| Literature DB >> 25891167 |
Sergio Sanz1, Helen M O'Connor1, Eufemio Moreno Pineda2, Kasper S Pedersen3, Gary S Nichol1, Ole Mønsted3, Høgni Weihe3, Stergios Piligkos4, Eric J L McInnes5, Paul J Lusby6, Euan K Brechin7.
Abstract
[Cr(III)8M(II)6](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a "naked" M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.Entities:
Keywords: EPR spectroscopy; heterometallic cages; magnetometry; molecular magnetism; transition metals
Year: 2015 PMID: 25891167 PMCID: PMC4471575 DOI: 10.1002/anie.201501041
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336