Understanding Interfaces in Metal-Graphitic Hybrid Nanostructures.

Metal-graphitic interfaces formed between metal nanoparticles (MNPs) and carbon nanotubes (CNTs) or graphene play an important role in the properties of such hybrid nanostructures. This Perspective summarizes different types of interfaces that exist within the metal-carbon nanoassemblies and discusses current efforts on understanding and modeling the interfacial conditions and interactions. Characterization of the metal-graphitic interfaces is described here, including microscopy, spectroscopy, electrochemical techniques, and electrical measurements. Recent studies on these nanohybrids have shown that the metal-graphitic interfaces play critical roles in both controlled assembly of nanoparticles and practical applications of nanohybrids in chemical sensors and fuel cells. Better understanding, design, and manipulation of metal-graphitic interfaces could therefore become the new frontier in the research of MNP/CNT or MNP/graphene hybrid systems.