Literature DB >> 26605977

An Enantioselective Approach to 4-O-Protected-2-cyclopentene-l,4-diol Derivatives via a Rhodium-Catalyzed Redox-Isomerization Reaction.

Kai Ren1, Mengmeng Zhao1, Bei Hu1, Bin Lu1, Xiaomin Xie1, Virginie Ratovelomanana-Vidal2, Zhaoguo Zhang1,3.   

Abstract

Kinetic resolution of a series of cyclopentene-1,4-diol derivatives has been successfully achieved with enantiomeric excess up to 99.4% and a kf/ks ratio of 55 by a rhodium-catalyzed redox-isomerization reaction in a noncoordinating solvent.

Entities:  

Year:  2015        PMID： 26605977     DOI： 10.1021/acs.joc.5b02519

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Tritylation of Alcohols under Mild Conditions without Using Silver Salts.

Authors:  Shahien Shahsavari; Jinsen Chen; Travis Wigstrom; James Gooding; Alexander Gauronskas; Shiyue Fang
Journal:  Tetrahedron Lett       Date:  2016-07-18       Impact factor: 2.415

2.  Oxidation of Secondary Methyl Ethers to Ketones.

Authors:  Pieter J Gilissen; Daniel Blanco-Ania; Floris P J T Rutjes
Journal:  J Org Chem       Date:  2017-06-12       Impact factor: 4.354

3.  Enantiocontrolled Preparation of ϒ-Substituted Cyclohexenones: Synthesis and Kinase Activity Assays of Cyclopropyl-Fused Cyclohexane Nucleosides.

Authors:  Sergio Jurado; Beatriz Domínguez-Pérez; Ona Illa; Jan Balzarini; Félix Busqué; Ramon Alibés
Journal:  Int J Mol Sci       Date:  2022-08-26       Impact factor: 6.208
  3 in total

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