Literature DB >> 26864731

Amine-bis(phenolate) Iron(III)-Catalyzed Formal Hydroamination of Olefins.

Kailong Zhu1, Michael P Shaver2, Stephen P Thomas3.   

Abstract

A practical synthesis of highly functionalized amines by the formal hydroamination reaction of alkenes with nitroarenes catalyzed by an air stable amine-bis(phenolate) iron(III) complex is reported. The reaction uses an easily handled silane, low catalyst loadings, and mild reaction conditions. A wide range of substrates are transformed with synthetically useful yields (21 examples).
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  amine-bis(phenolate); hydroamination; iron; radicals; silanes

Mesh：

Substances：

Year:  2016        PMID： 26864731     DOI： 10.1002/asia.201501098

Source DB:  PubMed          Journal:  Chem Asian J        ISSN： 1861-471X


  7 in total

1.  DFT analysis of the electronic structure of Fe(IV) species active in nitrene transfer catalysis: influence of the coordination sphere.

Authors:  Ranjan Patra; Pascale Maldivi
Journal:  J Mol Model       Date:  2016-10-27       Impact factor: 1.810

2.  Cobalt-Catalyzed Cyclization of Unsaturated N-Acyl Sulfonamides: a Diverted Mukaiyama Hydration Reaction.

Authors:  David M Fischer; Moritz Balkenhohl; Erick M Carreira
Journal:  JACS Au       Date:  2022-05-06

3.  Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

Authors:  Steven W M Crossley; Carla Obradors; Ruben M Martinez; Ryan A Shenvi
Journal:  Chem Rev       Date:  2016-07-27       Impact factor: 60.622

4.  Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes.

Authors:  Xuzhong Shen; Xu Chen; Jieping Chen; Yufeng Sun; Zhaoyang Cheng; Zhan Lu
Journal:  Nat Commun       Date:  2020-02-07       Impact factor: 14.919

Review 5.  Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals.

Authors:  Sophia L Shevick; Conner V Wilson; Simona Kotesova; Dongyoung Kim; Patrick L Holland; Ryan A Shenvi
Journal:  Chem Sci       Date:  2020-09-29       Impact factor: 9.825

6.  Amine synthesis via iron-catalysed reductive coupling of nitroarenes with alkyl halides.

Authors:  Chi Wai Cheung; Xile Hu
Journal:  Nat Commun       Date:  2016-08-12       Impact factor: 14.919

Review 7.  First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation.

Authors:  Sophie Bezzenine-Lafollée; Richard Gil; Damien Prim; Jérôme Hannedouche
Journal:  Molecules       Date:  2017-11-04       Impact factor: 4.411
  7 in total

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