Literature DB >> 26166879

An efficient synthesis of novel sucrose-containing dilactams.

Mykhaylo A Potopnyk1, Sławomir Jarosz1.   

Abstract

ABSTRACT: An efficient and convenient approach to sucrose-containing dilactams has been developed. The method, based on reaction of regioisomeric 6,6'-di-O-[(aminomethyl)-phenyl]-1',2,3,3',4,4'-hexa-O-methylsucrose with isophtaloyl or 2,6-pyridinedicarbonyl dichlorides, provided the 1:1-macrocycles in good yields. GRAPHICAL ABSTRACT: .

Entities:  

Keywords:  Alkylation; Carbohydrates; Cyclization; Macrocycles; Reductions

Year:  2013        PMID: 26166879      PMCID: PMC4495044          DOI: 10.1007/s00706-012-0894-2

Source DB:  PubMed          Journal:  Monatsh Chem        ISSN: 0026-9247            Impact factor:   1.451


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