| Literature DB >> 25847222 |
Emmanuel Nicolas1, Alexia Ohleier, Florian D'Accriscio, Anne-Frédérique Pécharman, Matthieu Demange, Philippe Ribagnac, Jorge Ballester, Corinne Gosmini, Nicolas Mézailles.
Abstract
The use of a strongly donating "(bis-dialkylphosphine)Ni" fragment promotes the catalytic coupling of a large range of ArCl and ArZnCl derivatives under mild conditions. Stoichiometric mechanistic investigations and DFT calculations prove that a Ni(0) /Ni(II) cycle is operative in this system.Entities:
Keywords: Negishi coupling; Ni catalysis; cross-coupling; dft; diphosphine ligands; mechanistic study
Year: 2015 PMID： 25847222 DOI： 10.1002/chem.201500192
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236