Literature DB >> 26488683

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C-F Bond Functionalizations.

Takashi Niwa1, Hidenori Ochiai1, Yasuyoshi Watanabe1, Takamitsu Hosoya1.   

Abstract

Ni/Cu-catalyzed transformation of fluoroarenes to arylboronic acid pinacol esters via C-F bond cleavage has been achieved. Further versatile derivatization of an arylboronic ester has allowed for the facile two-step conversion of a fluoroarene to diverse functionalized arenes, demonstrating the synthetic utility of the method.

Entities:  

Year:  2015        PMID： 26488683     DOI： 10.1021/jacs.5b10119

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  19 in total

1.  Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.

Authors:  Adelphe M Mfuh; John D Doyle; Bhuwan Chhetri; Hadi D Arman; Oleg V Larionov
Journal:  J Am Chem Soc       Date:  2016-03-01       Impact factor: 15.419

Review 2.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

3.  Nucleophilic Aromatic Substitution of Unactivated Fluoroarenes Enabled by Organic Photoredox Catalysis.

Authors:  Vincent A Pistritto; Megan E Schutzbach-Horton; David A Nicewicz
Journal:  J Am Chem Soc       Date:  2020-09-28       Impact factor: 15.419

4.  Manual and automated Cu-mediated radiosynthesis of the PARP inhibitor [18F]olaparib.

Authors:  Florian Guibbal; Patrick G Isenegger; Thomas C Wilson; Anna Pacelli; Damien Mahaut; Jeroen B I Sap; Nicholas J Taylor; Stefan Verhoog; Sean Preshlock; Rebekka Hueting; Bart Cornelissen; Véronique Gouverneur
Journal:  Nat Protoc       Date:  2020-02-28       Impact factor: 13.491

5.  Copper-Mediated Late-stage Radiofluorination: Five Years of Impact on Pre-clinical and Clinical PET Imaging.

Authors:  Jay S Wright; Tanpreet Kaur; Sean Preshlock; Sean S Tanzey; Wade P Winton; Liam S Sharninghausen; Nicholas Wiesner; Allen F Brooks; Melanie S Sanford; Peter J H Scott
Journal:  Clin Transl Imaging       Date:  2020-05-26

6.  Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution.

Authors:  Clare Bakewell; Andrew J P White; Mark R Crimmin
Journal:  J Am Chem Soc       Date:  2016-09-22       Impact factor: 15.419

7.  Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions.

Authors:  Xinxin Qi; Li-Bing Jiang; Chao Zhou; Jin-Bao Peng; Xiao-Feng Wu
Journal:  ChemistryOpen       Date:  2017-03-16       Impact factor: 2.911

8.  Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.

Authors:  Hidenori Ochiai; Yuta Uetake; Takashi Niwa; Takamitsu Hosoya
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-26       Impact factor: 15.336

9.  Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation.

Authors:  Jun Zhou; Bingyao Jiang; Yamato Fujihira; Zhengyu Zhao; Takanori Imai; Norio Shibata
Journal:  Nat Commun       Date:  2021-06-18       Impact factor: 14.919

10.  Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.

Authors:  Johannes Landmann; Philipp T Hennig; Nikolai V Ignat'ev; Maik Finze
Journal:  Chem Sci       Date:  2017-06-26       Impact factor: 9.825
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