Literature DB >> 26396877

Crystal structure of 2-methyl-N-{[2-(pyri-din-2-yl)eth-yl]carbamo-thio-yl}benzamide.

Nadiah Ameram1, Farook Adam1.   

Abstract

In the title compound, C16H17N3OS, a benzoyl thio-urea derivative, the planes of the pyridine and benzene rings are inclined to one another by 66.54 (9)°. There is an intra-molecular N-H⋯O hydrogen bond present forming an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers, which are reinforced by pairs of C-H⋯S hydrogen bonds. The dimers are linked via C-H⋯π inter-actions, forming ribbons along [010].

Entities:  

Keywords:  benzamide; carbonyl thio­urea; crystal structure; hydrogen bonding; inversion dimers

Year:  2015        PMID: 26396877      PMCID: PMC4555406          DOI: 10.1107/S2056989015013559

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  4 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172

3.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20

4.  4-Methyl-N-[2-(pyridin-2-yl)ethyl-carbamo-thio-yl]benzamide.

Authors:  Farook Adam; Nadiah Ameram; Naser Eltaher Eltayeb
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-07-31
  4 in total

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