Literature DB >> 25976100

Equilibrium phase diagram of a randomly pinned glass-former.

Misaki Ozawa1, Walter Kob2, Atsushi Ikeda3, Kunimasa Miyazaki4.   

Abstract

We use computer simulations to study the thermodynamic properties of a glass-former in which a fraction c of the particles has been permanently frozen. By thermodynamic integration, we determine the Kauzmann, or ideal glass transition, temperature [Formula: see text] at which the configurational entropy vanishes. This is done without resorting to any kind of extrapolation, i.e., [Formula: see text] is indeed an equilibrium property of the system. We also measure the distribution function of the overlap, i.e., the order parameter that signals the glass state. We find that the transition line obtained from the overlap coincides with that obtained from the thermodynamic integration, thus showing that the two approaches give the same transition line. Finally, we determine the geometrical properties of the potential energy landscape, notably the T- and c dependence of the saddle index, and use these properties to obtain the dynamic transition temperature [Formula: see text]. The two temperatures [Formula: see text] and [Formula: see text] cross at a finite value of c and indicate the point at which the glass transition line ends. These findings are qualitatively consistent with the scenario proposed by the random first-order transition theory.

Keywords:  Kauzmann temperature; computer simulations; configurational entropy; ideal glass transition; random first-order transition theory

Year:  2015        PMID: 25976100      PMCID: PMC4460508          DOI: 10.1073/pnas.1500730112

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  21 in total

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Authors:  K Broderix; K K Bhattacharya; A Cavagna; A Zippelius; I Giardina
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2.  Mean-field theory, mode-coupling theory, and the onset temperature in supercooled liquids.

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Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2004-04-29

3.  Static point-to-set correlations in glass-forming liquids.

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Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2012-01-03

4.  Mode-coupling theory as a mean-field description of the glass transition.

Authors:  Atsushi Ikeda; Kunimasa Miyazaki
Journal:  Phys Rev Lett       Date:  2010-06-25       Impact factor: 9.161

5.  Scaling concepts for the dynamics of viscous liquids near an ideal glassy state.

Authors: 
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6.  Roles of bond orientational ordering in glass transition and crystallization.

Authors:  Hajime Tanaka
Journal:  J Phys Condens Matter       Date:  2011-06-27       Impact factor: 2.333

7.  Slow dynamics, dynamic heterogeneities, and fragility of supercooled liquids confined in random media.

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Journal:  J Phys Condens Matter       Date:  2011-05-25       Impact factor: 2.333

8.  Critical dynamical heterogeneities close to continuous second-order glass transitions.

Authors:  Saroj Kumar Nandi; Giulio Biroli; Jean-Philippe Bouchaud; Kunimasa Miyazaki; David R Reichman
Journal:  Phys Rev Lett       Date:  2014-12-09       Impact factor: 9.161

9.  Novel approach to numerical measurements of the configurational entropy in supercooled liquids.

Authors:  Ludovic Berthier; Daniele Coslovich
Journal:  Proc Natl Acad Sci U S A       Date:  2014-07-28       Impact factor: 11.205

10.  Random-field-like criticality in glass-forming liquids.

Authors:  Giulio Biroli; Chiara Cammarota; Gilles Tarjus; Marco Tarzia
Journal:  Phys Rev Lett       Date:  2014-04-30       Impact factor: 9.161

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  6 in total

1.  Vanishing of configurational entropy may not imply an ideal glass transition in randomly pinned liquids.

Authors:  Saurish Chakrabarty; Smarajit Karmakar; Chandan Dasgupta
Journal:  Proc Natl Acad Sci U S A       Date:  2015-08-17       Impact factor: 11.205

2.  Reply to Chakrabarty et al.: Particles move even in ideal glasses.

Authors:  Misaki Ozawa; Walter Kob; Atsushi Ikeda; Kunimasa Miyazaki
Journal:  Proc Natl Acad Sci U S A       Date:  2015-08-17       Impact factor: 11.205

3.  Probing the non-Debye low-frequency excitations in glasses through random pinning.

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Journal:  Proc Natl Acad Sci U S A       Date:  2018-08-13       Impact factor: 11.205

4.  A topologically driven glass in ring polymers.

Authors:  Davide Michieletto; Matthew S Turner
Journal:  Proc Natl Acad Sci U S A       Date:  2016-04-26       Impact factor: 11.205

5.  Dynamics of Glass Forming Liquids with Randomly Pinned Particles.

Authors:  Saurish Chakrabarty; Smarajit Karmakar; Chandan Dasgupta
Journal:  Sci Rep       Date:  2015-07-24       Impact factor: 4.379

6.  Measurements of growing surface tension of amorphous-amorphous interfaces on approaching the colloidal glass transition.

Authors:  Divya Ganapathi; K Hima Nagamanasa; A K Sood; Rajesh Ganapathy
Journal:  Nat Commun       Date:  2018-01-26       Impact factor: 14.919

  6 in total

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