Literature DB >> 26743787

Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes.

José A Castro-Osma1, Michael North2, Xiao Wu1.   

Abstract

Chromium and aluminium salphen complexes have been found to display remarkable catalytic activity in the synthesis of cyclic carbonates from a range of epoxides and carbon dioxide. The Al(salphen) complex is more reactive towards terminal epoxides at ambient temperature and pressure, whereas the Cr(salphen) complex exhibits higher catalytic activity towards more challenging internal epoxides at elevated temperature and pressure.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  aluminium; chromium; cyclic carbonates; epoxides; homogeneous catalysis; salphen ligands

Year:  2016        PMID: 26743787     DOI: 10.1002/chem.201504305

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  6 in total

1.  Synthesis of novel polycarbonyl Schiff bases by ring-opening reaction of ethyl 5-acyl-4-pyrone-2-carboxylates with primary mono- and diamines.

Authors:  D L Obydennov; L R Khammatova; V D Steben'kov; V Y Sosnovskikh
Journal:  RSC Adv       Date:  2019-12-03       Impact factor: 4.036

2.  CO2 Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System.

Authors:  Maximilian Tiffner; Sabrina Gonglach; Michael Haas; Wolfgang Schöfberger; Mario Waser
Journal:  Chem Asian J       Date:  2017-04-20

3.  Green Synthesis of Novel Polyesterurethane Materials from Epoxides and Carbon Dioxide by New Set of One-Dimensional Coordination Polymer Catalyst.

Authors:  Arunangshu Kundu; Gobinda Chandra De; Sushobhan Ghosh
Journal:  ACS Omega       Date:  2019-08-14

4.  Ring-Opening Polymerization of ε-Caprolactone and Styrene Oxide-CO2 Coupling Reactions Catalyzed by Chelated Dehydroacetic Acid-Imine Aluminum Complexes.

Authors:  Ting-Yen Wang; Yu-Chia Su; Bao-Tsan Ko; Yu Hsu; Yu-Fang Zeng; Ching-Han Hu; Amitabha Datta; Jui-Hsien Huang
Journal:  Molecules       Date:  2021-12-28       Impact factor: 4.411

5.  Synthesis of Novel Non-Isocyanate Polyurethane/Functionalized Boron Nitride Composites.

Authors:  Said El Khezraji; Manal Chaib; Suman Thakur; Mustapha Raihane; Miguel A Lopez-Manchado; Raquel Verdejo; Mohammed Lahcini
Journal:  Polymers (Basel)       Date:  2022-09-20       Impact factor: 4.967

6.  Developing Eco-Friendly and Cost-Effective Porous Adsorbent for Carbon Dioxide Capture.

Authors:  Mahboubeh Nabavinia; Baishali Kanjilal; Noahiro Fujinuma; Amos Mugweru; Iman Noshadi
Journal:  Molecules       Date:  2021-03-31       Impact factor: 4.411

  6 in total

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