Literature DB >> 26402516

A Novel Mechanochromic and Photochromic Polymer Film: When Rhodamine Joins Polyurethane.

Zhijian Wang1, Zhiyong Ma1, Yao Wang1, Zejun Xu1, Yiyang Luo1, Yen Wei2, Xinru Jia1.   

Abstract

A rhodamine-based molecule, Rh-OH, is synthesized. Rh-OH exhibits a reversible mechanochromic luminescent character but a passivating response to UV light. An elastomeric polymer film based on polyurethane with embedded Rh-OH is prepared via a polycondensation reaction. The film shows mechanochromic and photochromic properties with reversible color change, which originates from the isomerization of the Rh-OH molecule from a twisted spirolactam in the ring-closed form to a planarized zwitterionic structure in the ring-open state.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  crosslinking; mechanochromism; photochromism; polymer film; rhodamine derivative

Year:  2015        PMID: 26402516     DOI: 10.1002/adma.201503424

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  13 in total

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Authors:  Deniz Yildiz; Christoph Baumann; Annabel Mikosch; Alexander J C Kuehne; Andreas Herrmann; Robert Göstl
Journal:  Angew Chem Int Ed Engl       Date:  2019-07-19       Impact factor: 15.336

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Journal:  Nat Commun       Date:  2019-09-19       Impact factor: 14.919

4.  Protonation-Induced Enhanced Optical-Light Photochromic Properties of an Inorganic-Organic Phosphomolybdic Acid/Polyaniline Hybrid Thin Film.

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Journal:  Nanomaterials (Basel)       Date:  2020-09-15       Impact factor: 5.076

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Authors:  Yifei Pan; Huan Zhang; Piaoxue Xu; Yancong Tian; Chenxu Wang; Shishuai Xiang; Roman Boulatov; Wengui Weng
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-25       Impact factor: 15.336

6.  Fast reversible isomerization of merocyanine as a tool to quantify stress history in elastomers.

Authors:  Yinjun Chen; C Joshua Yeh; Qiang Guo; Yuan Qi; Rong Long; Costantino Creton
Journal:  Chem Sci       Date:  2020-12-17       Impact factor: 9.825

7.  A mechanochromic donor-acceptor torsional spring.

Authors:  Maximilian Raisch; Wafa Maftuhin; Michael Walter; Michael Sommer
Journal:  Nat Commun       Date:  2021-07-09       Impact factor: 14.919

8.  Rhodamine-Installed Polynorbornenes: Molecular Design, Structure, and Stimuli-Responsive Properties.

Authors:  Samiksha Vaidya; Meenakshi Sharma; Christian Brückner; Rajeswari M Kasi
Journal:  ACS Omega       Date:  2021-06-01

9.  Multi-modal mechanophores based on cinnamate dimers.

Authors:  Huan Zhang; Xun Li; Yangju Lin; Fei Gao; Zhen Tang; Peifeng Su; Wenke Zhang; Yuanze Xu; Wengui Weng; Roman Boulatov
Journal:  Nat Commun       Date:  2017-10-27       Impact factor: 14.919

10.  Water assisted biomimetic synergistic process and its application in water-jet rewritable paper.

Authors:  Guan Xi; Lan Sheng; Jiahui Du; Jinyan Zhang; Minjie Li; Hongze Wang; Yufei Ma; Sean Xiao-An Zhang
Journal:  Nat Commun       Date:  2018-11-16       Impact factor: 14.919

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