Literature DB >> 26166860

Reversible photochromism of polynorbornenes bearing spiropyran side groups.

Lucas Hauser1, Astrid-Caroline Knall1, Meinhart Roth1, Gregor Trimmel1, Matthias Edler2, Thomas Griesser2, Wolfgang Kern2.   

Abstract

ABSTRACT: In this paper, the synthesis aclass="Disease">nd characterization of <class="Chemical">span class="Chemical">poly(norbornene) homo- and copolymers bearing spiropyran side groups are described. Difficulties in the homopolymerization of spiropyrans due to the opened merocyanine form were observed leading to low polymerization yields for homopolymers while copolymers with 10 mol% spiropyran content were prepared in good yield. Spiropyrans are characterized by their reversible photochromism, which was conserved in the polymers as shown by UV-Vis spectroscopy and FT-IR spectroscopy. The switching between the apolar spiropyran form and the zwitterionic merocyanine form also leads to switchable wettability as evidenced by contact angle measurements.

Entities:  

Keywords:  Photochemistry; Photolithography; Ring-opening metathesis polymerization; Spiro compounds

Year:  2012        PMID： 26166860      PMCID： PMC4495054          DOI： 10.1007/s00706-012-0827-0

Source DB:  PubMed          Journal:  Monatsh Chem        ISSN： 0026-9247            Impact factor:   1.451


  15 in total

1.  Spiropyrans and Spirooxazines for Memories and Switches.

Authors:  Garry Berkovic; Valeri Krongauz; Victor Weiss
Journal:  Chem Rev       Date:  2000-05-10       Impact factor: 60.622

2.  Light-controlled molecular switches modulate nanocrystal fluorescence.

Authors:  Linyong Zhu; Ming-Qiang Zhu; James K Hurst; Alexander D Q Li
Journal:  J Am Chem Soc       Date:  2005-06-29       Impact factor: 15.419

3.  Light-induced reversible formation of polymeric micelles.

Authors:  Hyung-Il Lee; Wei Wu; Jung Kwon Oh; Laura Mueller; Gizelle Sherwood; Linda Peteanu; Tomasz Kowalewski; Krzysztof Matyjaszewski
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

4.  Merocyanine solvatochromic dyes in the study of synergistic effects in mixtures of chloroform with hydrogen-bond accepting solvents.

Authors:  Fabíola M Testoni; Eduardo A Ribeiro; Luciano A Giusti; Vanderlei G Machado
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2008-07-03       Impact factor: 4.098

5.  Photoswitched DNA-binding of a photochromic spiropyran.

Authors:  Johanna Andersson; Shiming Li; Per Lincoln; Joakim Andréasson
Journal:  J Am Chem Soc       Date:  2008-08-13       Impact factor: 15.419

6.  Two-photon three-dimensional optical storage memory.

Authors:  A S Dvornikov; E P Walker; P M Rentzepis
Journal:  J Phys Chem A       Date:  2009-12-10       Impact factor: 2.781

7.  Spiropyran-based photochromic polymer nanoparticles with optically switchable luminescence.

Authors:  Ming-Qiang Zhu; Linyong Zhu; Jason J Han; Wuwei Wu; James K Hurst; Alexander D Q Li
Journal:  J Am Chem Soc       Date:  2006-04-05       Impact factor: 15.419

8.  Reversible colorimetric ion sensors based on surface initiated polymerization of photochromic polymers.

Authors:  Kristen Fries; Satyabrata Samanta; Sara Orski; Jason Locklin
Journal:  Chem Commun (Camb)       Date:  2008-11-04       Impact factor: 6.222

9.  Photon-modulated changes of cell attachments on poly(spiropyran-co-methyl methacrylate) membranes.

Authors:  Akon Higuchi; Ayu Hamamura; Yosuke Shindo; Hanako Kitamura; Boo Ok Yoon; Taisuke Mori; Taro Uyama; Akihiro Umezawa
Journal:  Biomacromolecules       Date:  2004 Sep-Oct       Impact factor: 6.988

10.  Formation of photochromic spiropyran polymer brushes via surface-initiated, ring-opening metathesis polymerization: reversible photocontrol of wetting behavior and solvent dependent morphology changes.

Authors:  Satyabrata Samanta; Jason Locklin
Journal:  Langmuir       Date:  2008-07-19       Impact factor: 3.882
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  2 in total

1.  Ex situ and in situ characterization of patterned photoreactive thin organic surface layers using friction force microscopy.

Authors:  Quan Shen; Matthias Edler; Thomas Griesser; Astrid-Caroline Knall; Gregor Trimmel; Wolfgang Kern; Christian Teichert
Journal:  Scanning       Date:  2014-09-02       Impact factor: 1.932

2.  Synthesis and characterization of naphthalimide-functionalized polynorbornenes.

Authors:  Manuel Hollauf; Merima Cajlakovič; Martin Tscherner; Stefan Köstler; Astrid-Caroline Knall; Gregor Trimmel
Journal:  Monatsh Chem       Date:  2016-12-21       Impact factor: 1.451
  2 in total

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