Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer.

Literature DB >> 26249108

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer.

Abstract

Environmentally sustainable hydrogen-evolving electrocatalysts are key in a renewable fuel economy, and ligand-based proton and electron transfer could circumvent the need for precious metal ions in electrocatalytic H2 production. Herein, we show that electrocatalytic generation of H2 by a redox-active ligand complex of Al(3+) occurs at -1.16 V vs. SCE (500 mV overpotential).

Entities: Chemical

Keywords: N ligands; aluminum; electrocatalysis; hydrogen evolution; redox-active ligands

Year: 2015 PMID： 26249108 DOI： 10.1002/anie.201503935

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

12 in total

1. Hemilabile Proton Relays and Redox Activity Lead to {FeNO} ^x and Significant Rate Enhancements in NO₂^- Reduction.

Authors: Pui Man Cheung; Kyle T Burns; Yubin M Kwon; Megan Y Deshaye; Kristopher J Aguayo; Victoria F Oswald; Takele Seda; Lev N Zakharov; Tim Kowalczyk; John D Gilbertson
Journal: J Am Chem Soc Date: 2018-11-30 Impact factor: 15.419

2. Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand.

Authors: Kate A Jesse; Mu-Chieh Chang; Alexander S Filatov; John S Anderson
Journal: Z Anorg Allg Chem Date: 2021-05-27 Impact factor: 1.414

3. Catalytic hydrogenation enabled by ligand-based storage of hydrogen.

Authors: Andrew J McNeece; Kate A Jesse; Alexander S Filatov; Joseph E Schneider; John S Anderson
Journal: Chem Commun (Camb) Date: 2021-03-17 Impact factor: 6.222

4. Reactivity of Two-Electron-Reduced Boron Formazanate Compounds with Electrophiles: Facile N-H/N-C Bond Homolysis Due to the Formation of Stable Ligand Radicals.

Authors: Ranajit Mondol; Edwin Otten
Journal: Inorg Chem Date: 2018-02-15 Impact factor: 5.165

9. Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction.

Authors: Yongzhen Han; Huayi Fang; Huize Jing; Huiling Sun; Haitao Lei; Wenzhen Lai; Rui Cao
Journal: Angew Chem Int Ed Engl Date: 2016-03-30 Impact factor: 15.336

10. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.

Authors: Jarl Ivar van der Vlugt
Journal: Chemistry Date: 2018-11-26 Impact factor: 5.236

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer.

1. Hemilabile Proton Relays and Redox Activity Lead to {FeNO} ^x and Significant Rate Enhancements in NO₂^- Reduction.

2. Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand.

3. Catalytic hydrogenation enabled by ligand-based storage of hydrogen.

4. Reactivity of Two-Electron-Reduced Boron Formazanate Compounds with Electrophiles: Facile N-H/N-C Bond Homolysis Due to the Formation of Stable Ligand Radicals.

5. Unraveling the catalytic mechanisms of H₂ production with thiosemicarbazone nickel complexes.

6. Proton reduction by a bimetallic zinc selenolate electrocatalyst.

7. Charge-State Dependence of Proton Uptake in Polyoxovanadate-alkoxide Clusters.

8. Controlling Chemoselectivity of Catalytic Hydroboration with Light.

9. Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen-Evolution Reaction.

10. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.