Literature DB >> 26262554

Metal-Free Reduction of Aromatic and Aliphatic Nitro Compounds to Amines: A HSiCl3-Mediated Reaction of Wide General Applicability.

M Orlandi1, F Tosi1, M Bonsignore1, M Benaglia1.   

Abstract

A new, mild, metal-free, HSiCl3-mediated reduction of both aromatic and aliphatic nitro groups to amines that is of wide general applicability, tolerant of many functional groups, and respectful of the stereochemical integrity of stereocenters is reported.

Entities:  

Year:  2015        PMID： 26262554     DOI： 10.1021/acs.orglett.5b01698

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  10 in total

1.  Organocatalytic Insertion of Isatins into Aryl Difluoronitromethyl Ketones.

Authors:  Ransheng Ding; Pegah R Bakhshi; Christian Wolf
Journal:  J Org Chem       Date:  2017-01-09       Impact factor: 4.354

Review 2.  Methods for Direct Reductive N-Methylation of Nitro Compounds.

Authors:  Zhijie Jiang; Evan Abdulkareem Mahmood; Nazanin Zare Harofteh; Abdol Ghaffar Ebadi; Mohsen Toughani; Esmail Vessally
Journal:  Top Curr Chem (Cham)       Date:  2022-05-24

3.  Substitution of a triazole for the central olefin in biologically active stilbenes.

Authors:  David P Stockdale; John A Beutler; David F Wiemer
Journal:  Bioorg Med Chem Lett       Date:  2022-09-09       Impact factor: 2.940

4.  1-Deazaguanosine-Modified RNA: The Missing Piece for Functional RNA Atomic Mutagenesis.

Authors:  Raphael Bereiter; Eva Renard; Kathrin Breuker; Christoph Kreutz; Eric Ennifar; Ronald Micura
Journal:  J Am Chem Soc       Date:  2022-06-06       Impact factor: 16.383

5.  Continuous-flow synthesis of primary amines: Metal-free reduction of aliphatic and aromatic nitro derivatives with trichlorosilane.

Authors:  Riccardo Porta; Alessandra Puglisi; Giacomo Colombo; Sergio Rossi; Maurizio Benaglia
Journal:  Beilstein J Org Chem       Date:  2016-12-05       Impact factor: 2.883

Review 6.  Whole Cells as Biocatalysts in Organic Transformations.

Authors:  Fabián Garzón-Posse; Liliana Becerra-Figueroa; José Hernández-Arias; Diego Gamba-Sánchez
Journal:  Molecules       Date:  2018-05-25       Impact factor: 4.411

7.  A Mild, DNA-Compatible Nitro Reduction Using B2(OH)4.

Authors:  Huang-Chi Du; Nicholas Simmons; John C Faver; Zhifeng Yu; Murugesan Palaniappan; Kevin Riehle; Martin M Matzuk
Journal:  Org Lett       Date:  2019-03-12       Impact factor: 6.005

8.  A one pot protocol to convert nitro-arenes into N-aryl amides.

Authors:  Elisabetta Massolo; Margherita Pirola; Alessandra Puglisi; Sergio Rossi; Maurizio Benaglia
Journal:  RSC Adv       Date:  2020-01-23       Impact factor: 4.036

9.  Telescoped Continuous Flow Synthesis of Optically Active γ-Nitrobutyric Acids as Key Intermediates of Baclofen, Phenibut, and Fluorophenibut.

Authors:  Sándor B Ötvös; Patricia Llanes; Miquel A Pericàs; C Oliver Kappe
Journal:  Org Lett       Date:  2020-10-07       Impact factor: 6.005

10.  Enantioselective Flow Synthesis of Rolipram Enabled by a Telescoped Asymmetric Conjugate Addition-Oxidative Aldehyde Esterification Sequence Using in Situ-Generated Persulfuric Acid as Oxidant.

Authors:  Bence S Nagy; Patricia Llanes; Miquel A Pericas; C Oliver Kappe; Sándor B Ötvös
Journal:  Org Lett       Date:  2022-01-20       Impact factor: 6.005
  10 in total

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