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Literature DB >> 26853380

Recent highlights in mixed-coordinate oligophosphorus chemistry.

Maximilian Donath¹, Felix Hennersdorf, Jan J Weigand.

Abstract

This review aims to highlight and comprehensively summarize recent developments in the field of mixed-coordinate phosphorus chemistry. Particular attention is focused on the synthetic approaches to compounds containing at least two directly bonded phosphorus atoms in different coordination environments and their unexpected properties that are derived from spectroscopic and crystallographic data. Novel substance classes are discussed in order to supplement previous reviews about mixed-coordinate phosphorus compounds.

Entities: Chemical Disease

Year: 2016 PMID： 26853380 DOI： 10.1039/c5cs00682a

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

6 in total

Recent highlights in mixed-coordinate oligophosphorus chemistry.

1. P-P Condensation and P-N/P-P Bond Metathesis: Facile Synthesis of Cationic Tri- and Tetraphosphanes.

Review 2. Functionalization of Pentaphosphorus Cations by Complexation.

3. First experimental evidence for the elusive tetrahedral cations [EP₃]⁺ (E = S, Se, Te) in the condensed phase.

4. Homoatomic cations: From [P₅]⁺ to [P₉]^.

5. Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor.

6. A Systematic Survey of the Reactivity of Chlorinated N₂ P₂ , NP₃ and P₄ Ring Systems.

Recent highlights in mixed-coordinate oligophosphorus chemistry.

1. P-P Condensation and P-N/P-P Bond Metathesis: Facile Synthesis of Cationic Tri- and Tetraphosphanes.

Review 2. Functionalization of Pentaphosphorus Cations by Complexation.

3. First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase.

4. Homoatomic cations: From [P5]+ to [P9].

5. Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor.

6. A Systematic Survey of the Reactivity of Chlorinated N2 P2 , NP3 and P4 Ring Systems.

3. First experimental evidence for the elusive tetrahedral cations [EP₃]⁺ (E = S, Se, Te) in the condensed phase.

4. Homoatomic cations: From [P₅]⁺ to [P₉]^.

6. A Systematic Survey of the Reactivity of Chlorinated N₂ P₂ , NP₃ and P₄ Ring Systems.