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Literature DB >> 26458726

[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) Chemistry.

Miriam M Schwab¹, Daniel Himmel¹, Sylwia Kacprzak², Daniel Kratzert¹, Valentin Radtke¹, Philippe Weis¹, Kallol Ray³, Ernst-Wilhelm Scheidt⁴, Wolfgang Scherer⁴, Bas de Bruin⁵, Stefan Weber^2,6, Ingo Krossing⁷.

Abstract

The straightforward synthesis of the cationic, purely organometallic Ni(I) salt [Ni(cod)2](+)[Al(OR(F))4](-) was realized through a reaction between [Ni(cod)2] and Ag[Al(OR(F))4] (cod = 1,5-cyclooctadiene). Crystal-structure analysis and EPR, XANES, and cyclic voltammetry studies confirmed the presence of a homoleptic Ni(I) olefin complex. Weak interactions between the metal center, the ligands, and the anion provide a good starting material for further cationic Ni(I) complexes.

Entities: Chemical Disease Gene Species

Keywords: crystallography; cyclic voltammetry; density functional calculations; electron paramagnetic resonance; nickel(I) complexes

Mesh：

Substances：

Year: 2015 PMID： 26458726 PMCID： PMC5531756 DOI： 10.1002/anie.201506475

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

29 in total

1. Transition-metal ions in aluminophosphate and silicoaluminophosphate molecular sieves: location, interaction with adsorbates and catalytic properties.

Authors: M Hartmann; L Kevan
Journal: Chem Rev Date: 1999-03-10 Impact factor: 60.622

2. Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides.

Authors: Stefan Pelties; Dirk Herrmann; Bas de Bruin; František Hartl; Robert Wolf
Journal: Chem Commun (Camb) Date: 2014-05-21 Impact factor: 6.222

3. Lessons from isolable nickel(I) precursor complexes for small molecule activation.

Authors: Shenglai Yao; Matthias Driess
Journal: Acc Chem Res Date: 2011-08-29 Impact factor: 22.384

4. Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity.

Authors: Michael J Page; Wei Y Lu; Rebecca C Poulten; Emma Carter; Andrés G Algarra; Benson M Kariuki; Stuart A Macgregor; Mary F Mahon; Kingsley J Cavell; Damien M Murphy; Michael K Whittlesey
Journal: Chemistry Date: 2013-01-04 Impact factor: 5.236

5. [Transitory metal complexes. I. Olefin complexes of nickel (O)].

Authors: B Bogdanović; M Kröner; G Wilke
Journal: Justus Liebigs Ann Chem Date: 1966-11

6. First-row transition-metal chloride complexes of the wide bite-angle diphosphine (iPr)DPDBFphos and reactivity studies of monovalent nickel.

Authors: Elodie E Marlier; Stephen J Tereniak; Keying Ding; Jenna E Milliken; Jenna E Mulliken; Connie C Lu
Journal: Inorg Chem Date: 2011-08-31 Impact factor: 5.165

7. A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(I) chloride bearing a bulky NHC ligand.

Authors: Satoshi Miyazaki; Yuji Koga; Taisuke Matsumoto; Kouki Matsubara
Journal: Chem Commun (Camb) Date: 2010-02-11 Impact factor: 6.222

[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) Chemistry.

1. Transition-metal ions in aluminophosphate and silicoaluminophosphate molecular sieves: location, interaction with adsorbates and catalytic properties.

2. Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides.

3. Lessons from isolable nickel(I) precursor complexes for small molecule activation.

4. Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity.

5. [Transitory metal complexes. I. Olefin complexes of nickel (O)].

6. First-row transition-metal chloride complexes of the wide bite-angle diphosphine (iPr)DPDBFphos and reactivity studies of monovalent nickel.

7. A new aspect of nickel-catalyzed Grignard cross-coupling reactions: selective synthesis, structure, and catalytic behavior of a T-shape three-coordinate nickel(I) chloride bearing a bulky NHC ligand.

8. Propagation and termination steps in Rh-mediated carbene polymerisation using diazomethane.

9. A dinuclear nickel(I) dinitrogen complex and its reduction in single-electron steps.

10. Three-coordinate nickel(II) and nickel(I) thiolate complexes based on the β-diketiminate ligand system.

1. Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands.