| Literature DB >> 24393071 |
Florian Reichel1, Jack K Clegg, Karsten Gloe, Kerstin Gloe, Jan J Weigand, Jason K Reynolds, Chun-Guang Li, Janice R Aldrich-Wright, Cameron J Kepert, Leonard F Lindoy, Hong-Chang Yao, Feng Li.
Abstract
A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12·χsolvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl}amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.Entities:
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Year: 2014 PMID： 24393071 DOI： 10.1021/ic402686s
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165