| Literature DB >> 26368791 |
Michal Majek1, Uwe Faltermeier2, Bernhard Dick2, Raúl Pérez-Ruiz3, Axel Jacobi von Wangelin4.
Abstract
The activation of aryl-Br bonds was achieved by sequential combination of a triplet-triplet annihilation process of the organic dyes, butane-2,3-dione and 2,5-diphenyloxazole, with a single-electron-transfer activation of aryl bromides. The photophysical and chemical steps were studied by time-resolved transient fluorescence and absorption spectroscopy with a pulsed laser, quenching experiments, and DFT calculations.Entities:
Keywords: aryl halides; defunctionalization; organocatalysis; photocatalysis; triplet states; two-photon process
Year: 2015 PMID: 26368791 DOI: 10.1002/chem.201502698
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236