Literature DB >> 25891820

Plausible mechanisms of the fenton-like reactions, M = Fe(II) and Co(II), in the presence of RCO2(-) substrates: are OH(•) radicals formed in the process?

Haya Kornweitz1, Ariela Burg2, Dan Meyerstein1,3.   

Abstract

DFT calculations concerning the plausible mechanism of Fenton-like reactions catalyzed by Fe(II) and Co(II) cations in the presence of carboxylate ligands suggest that hydroxyl radicals are not formed in these reactions. This conclusion suggests that the commonly accepted mechanisms of Fenton-like reactions induced oxidative stress and advanced oxidation processes have to be reconsidered.

Entities:  

Year:  2015        PMID： 25891820     DOI： 10.1021/jp512826f

Source DB:  PubMed          Journal:  J Phys Chem A        ISSN： 1089-5639            Impact factor:   2.781


  5 in total

Review 1.  Proteolysis and Oxidation of Therapeutic Proteins After Intradermal or Subcutaneous Administration.

Authors:  Ninad Varkhede; Rupesh Bommana; Christian Schöneich; M Laird Forrest
Journal:  J Pharm Sci       Date:  2019-08-10       Impact factor: 3.534

2.  Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

Authors:  Steven W M Crossley; Carla Obradors; Ruben M Martinez; Ryan A Shenvi
Journal:  Chem Rev       Date:  2016-07-27       Impact factor: 60.622

Review 3.  What Are the Oxidizing Intermediates in the Fenton and Fenton-like Reactions? A Perspective.

Authors:  Dan Meyerstein
Journal:  Antioxidants (Basel)       Date:  2022-07-14

4.  Oxidation of Cr(III)-Fe(III) Mixed-Phase Hydroxides by Chlorine: Implications on the Control of Hexavalent Chromium in Drinking Water.

Authors:  Michelle Chebeir; Haizhou Liu
Journal:  Environ Sci Technol       Date:  2018-07-06       Impact factor: 9.028

5.  The Role of Carbonate in Catalytic Oxidations.

Authors:  Shanti Gopal Patra; Amir Mizrahi; Dan Meyerstein
Journal:  Acc Chem Res       Date:  2020-09-25       Impact factor: 22.384
  5 in total

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