| Literature DB >> 26029406 |
Peter Mangwala Kimpende1, Ngoc Thanh Nguyen2, Minh Thao Nguyen3, Quoc Trung Vu4, Luc Van Meervelt5.
Abstract
In the title compound, C20H17NO5, the dihedral angle between the mean plane of the di-hydro-quinoline ring system (r.m.s. deviation = 0.003 Å) and the benzene ring is 1.83 (11)°. The almost planar conformation is a consequence of an intra-molecular O-H⋯O hydrogen bond and the E configuration about the central C=C bond. In the crystal structure, O-H⋯O hydrogen bonds generate chains of mol-ecules along the [10-1] direction. These chains are linked via π-π inter-actions [inter-centroid distances are in the range 3.6410 (16)-3.8663 (17) Å].Entities:
Keywords: 4-hydroxy-1,2-dihydroquinolin-2(1H)-one; crystal structure; hydrogen bonding; α,β-unsaturated ketones; π–π interactions
Year: 2015 PMID: 26029406 PMCID: PMC4438805 DOI: 10.1107/S2056989015005630
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun