Literature DB >> 26237275

Beyond the Butterfly: Sc2C2@C(2v)(9)-C86, an Endohedral Fullerene Containing a Planar, Twisted Sc2C2 Unit with Remarkable Crystalline Order in an Unprecedented Carbon Cage.

Chia-Hsiang Chen1, Kamran B Ghiassi2, Maira R Cerón1, Miguel A Guerrero-Ayala1, Luis Echegoyen1, Marilyn M Olmstead2, Alan L Balch2.   

Abstract

The synthesis, isolation, and characterization of a new endohedral fullerene, Sc2C88, is reported. Characterization by single crystal X-ray diffraction revealed that it is the carbide Sc2C2@C(2v)(9)-C86 with a planar, twisted Sc2C2 unit inside a previously unseen C(2v)(9)-C86 fullerene cage.

Entities:  

Year:  2015        PMID： 26237275     DOI： 10.1021/jacs.5b06425

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Redox-active metal-metal bonds between lanthanides in dimetallofullerenes.

Authors:  Alexey A Popov
Journal:  Curr Opin Electrochem       Date:  2017-12-18

2.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236
  2 in total

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