A column evaluation of Appalachian coal mine spoils' temporal leaching behavior.

Appalachian surface coal mine overburden affects water quality as drainage percolates through spoil disposal fills. This study evaluated leaching potentials of 15 spoils from south-central Appalachia. Most bulk samples were non acid-forming, all were low in total-S, (≤0.34%), and initial saturated paste specific conductance (SC) ranged from 264 to 3560 μS cm(-1). Samples were leached unsaturated (40 cycles) and leachates analyzed for pH, SC, and ion composition. Overall, leachates from unweathered spoils were higher in pH and SC than leachates from weathered spoils. Fine-textured spoils generally produced higher SCs than more coarsely textured spoils. Mean SC for all spoils decreased rapidly from an initial peak of 1468 μS cm(-1) (±150) to 247 μS cm(-1) (±23). Release patterns for most major ions reflected declining SC. Bicarbonate typically increased with successive leaches, replacing sulfate as the dominant anion. Column SC values were comparable to relevant published field data.