| Literature DB >> 26594571 |
Alexander A Golovanov1, Anna V Vologzhanina2, Ivan S Odin1, Tat'yana P Tret'yakova3, Sergey V Naumov3.
Abstract
In the title compound, C21H22ClNO3, the penta-diene unit is nearly planar [maximum deviation = 0.023 (1) Å], but the carbonyl O atom deviates significantly [by 0.304 (1) Å] from its mean plane, which is twisted with respect to the phenyl and chloro-benzene rings by 71.34 (13) and 46.40 (13)°, respectively. In the crystal, inversion-related molecules are linked by two pairs of O-H⋯O hydrogen bonds, forming chains propagating along [01-1], enclosing R (2) 2(16) and R (2) 2(22) ring motifs. The chains are linked via C-H⋯O hydrogen bonds and C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.Entities:
Keywords: C—H⋯π interactions; crystal structure; dienes; enamines; hydrogen bonding
Year: 2015 PMID: 26594571 PMCID: PMC4645000 DOI: 10.1107/S2056989015019568
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun