Literature DB >> 30079381

Redox-active metal-metal bonds between lanthanides in dimetallofullerenes.

Alexey A Popov1.   

Abstract

The empty space inside a fullerene cage can be filled with a variety of species, including metal dimers. Encapsulation of Sc2, Y2, or lanthanide dimers leads to dimetallofullerenes featuring metal-metal bonding molecular orbital. Such an orbital can be either HOMO or LUMO of the dimetallofullerene molecule. In certain cases, single-occupied metal-metal bonding orbital can be also stabilized. This review is focused on redox processes involving variation of the electron population of metal-metal bonding orbitals in dimetallofullerenes.

Entities:  

Year:  2017        PMID： 30079381      PMCID： PMC6071841          DOI： 10.1016/j.coelec.2017.12.003

Source DB:  PubMed          Journal:  Curr Opin Electrochem        ISSN： 2451-9103


  33 in total

1.  Crystallographic characterization of isomer 2 of Er2@C82 and comparison with isomer 1 of Er2@C82.

Authors:  Marilyn M Olmstead; Hon Man Lee; Steve Stevenson; Harry C Dorn; Alan L Balch
Journal:  Chem Commun (Camb)       Date:  2002-11-21       Impact factor: 6.222

2.  Bonding between strongly repulsive metal atoms: an oxymoron made real in a confined space of endohedral metallofullerenes.

Authors:  Alexey A Popov; Stas M Avdoshenko; Angel Martín Pendás; Lothar Dunsch
Journal:  Chem Commun (Camb)       Date:  2012-07-06       Impact factor: 6.222

3.  General rule for the stabilization of fullerene cages encapsulating trimetallic nitride templates.

Authors:  Josep M Campanera; Carles Bo; Josep M Poblet
Journal:  Angew Chem Int Ed Engl       Date:  2005-11-11       Impact factor: 15.336

4.  Location of the metal atoms in Ce2@C78 and its bis-silylated derivative.

Authors:  Michio Yamada; Takatsugu Wakahara; Takahiro Tsuchiya; Yutaka Maeda; Masahiro Kako; Takeshi Akasaka; Kenji Yoza; Ernst Horn; Naomi Mizorogi; Shigeru Nagase
Journal:  Chem Commun (Camb)       Date:  2007-10-26       Impact factor: 6.222

5.  Very large, soluble endohedral fullerenes in the series La2C90 to La2C138: isolation and crystallographic characterization of La2@D5(450)-C100.

Authors:  Christine M Beavers; Hongxiao Jin; Hua Yang; Zhimin Wang; Xinqing Wang; Hongliang Ge; Ziyang Liu; Brandon Q Mercado; Marilyn M Olmstead; Alan L Balch
Journal:  J Am Chem Soc       Date:  2011-09-08       Impact factor: 15.419

6.  Endohedral metallofullerenes: a unique host-guest association.

Authors:  Antonio Rodríguez-Fortea; Alan L Balch; Josep M Poblet
Journal:  Chem Soc Rev       Date:  2011-04-19       Impact factor: 54.564

7.  Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene.

Authors:  Fupin Liu; Denis S Krylov; Lukas Spree; Stanislav M Avdoshenko; Nataliya A Samoylova; Marco Rosenkranz; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Bernd Büchner; Alexey A Popov
Journal:  Nat Commun       Date:  2017-07-14       Impact factor: 14.919

Review 8.  Current status and future developments of endohedral metallofullerenes.

Authors:  Xing Lu; Lai Feng; Takeshi Akasaka; Shigeru Nagase
Journal:  Chem Soc Rev       Date:  2012-12-07       Impact factor: 54.564

9.  Isolation, characterization, and theoretical study of La2@C78.

Authors:  Baopeng Cao; Takatsugu Wakahara; Takahiro Tsuchiya; Masahiro Kondo; Yutaka Maeda; G M Aminur Rahman; Takeshi Akasaka; Kaoru Kobayashi; Shigeru Nagase; Kazunori Yamamoto
Journal:  J Am Chem Soc       Date:  2004-08-04       Impact factor: 15.419

10.  Selective arc-discharge synthesis of Dy2S-clusterfullerenes and their isomer-dependent single molecule magnetism.

Authors:  Chia-Hsiang Chen; Denis S Krylov; Stanislav M Avdoshenko; Fupin Liu; Lukas Spree; Ravi Yadav; Antonis Alvertis; Liviu Hozoi; Konstantin Nenkov; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Alexey A Popov
Journal:  Chem Sci       Date:  2017-06-30       Impact factor: 9.825
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  3 in total

1.  Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond.

Authors:  Fupin Liu; Georgios Velkos; Denis S Krylov; Lukas Spree; Michal Zalibera; Rajyavardhan Ray; Nataliya A Samoylova; Chia-Hsiang Chen; Marco Rosenkranz; Sandra Schiemenz; Frank Ziegs; Konstantin Nenkov; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Manuel Richter; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov
Journal:  Nat Commun       Date:  2019-02-04       Impact factor: 14.919

2.  Recent advances in single molecule magnetism of dysprosium-metallofullerenes.

Authors:  Lukas Spree; Alexey A Popov
Journal:  Dalton Trans       Date:  2019-02-26       Impact factor: 4.390

3.  Single-Electron Lanthanide-Lanthanide Bonds Inside Fullerenes toward Robust Redox-Active Molecular Magnets.

Authors:  Fupin Liu; Lukas Spree; Denis S Krylov; Georgios Velkos; Stanislav M Avdoshenko; Alexey A Popov
Journal:  Acc Chem Res       Date:  2019-10-01       Impact factor: 22.384
  3 in total

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