| Literature DB >> 25848654 |
Brian J Smith1, Nicky Hwang, Anton D Chavez, Jennifer L Novotney, William R Dichtel.
Abstract
We examine the growth rates, activation energies, and hydrolytic stability of multiple 2D boronate ester covalent organic frameworks by turbidity measurements, observing a 200-fold range in stability. The rate-determining step in boronate ester 2D COF growth is not in-solution condensation, but rather interlayer polymer stacking through a nucleation-elongation process.Entities:
Year: 2015 PMID: 25848654 DOI: 10.1039/c5cc00379b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222