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Literature DB >> 26450149

Crystal Structures of a Molecule Designed Not To Pack Tightly.

Bernd Kohl¹, Frank Rominger¹, Michael Mastalerz².

Abstract

Organic molecules of intrinsic microporosity (OMIMs) are structurally constructed to not pack tightly. Consequently, only weak interactions between OMIM molecules can occur, which is the reason that almost all OMIMs have been described and investigated in their amorphous states. For the same reason it is very difficult to grow single crystals of OMIMs for X-ray structural analysis. Here we describe four different polymorphs of an OMIM that was before only described in the amorphous state.

Keywords: OMIMs; X-ray crystal structure analysis; microporous materials; quinoxalinophenanthrophenazines; triptycene

Year: 2015 PMID： 26450149 DOI： 10.1002/chem.201502847

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

11 in total

Review 1. Recent Advances in Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds.

Authors: Arseni Borissov; Yogesh Kumar Maurya; Liliia Moshniaha; Wai-Shing Wong; Marika Żyła-Karwowska; Marcin Stępień
Journal: Chem Rev Date: 2021-12-01 Impact factor: 60.622

2. The Synthesis of Organic Molecules of Intrinsic Microporosity Designed to Frustrate Efficient Molecular Packing.

Authors: Rupert G D Taylor; C Grazia Bezzu; Mariolino Carta; Kadhum J Msayib; Jonathan Walker; Rhys Short; Benson M Kariuki; Neil B McKeown
Journal: Chemistry Date: 2016-01-11 Impact factor: 5.236

3. Arene Selectivity by a Flexible Coordination Polymer Host.

Authors: James S Wright; Iñigo J Vitórica-Yrezábal; Stephen P Thompson; Lee Brammer
Journal: Chemistry Date: 2016-08-02 Impact factor: 5.236

4. Functional materials discovery using energy-structure-function maps.

Authors: Angeles Pulido; Linjiang Chen; Tomasz Kaczorowski; Daniel Holden; Marc A Little; Samantha Y Chong; Benjamin J Slater; David P McMahon; Baltasar Bonillo; Chloe J Stackhouse; Andrew Stephenson; Christopher M Kane; Rob Clowes; Tom Hasell; Andrew I Cooper; Graeme M Day
Journal: Nature Date: 2017-03-22 Impact factor: 49.962

5. Triperyleno[3,3,3]propellane triimides: achieving a new generation of quasi-D _3h symmetric nanostructures in organic electronics.

Authors: Lingling Lv; Josiah Roberts; Chengyi Xiao; Zhenmei Jia; Wei Jiang; Guowei Zhang; Chad Risko; Lei Zhang
Journal: Chem Sci Date: 2019-04-12 Impact factor: 9.825

Crystal Structures of a Molecule Designed Not To Pack Tightly.

Review 1. Recent Advances in Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds.

2. The Synthesis of Organic Molecules of Intrinsic Microporosity Designed to Frustrate Efficient Molecular Packing.

3. Arene Selectivity by a Flexible Coordination Polymer Host.

4. Functional materials discovery using energy-structure-function maps.

5. Triperyleno[3,3,3]propellane triimides: achieving a new generation of quasi-D _3h symmetric nanostructures in organic electronics.

6. Three-Dimensional Pyrene-Fused N-Heteroacenes.

7. Di- and Tetracyano-Substituted Pyrene-Fused Pyrazaacenes: Aggregation in the Solid State.

8. Digital navigation of energy-structure-function maps for hydrogen-bonded porous molecular crystals.

9. Triptycene End-Capped Indigo Derivatives - Turning Insoluble Pigments to Soluble Dyes.

10. Regiocontrolled dimerization of asymmetric diazaheptacene derivatives toward X-shaped porous semiconductors.