| Literature DB >> 25910509 |
Yu Jin Park1, Ji Yeon Ryu1, Halima Begum1, Min Hyung Lee2, Peter J Stang3, Junseong Lee1.
Abstract
Stoichiometric control of Ru, Ag, and tetrazolyl ligands resulted in the formation of different heterometallic Ru-Ag supramolecular architectures. Although the reaction of Ru and 5-(2-hydroxyphenyl)-1H-tetrazolyl (LH2) in a molar ratio of 2:1 or 6:4 resulted in the formation of dimeric or hexameric Ru complexes, Ag metal ions caused the Ru complexes to form three-dimensional cylindrical Ru6Ag6L6 and double-cone-shaped Ru6Ag8L6 complexes by occupying vacant coordination sites.Entities:
Year: 2015 PMID: 25910509 DOI: 10.1021/jacs.5b01253
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419