| Literature DB >> 26743787 |
José A Castro-Osma1, Michael North2, Xiao Wu1.
Abstract
Chromium and aluminium salphen complexes have been found to display remarkable catalytic activity in the synthesis of cyclic carbonates from a range of epoxides and carbon dioxide. The Al(salphen) complex is more reactive towards terminal epoxides at ambient temperature and pressure, whereas the Cr(salphen) complex exhibits higher catalytic activity towards more challenging internal epoxides at elevated temperature and pressure.Entities:
Keywords: aluminium; chromium; cyclic carbonates; epoxides; homogeneous catalysis; salphen ligands
Year: 2016 PMID: 26743787 DOI: 10.1002/chem.201504305
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236