Literature DB >> 25891167

[Cr(III)8M(II)6](12+) Coordination Cubes (M(II)=Cu, Co).

Sergio Sanz1, Helen M O'Connor1, Eufemio Moreno Pineda2, Kasper S Pedersen3, Gary S Nichol1, Ole Mønsted3, Høgni Weihe3, Stergios Piligkos4, Eric J L McInnes5, Paul J Lusby6, Euan K Brechin7.   

Abstract

[Cr(III)8M(II)6](12+) (M(II) =Cu, Co) coordination cubes were constructed from a simple [Cr(III) L3 ] metalloligand and a "naked" M(II) salt. The flexibility in the design proffers the potential to tune the physical properties, as all the constituent parts of the cage can be changed without structural alteration. Computational techniques (known in theoretical nuclear physics as statistical spectroscopy) in tandem with EPR spectroscopy are used to interpret the magnetic behavior.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  EPR spectroscopy; heterometallic cages; magnetometry; molecular magnetism; transition metals

Year:  2015        PMID: 25891167      PMCID: PMC4471575          DOI: 10.1002/anie.201501041

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  19 in total

1.  Cage-catalyzed Knoevenagel condensation under neutral conditions in water.

Authors:  Takashi Murase; Yuki Nishijima; Makoto Fujita
Journal:  J Am Chem Soc       Date:  2011-12-12       Impact factor: 15.419

2.  Integrative self-sorting synthesis of a Fe8Pt6L24 cubic cage.

Authors:  Maarten M J Smulders; Azucena Jiménez; Jonathan R Nitschke
Journal:  Angew Chem Int Ed Engl       Date:  2012-06-05       Impact factor: 15.336

3.  EasySpin, a comprehensive software package for spectral simulation and analysis in EPR.

Authors:  Stefan Stoll; Arthur Schweiger
Journal:  J Magn Reson       Date:  2005-09-26       Impact factor: 2.229

4.  Design of magnetic coordination complexes for quantum computing.

Authors:  Guillem Aromí; David Aguilà; Patrick Gamez; Fernando Luis; Olivier Roubeau
Journal:  Chem Soc Rev       Date:  2011-08-04       Impact factor: 54.564

5.  Physical studies of heterometallic rings: an ideal system for studying magnetically-coupled systems.

Authors:  Grigore A Timco; Eric J L McInnes; Richard E P Winpenny
Journal:  Chem Soc Rev       Date:  2012-09-18       Impact factor: 54.564

6.  Strong spin-phonon coupling between a single-molecule magnet and a carbon nanotube nanoelectromechanical system.

Authors:  Marc Ganzhorn; Svetlana Klyatskaya; Mario Ruben; Wolfgang Wernsdorfer
Journal:  Nat Nanotechnol       Date:  2013-02-03       Impact factor: 39.213

7.  Electrically driven nuclear spin resonance in single-molecule magnets.

Authors:  Stefan Thiele; Franck Balestro; Rafik Ballou; Svetlana Klyatskaya; Mario Ruben; Wolfgang Wernsdorfer
Journal:  Science       Date:  2014-06-06       Impact factor: 47.728

8.  Self-assembly of an imidazolate-bridged Fe(III)/Cu(II) heterometallic cage.

Authors:  Florian Reichel; Jack K Clegg; Karsten Gloe; Kerstin Gloe; Jan J Weigand; Jason K Reynolds; Chun-Guang Li; Janice R Aldrich-Wright; Cameron J Kepert; Leonard F Lindoy; Hong-Chang Yao; Feng Li
Journal:  Inorg Chem       Date:  2014-01-07       Impact factor: 5.165

9.  3V: cavity, channel and cleft volume calculator and extractor.

Authors:  Neil R Voss; Mark Gerstein
Journal:  Nucleic Acids Res       Date:  2010-05-16       Impact factor: 16.971

10.  Spin qubits with electrically gated polyoxometalate molecules.

Authors:  Jörg Lehmann; Alejandro Gaita-Arino; Eugenio Coronado; Daniel Loss
Journal:  Nat Nanotechnol       Date:  2007-05       Impact factor: 39.213

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  3 in total

1.  Incorporation of a Phosphino(pyridine) Subcomponent Enables the Formation of Cages with Homobimetallic and Heterobimetallic Vertices.

Authors:  John P Carpenter; Tanya K Ronson; Felix J Rizzuto; Théophile Héliot; Peter Grice; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2022-05-05       Impact factor: 16.383

2.  [CrIII8NiII6]n+ Heterometallic Coordination Cubes.

Authors:  Helen M O'Connor; Sergio Sanz; Aaron J Scott; Mateusz B Pitak; Wim T Klooster; Simon J Coles; Nicholas F Chilton; Eric J L McInnes; Paul J Lusby; Høgni Weihe; Stergios Piligkos; Euan K Brechin
Journal:  Molecules       Date:  2021-02-02       Impact factor: 4.411

3.  [MIII2MII3] n+ trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands.

Authors:  S Sanz; H M O'Connor; V Martí-Centelles; P Comar; M B Pitak; S J Coles; G Lorusso; E Palacios; M Evangelisti; A Baldansuren; N F Chilton; H Weihe; E J L McInnes; P J Lusby; S Piligkos; E K Brechin
Journal:  Chem Sci       Date:  2017-05-19       Impact factor: 9.825

  3 in total

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