Literature DB >> 26404541

Comparative Catalytic Activity of Group 9 [Cp*M(III)] Complexes: Cobalt-Catalyzed C-H Amidation of Arenes with Dioxazolones as Amidating Reagents.

Juhyeon Park1,2, Sukbok Chang3,4.   

Abstract

A procedure for the [Cp*Co(III)]-catalyzed direct C-H amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 [{Cp*MCl2}2] complexes revealed the unique efficiency of the cobalt catalyst.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CH activation; amidation; anilides; cobalt catalysis; dioxazolones

Year:  2015        PMID： 26404541     DOI： 10.1002/anie.201505820

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  12 in total

1.  Cobalt(III)-Catalyzed C-H Amidation of Dehydroalanine for the Site-Selective Structural Diversification of Thiostrepton.

Authors:  Ryan J Scamp; Edward deRamon; Eric K Paulson; Scott J Miller; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-27       Impact factor: 15.336

2.  Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C-H Bond Addition Cascade.

Authors:  Jeffrey A Boerth; Joshua R Hummel; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-15       Impact factor: 15.336

3.  CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes.

Authors:  Yujing Zhou; Oliver D Engl; Jeffrey S Bandar; Emma D Chant; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2018-04-30       Impact factor: 15.336

4.  RhodiumIII-catalyzed remote difunctionalization of arenes assisted by a relay directing group.

Authors:  Lincong Sun; Yuyao Zhao; Bingxian Liu; Junbiao Chang; Xingwei Li
Journal:  Chem Sci       Date:  2022-05-30       Impact factor: 9.969

5.  A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp(2) C-H Bond Amination.

Authors:  James Roane; Olafs Daugulis
Journal:  J Am Chem Soc       Date:  2016-03-18       Impact factor: 15.419

Review 6.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

7.  Co-catalyzed ortho-C-H functionalization/annulation of arenes and alkenes with alkynylsilanes: access to isoquinolone and pyridone motifs.

Authors:  Cong Lin; Liang Shen
Journal:  RSC Adv       Date:  2019-09-26       Impact factor: 4.036

8.  Radical-mediated direct C-H amination of arenes with secondary amines.

Authors:  Sebastian C Cosgrove; John M C Plane; Stephen P Marsden
Journal:  Chem Sci       Date:  2018-07-11       Impact factor: 9.825

9.  Thiocarbonyl-enabled ferrocene C-H nitrogenation by cobalt(III) catalysis: thermal and mechanochemical.

Authors:  Santhivardhana Reddy Yetra; Zhigao Shen; Hui Wang; Lutz Ackermann
Journal:  Beilstein J Org Chem       Date:  2018-06-25       Impact factor: 2.883

10.  A challenging redox neutral Cp*Co(III)-catalysed alkylation of acetanilides with 3-buten-2-one: synthesis and key insights into the mechanism through DFT calculations.

Authors:  Andrew Kenny; Alba Pisarello; Arron Bird; Paula G Chirila; Alex Hamilton; Christopher J Whiteoak
Journal:  Beilstein J Org Chem       Date:  2018-09-10       Impact factor: 2.883
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