O1A—C29—O1—C33	−106 (4)
C28—C27—C32—C31	0.5 (4)	C28—C29—O1—C33	175.3 (5)
C26—C27—C32—C31	−179.1 (3)	C29—O1—C33—C34	−173.6 (8)
C27—C26—N1—N2	−179.63 (17)	O1—C29—O1A—C33A	73 (3)
C27—C26—N1—Ni1	7.3 (3)	C30—C29—O1A—C33A	−10.7 (19)
N3—C25—N2—N1	173.97 (14)	C28—C29—O1A—C33A	−179.3 (11)
S1—C25—N2—N1	−2.9 (2)	C29—O1A—C33A—C34A	−76.9 (19)

D—H···A	D—H	H···A	D···A	D—H···A
C12—H12···O1	0.93	2.46	3.314 (7)	154
C12—H12···O2	0.93	2.35	3.113 (2)	139
N3—H3A···N2i	0.87 (1)	2.22 (1)	3.0811 (19)	170 (2)
C33A—H33D···Cg7ii	0.97	2.79	3.279 (10)	112

Table 1

Hydrogen-bond geometry (Å, °)

Cg7 is the centroid of the C27–C32 ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C12—H12⋯O1	0.93	2.46	3.314 (7)	154
C12—H12⋯O2	0.93	2.35	3.113 (2)	139
N3—H3A⋯N2i	0.87 (1)	2.22 (1)	3.0811 (19)	170 (2)
C33A—H33D⋯Cg7ii	0.97	2.79	3.279 (10)	112

Symmetry codes: (i) ; (ii) .