Crystal structure of hepta-guanidinium nona-hydrogen bis-[α-hexa-molybdoplatinate(IV)] hepta-hydrate.

The title compound, (CH6N3)7H9[PtMo6O24]2·7H2O, containing the well-known Anderson-type heteropolyoxomolybdate, was obtained by recrystallization of its powdered guanidinium salt. The protonated O atoms in the polyanion were confirmed by electron-density maps, inter-polyanion hydrogen bonds and bond-valance sums (BVS). The {[H4.5PtMo6O24]2}(7-) polyanion is the same as that already characterized in K7[H4.5PtMo6O24]2·11H2O [space group P-1; Lee & Joo (2010 ▶). Acta Cryst. E66, i8-i9]. The heteropolyanions form inversion-generated dimers, {[H4.5PtMo6O24]2}(7-), held together by each of the four μ3-O-H⋯μ1-O, two μ2-O-H⋯μ2-O hydrogen bonds and one centrosymmetric μ3-O-H-μ3-O hydrogen bond. The H atom of the centrosymmetric hydrogen bond is located on an inversion centre. One guanidinium ion and one water mol-ecule are equally disordered about a twofold rotation axis.

Chemical context

The α (planar structure)-β (bent structure)-α geometrical isomerization, according to stepwise protonation in the [PtMo6O24]8− polyoxometalate (POM) species, viz. ([H3.5 α-PtMo6O24]4.5− (Lee & Sasaki, 1994 ▸), [H4 β-PtMo6O24]4− (Lee & Sasaki, 1994 ▸; Joo et al., 1994 ▸) and [H4.5 α-PtMo6O24]3.5− (Lee & Sasaki, 1994 ▸; Lee et al., 2010 ▸) is an unprecedented phenomenon in the Anderson-type heteropolyanion (Anderson, 1937 ▸), as well as in the chemistry of polyoxo­metalates.

As a result of the insolubility of the guanidinium salt, replaceable counter-cations in POMs can be exchanged by guanidinium ions. It is thus possible to obtain stable POMs by precipitation from aqueous solution with guanidinium salts. The guanidinium salts of platinum-containing POM species, viz. (CH6N3)8[PtW6O24] (Lee et al., 2003 ▸ ▸), (CH6N3)5[H2PtV9O28] (Joo et al., 2011 ▸) and (CH6N3)8[α-SiPt2W10O40]·6H2O (Lee et al., 2003 ▸ ▸) have been reported by our group. The positions of the protonated O atoms in the {[H4.5α-PtMo6O24]2}7− polyanion were reconfirmed in the present study.

Sometimes a short hydrogen bond, O⋯O distance < 2.60 Å, in which the H atom lies on a crystallographic center of symmetry, occurs in this class of structure. The H atom of the central hydrogen bond, O6C—H6—O6C i in the title compound lies on a crystallographic center of symmetry (space group C2/c: , , ).

Structural commentary

The structure of the title compound POM anion has been discussed in detail (Lee et al., 2010 ▸). Fig. 1 ▸ shows the structure of the title compound, and selected geometrical parameters are given in Table 1 ▸. The complete polyanion has C 1 (1) symmetry. The O atoms of the heteropolyanion have been designated as OT (terminal Mo=O atom), OB (bridging μ2-O atom), and OC (centered μ3-O atom). The protonated O atoms in the polyanion were confirmed in electron density maps, inter­polyanion hydrogen bonds (Table 2 ▸) and by bond-valence sums (BVS; Brown & Altermatt, 1985 ▸; Brese & O’Keeffe, 1991 ▸). Fig. 2 ▸ shows a symmetric electron-density map around the position of atom H6. The H atom of the centrosymmetric hydrogen bond in the compound lies on a crystallographic centre of symmetry (space group C2/c: , , ). The O6C—H6 and O6C⋯O6C i distances are 1.27 and 2.532 (6) Å, and the O6C—H6—O6C i angle is 180° (Table 2 ▸ and Fig. 3 ▸). Atom H3 does not contribute to dimer formation because it is located on the other side of the polyanion.

Figure 1

The mol­ecular structure of the title compound, showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. H atoms are presented as small spheres of arbitrary radius. Disordered parts have been omitted for clarity.

Table 1

Selected geometric parameters (, )

Pt1O1C	1.995(3)	Mo5O5C	2.178(3)
Pt1O2C	2.015(3)	Mo6O5C	2.123(3)
Pt1O3C	2.027(3)	Mo6O6C	2.277(3)
Pt1O4C	2.011(3)	Mo1O7B	1.965(3)
Pt1O5C	1.997(3)	Mo1O12B	1.959(3)
Pt1O6C	2.005(3)	Mo2O7B	1.978(3)
Mo1O1C	2.150(3)	Mo2O8B	1.945(3)
Mo1O6C	2.317(3)	Mo3O8B	1.934(3)
Mo2O1C	2.248(3)	Mo3O9B	1.952(3)
Mo2O2C	2.286(3)	Mo4O9B	1.941(3)
Mo3O2C	2.307(3)	Mo4O10B	1.959(3)
Mo3O3C	2.318(3)	Mo5O10B	1.895(3)
Mo4O3C	2.287(3)	Mo5O11B	2.058(3)
Mo4O4C	2.327(3)	Mo6O11B	2.075(4)
Mo5O4C	2.289(3)	Mo6O12B	1.894(4)
Mo1O1CMo2	95.79(12)	Mo1O7BMo2	111.71(15)
Mo2O2CMo3	93.64(11)	Mo3O8BMo2	119.36(16)
Mo4O3CMo3	93.75(12)	Mo4O9BMo3	119.39(17)
Mo5O4CMo4	92.64(11)	Mo5O10BMo4	120.02(16)
Mo6O5CMo5	102.87(13)	Mo5O11BMo6	108.97(15)
Mo6O6CMo1	91.14(12)	Mo6O12BMo1	116.75(17)

Table 2

Hydrogen-bond geometry (, )

DHA	DH	HA	D A	DHA
O2CH2O24T i	0.96(2)	1.61(2)	2.578(5)	179(6)
O3CH3O2W	0.96(2)	1.69(3)	2.622(6)	164(7)
O4CH4O13T i	0.95(2)	1.63(2)	2.568(5)	173(9)
O6CH6O6C i	1.27	1.27	2.532(6)	180
O11BH11O7B i	0.95(2)	1.74(2)	2.679(5)	173(10)
N1H1BO1C	0.88	2.05	2.864(6)	154
N1H1AO3W	0.88	2.33	2.973(9)	130
N2H2AO18T ii	0.88	2.08	2.940(7)	165
N2H2BO19T iii	0.88	2.22	3.043(6)	155
N3H3BO8B	0.88	2.04	2.874(7)	157
N3H3AO2W iii	0.88	2.25	2.979(9)	140
N4H4BO14T iv	0.88	2.09	2.944(6)	164
N4H4AO24T i	0.88	2.48	3.006(6)	119
N5H5AO16T	0.88	2.06	2.890(6)	157
N5H5BO21T v	0.88	2.18	2.973(5)	149
N6H6AO15T iv	0.88	2.19	2.894(6)	136
N6H6BO21T v	0.88	2.59	3.281(6)	136
N7H7BO19T	0.88	2.40	2.936(5)	119
N7H7AO1W	0.88	2.11	2.927(6)	154
N8H8BO13T vi	0.88	2.39	3.006(6)	128
N8H8AO23T vii	0.88	2.04	2.918(6)	178
N9H9AO22T vii	0.88	2.21	2.938(7)	140
O1WH1AWO9B	0.94(2)	2.20(5)	2.916(5)	132(5)
O1WH1BWO17T viii	0.95(2)	1.85(3)	2.783(5)	166(6)
O2WH2BWO4W ii	0.95(2)	2.24(7)	2.902(12)	126(6)
O3WH3BWO9B ii	0.94(2)	2.35(8)	3.029(7)	128(8)

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) ; (viii) .

Figure 2

Difference-Fourier map around atom H6 (calculated with atom H6 absent from the model).

Figure 3

Polyhedral view of the heteropolyanion in the title compound with O—H⋯O contacts of the inter­anion hydrogen bonds shown as red dashed lines. [Symmetry code: (i) −x + , −y + , −z + 1.]

Confirmation of the protonated O atoms was strongly supported by the BVS analysis. The calculated BVS for atoms O2C, O3C, O4C, O6C and O11B are 1.40, 1.36, 1.38, 1.41 and 1.30 valence units (v.u.), respectively, if the valence of the O—H bond is not included. Since the BVS value around the μ2-O atom should be 2.0 v.u., the missing valences of O2C, O3C, O4C, O6C and O11B are 0.60, 0.64, 0.62, 0.59 and 0.70 v.u., respectively, which corresponds to the valence of the O—H bonds. The BVS value range for the unprotonated OC and OB atoms is 1.68–1.90 v.u. As a result, the protonated O atoms were O2C, O3C, O4C, O11B and O6C. The protonated features of both the {[H4.5PtMo6O24]2}7− polyanion in the title compound and in K7[H4.5PtMo6O24]2.11H2O (space group P ) are exactly the same. The bond lengths and bond angles involving protonated and unprotonated O atoms in the {[H4.5PtMo6O24]2}7− polyanion are compared in Table 1 ▸. The Pt—OC bond lengths were not affected by protonation of the OC atoms.

The C4 guanidinium ion and O4W water mol­ecule are equally disordered about a twofold rotation axis.

Supra­molecular features

The heteropolyanions form inversion-generated dimers, {[H4.5PtMo6O24]2}7− held together by each of the four μ3-O—H⋯μ1-O (terminal O atom), two μ2-O—H⋯μ2-O and one centrosymmetric μ3-O—H—μ3-O hydrogen bonds (Table 2 ▸). Furthermore, the polyanions are linked in three dimensions via N—H⋯O hydrogen bonds. All water mol­ecules form hydrogen bonds with O atoms of the polyanions except for the O2W water mol­ecule (Table 2 ▸). Hydrogen-bonding interactions involving the disordered molecules have been omitted.

Database survey

A number of Anderson-structure platinum(IV)-containing heteropolyoxomolybdates have been reported: [H4.5PtMo6O24]3.5− and [H4PtMo6O24]4−, [H3.5PtMo6O24]4.5− (Lee & Sasaki, 1994 ▸); [H4β-PtM06024]4− (Joo et al., 1994 ▸); [H2PtMo6O24]6− (Lee & Joo, 2000 ▸, 2004 ▸); [H4.5PtMo6O24]3.5− (Lee et al., 2010 ▸); [H6PtMo6O24]2− (Lee & Joo, 2010 ▸); [H23(PtMo6O24)4]9−, [H16(PtMo6O24)3]8− and [H14(PtMo6O24)3]14− (Day et al., 2009 ▸).

Synthesis and crystallization

A pale-yellow powder of the title compound was obtained by addition of a small excess of the stoichiometric qu­antity of guanidinium chloride, CH6N3Cl, to a solution of the sodium salt of hexa­molybdoplatinate hydrate. Single crystals were obtained by recrystallization from a hot aqueous solution of the crude sample in an insulating chamber.

Refinement

Crystal data, data collection and structure refinement details are summarized in Table 3 ▸. All the H atoms in the polyanion and all water H atoms were positioned using difference Fourier maps. All H atoms of the polyanion were refined with a distance restraint of O—H = 0.95 (2) Å using the DFIX command (Sheldrick, 2008 ▸). All H atoms of the guanidinium ions were positioned geometrically and refined using a riding model, with U iso(H) = 1.5U eq(N). The C4 guanidinium ion and O4W water mol­ecule are equally disordered about a twofold rotation axis. Refinement of the site occupation factors (s.o.f) converged at values close to half occupancy. In the final refinement, the s.o.f.s were constrained to 0.5 and reasonable displacement parameters were obtained. The C—N and N—H bond lengths were restrained to 1.30 (2) and 0.90 (2) Å, respectively, and the HA—N—HB angles were restrained by restraining the HA⋯HB distance to 1.55 (2) Å in the disordered C4 guanidinium ion using the DFIX command. The H atoms of all water mol­ecules (OW) were refined with a distance restraint of O—H = 0.95 (2) Å using the DFIX, and were included in the refinement with U iso(H) = 1.5U eq(O). The highest peak in the difference map is 0.98 Å from atom Pt1 and the largest hole is 0.36 Å from N3.

Table 3

Experimental details

Crystal data
Chemical formula	(CH6N3)7H9[PtMo6O24]27H2O
M r	2865.26
Crystal system, space group	Monoclinic, C2/c
Temperature (K)	173
a, b, c ()	31.413(10), 10.073(3), 23.677(7)
()	119.451(14)
V (3)	6524(3)
Z	4
Radiation type	Mo K
(mm1)	6.62
Crystal size (mm)	0.30 0.12 0.05
Data collection
Diffractometer	Bruker SMART APEXII CCD
Absorption correction	Multi-scan (SADABS; Sheldrick, 2008 ▸)
T min, T max	0.241, 0.729
No. of measured, independent and observed [I > 2(I)] reflections	56606, 7107, 6050
R int	0.033
(sin /)max (1)	0.639
Refinement
R[F 2 > 2(F 2)], wR(F 2), S	0.028, 0.073, 1.03
No. of reflections	7107
No. of parameters	505
No. of restraints	22
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
max, min (e 3)	2.50, 1.30

Computer programs: APEX2 and SAINT (Bruker, 2009 ▸), SHELXS97 and SHELXL97 (Sheldrick, 2008 ▸), ORTEP-3 for Windows (Farrugia, 2012 ▸), PLATON (Spek, 2009 ▸) and DIAMOND (Brandenburg, 1998 ▸).

Crystal structure: contains datablock(s) New_Global_Publ_Block, I. DOI: 10.1107/S2056989015002601/pk2544sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015002601/pk2544Isup2.hkl

CCDC reference: 1048266

Additional supporting information: crystallographic information; 3D view; checkCIF report

(CH6N3)7H9[PtMo6O24]2·7H2O	F(000) = 5416
Mr = 2865.26	Dx = 2.917 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 9569 reflections
a = 31.413 (10) Å	θ = 2.2–28.2°
b = 10.073 (3) Å	µ = 6.62 mm−1
c = 23.677 (7) Å	T = 173 K
β = 119.451 (14)°	Block, yellow
V = 6524 (3) Å3	0.30 × 0.12 × 0.05 mm
Z = 4

Bruker SMART APEXII CCD diffractometer	7107 independent reflections
Radiation source: Rotating Anode	6050 reflections with I > 2σ(I)
Graphite multilayer monochromator	Rint = 0.033
Detector resolution: 10.0 pixels mm-1	θmax = 27.0°, θmin = 1.5°
φ and ω scans	h = −40→36
Absorption correction: multi-scan (SADABS; Sheldrick, 2008)	k = −12→12
Tmin = 0.241, Tmax = 0.729	l = −30→30
56606 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.028	Hydrogen site location: difference Fourier map
wR(F2) = 0.073	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ2(Fo2) + (0.0337P)2 + 47.9084P] where P = (Fo2 + 2Fc2)/3
7107 reflections	(Δ/σ)max = 0.002
505 parameters	Δρmax = 2.50 e Å−3
22 restraints	Δρmin = −1.30 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pt1	0.652431 (6)	0.176198 (17)	0.467608 (8)	0.01525 (6)
Mo1	0.743430 (14)	−0.00319 (4)	0.57409 (2)	0.02093 (10)
Mo2	0.682566 (15)	0.17866 (4)	0.624195 (19)	0.02035 (10)
Mo3	0.583929 (15)	0.34871 (4)	0.51759 (2)	0.02171 (10)
Mo4	0.552026 (14)	0.34729 (4)	0.359683 (19)	0.01849 (9)
Mo5	0.618484 (14)	0.17217 (4)	0.311229 (19)	0.01901 (10)
Mo6	0.712270 (14)	−0.01255 (4)	0.42001 (2)	0.02259 (10)
O1C	0.66821 (11)	0.0483 (3)	0.53959 (14)	0.0194 (7)
O2C	0.66214 (11)	0.3107 (3)	0.53597 (15)	0.0187 (7)
H2	0.6862 (17)	0.378 (5)	0.544 (3)	0.050 (18)*
O3C	0.58105 (11)	0.1962 (3)	0.44249 (15)	0.0178 (7)
H3	0.568 (2)	0.109 (3)	0.439 (3)	0.07 (2)*
O4C	0.63463 (11)	0.3099 (3)	0.39634 (15)	0.0184 (7)
H4	0.656 (3)	0.379 (6)	0.398 (4)	0.10 (3)*
O5C	0.64084 (11)	0.0488 (3)	0.39683 (14)	0.0191 (7)
O6C	0.72274 (11)	0.1511 (3)	0.49205 (15)	0.0190 (7)
H6	0.7500	0.2500	0.5000	0.06 (3)*
O7B	0.74507 (12)	0.1539 (3)	0.62431 (16)	0.0229 (7)
O8B	0.61194 (12)	0.2010 (3)	0.57683 (16)	0.0243 (7)
O9B	0.57705 (11)	0.4420 (3)	0.44128 (15)	0.0226 (7)
O10B	0.55913 (11)	0.1971 (3)	0.31241 (15)	0.0212 (7)
O11B	0.69300 (12)	0.1458 (3)	0.35603 (16)	0.0235 (7)
H11	0.713 (3)	0.222 (7)	0.362 (5)	0.15 (4)*
O12B	0.71759 (12)	−0.1040 (3)	0.49309 (17)	0.0262 (8)
O13T	0.80360 (12)	0.0093 (3)	0.59080 (17)	0.0285 (8)
O14T	0.74286 (12)	−0.1258 (3)	0.62346 (17)	0.0305 (8)
O15T	0.68520 (13)	0.0508 (4)	0.67282 (16)	0.0299 (8)
O16T	0.69977 (13)	0.3193 (3)	0.67096 (17)	0.0312 (8)
O17T	0.52417 (13)	0.3226 (4)	0.49587 (19)	0.0371 (9)
O18T	0.60285 (14)	0.4814 (4)	0.56903 (17)	0.0370 (9)
O19T	0.49288 (12)	0.3228 (3)	0.34110 (17)	0.0275 (8)
O20T	0.55233 (12)	0.4783 (3)	0.31420 (16)	0.0283 (8)
O21T	0.62270 (13)	0.3112 (4)	0.27214 (17)	0.0292 (8)
O22T	0.60336 (13)	0.0433 (4)	0.25787 (17)	0.0315 (8)
O23T	0.69102 (12)	−0.1349 (3)	0.36251 (18)	0.0304 (8)
O24T	0.77302 (12)	0.0093 (3)	0.44119 (17)	0.0290 (8)
C1	0.5886 (2)	−0.1669 (7)	0.5871 (3)	0.0536 (18)
N1	0.6167 (2)	−0.1725 (5)	0.5534 (3)	0.0611 (18)
H1A	0.6273	−0.2493	0.5476	0.073*
H1B	0.6230	−0.0991	0.5388	0.073*
N2	0.57817 (17)	−0.2673 (5)	0.6092 (2)	0.0446 (13)
H2A	0.5879	−0.3464	0.6046	0.053*
H2B	0.5611	−0.2586	0.6293	0.053*
N3	0.5678 (3)	−0.0394 (7)	0.5888 (4)	0.106 (3)
H3A	0.5480	−0.0333	0.6052	0.127*
H3B	0.5748	0.0317	0.5735	0.127*
C2	0.69992 (17)	0.6537 (5)	0.7035 (2)	0.0252 (11)
N4	0.7180 (2)	0.6254 (5)	0.6658 (3)	0.0482 (14)
H4A	0.7210	0.5420	0.6571	0.058*
H4B	0.7273	0.6896	0.6490	0.058*
N5	0.68617 (16)	0.5573 (4)	0.7284 (2)	0.0310 (10)
H5A	0.6892	0.4741	0.7196	0.037*
H5B	0.6739	0.5760	0.7538	0.037*
N6	0.69567 (17)	0.7785 (5)	0.7166 (2)	0.0355 (11)
H6A	0.7050	0.8426	0.6999	0.043*
H6B	0.6835	0.7976	0.7420	0.043*
C3	0.4036 (2)	0.6616 (5)	0.2726 (3)	0.0290 (11)
N7	0.43204 (15)	0.5625 (4)	0.3073 (2)	0.0324 (10)
H7A	0.4546	0.5757	0.3479	0.039*
H7B	0.4284	0.4834	0.2898	0.039*
N8	0.36976 (18)	0.6419 (5)	0.2123 (2)	0.0444 (13)
H8A	0.3507	0.7078	0.1894	0.053*
H8B	0.3661	0.5628	0.1947	0.053*
N9	0.4097 (3)	0.7778 (5)	0.2998 (3)	0.075 (2)
H9A	0.3910	0.8448	0.2775	0.090*
H9B	0.4326	0.7894	0.3403	0.090*
C4	0.5228 (3)	0.8412 (9)	0.2828 (4)	0.028 (2)	0.50
N10	0.5000	0.7313 (6)	0.2500	0.0368 (16)
H10A	0.4775 (14)	0.686 (4)	0.2159 (13)	0.044*
N11	0.5000	0.9567 (6)	0.2500	0.0471 (19)
H11A	0.5223 (16)	1.002 (4)	0.2844 (14)	0.057*
N12	0.5653 (4)	0.8331 (14)	0.3368 (6)	0.039 (3)	0.50
H12A	0.579 (3)	0.753 (5)	0.343 (6)	0.046*	0.50
H12B	0.584 (3)	0.905 (6)	0.355 (6)	0.046*	0.50
O1W	0.51593 (15)	0.6741 (4)	0.42228 (19)	0.0400 (10)
H1AW	0.5475 (12)	0.638 (6)	0.446 (3)	0.060*
H1BW	0.507 (2)	0.678 (6)	0.456 (2)	0.060*
O2W	0.52988 (18)	−0.0205 (5)	0.4254 (3)	0.0609 (13)
H2AW	0.508 (3)	−0.006 (8)	0.3811 (14)	0.091*
H2BW	0.553 (2)	−0.091 (6)	0.435 (4)	0.091*
O3W	0.6421 (2)	−0.3187 (6)	0.4650 (3)	0.0764 (17)
H3AW	0.6747 (13)	−0.346 (9)	0.487 (4)	0.115*
H3BW	0.632 (4)	−0.398 (6)	0.441 (4)	0.115*
O4W	0.5802 (4)	0.8321 (11)	0.3704 (5)	0.036 (2)	0.50
H4AW	0.599 (4)	0.911 (8)	0.381 (6)	0.055*	0.50
H4BW	0.602 (4)	0.770 (10)	0.402 (5)	0.055*	0.50

	U11	U22	U33	U12	U13	U23
Pt1	0.01074 (9)	0.01946 (10)	0.01597 (9)	−0.00051 (6)	0.00690 (7)	−0.00191 (7)
Mo1	0.01368 (19)	0.0186 (2)	0.0308 (2)	0.00080 (15)	0.01116 (17)	0.00340 (17)
Mo2	0.0199 (2)	0.0212 (2)	0.0193 (2)	−0.00066 (16)	0.00908 (17)	0.00091 (16)
Mo3	0.0190 (2)	0.0282 (2)	0.0213 (2)	0.00438 (17)	0.01255 (17)	−0.00020 (17)
Mo4	0.01413 (19)	0.0230 (2)	0.01809 (19)	0.00203 (15)	0.00773 (16)	0.00188 (16)
Mo5	0.0170 (2)	0.0242 (2)	0.01814 (19)	−0.00386 (16)	0.01039 (17)	−0.00427 (16)
Mo6	0.01442 (19)	0.0212 (2)	0.0358 (2)	−0.00414 (16)	0.01523 (18)	−0.01035 (18)
O1C	0.0188 (16)	0.0194 (17)	0.0189 (15)	0.0004 (13)	0.0083 (13)	−0.0001 (13)
O2C	0.0175 (16)	0.0200 (17)	0.0203 (16)	−0.0025 (13)	0.0107 (14)	−0.0044 (13)
O3C	0.0110 (15)	0.0224 (17)	0.0212 (16)	0.0003 (13)	0.0089 (13)	−0.0007 (13)
O4C	0.0157 (16)	0.0218 (17)	0.0194 (16)	−0.0030 (13)	0.0099 (13)	−0.0016 (13)
O5C	0.0160 (15)	0.0227 (17)	0.0195 (15)	−0.0018 (13)	0.0093 (13)	−0.0053 (13)
O6C	0.0086 (14)	0.0223 (17)	0.0225 (16)	0.0019 (12)	0.0049 (13)	−0.0056 (13)
O7B	0.0182 (16)	0.0249 (18)	0.0228 (17)	−0.0009 (14)	0.0077 (14)	0.0004 (14)
O8B	0.0213 (17)	0.0329 (19)	0.0235 (17)	−0.0006 (15)	0.0149 (15)	0.0021 (15)
O9B	0.0224 (17)	0.0214 (17)	0.0241 (16)	0.0033 (14)	0.0116 (14)	0.0006 (14)
O10B	0.0144 (15)	0.0283 (18)	0.0201 (16)	−0.0035 (13)	0.0079 (13)	−0.0024 (14)
O11B	0.0180 (16)	0.0287 (18)	0.0271 (17)	−0.0031 (14)	0.0135 (15)	−0.0036 (15)
O12B	0.0200 (17)	0.0226 (18)	0.041 (2)	−0.0029 (14)	0.0185 (16)	−0.0060 (15)
O13T	0.0204 (17)	0.0244 (18)	0.038 (2)	−0.0017 (14)	0.0124 (16)	0.0006 (15)
O14T	0.0245 (18)	0.0262 (19)	0.038 (2)	0.0018 (15)	0.0131 (16)	0.0075 (16)
O15T	0.0318 (19)	0.032 (2)	0.0264 (18)	0.0031 (16)	0.0144 (16)	0.0078 (16)
O16T	0.030 (2)	0.029 (2)	0.0307 (19)	0.0001 (15)	0.0115 (17)	−0.0062 (15)
O17T	0.0255 (19)	0.057 (3)	0.037 (2)	0.0066 (17)	0.0210 (18)	0.0066 (18)
O18T	0.048 (2)	0.036 (2)	0.0266 (19)	0.0097 (18)	0.0184 (18)	−0.0030 (17)
O19T	0.0159 (16)	0.033 (2)	0.0313 (19)	0.0022 (14)	0.0099 (15)	0.0011 (15)
O20T	0.0261 (18)	0.031 (2)	0.0254 (17)	0.0023 (15)	0.0112 (15)	0.0051 (15)
O21T	0.0292 (19)	0.038 (2)	0.0257 (18)	−0.0018 (16)	0.0173 (16)	0.0027 (15)
O22T	0.0311 (19)	0.038 (2)	0.0292 (18)	−0.0069 (17)	0.0176 (16)	−0.0152 (16)
O23T	0.0255 (18)	0.0244 (18)	0.044 (2)	−0.0039 (15)	0.0197 (17)	−0.0126 (17)
O24T	0.0257 (18)	0.0280 (19)	0.040 (2)	0.0018 (15)	0.0208 (17)	−0.0045 (16)
C1	0.035 (3)	0.063 (5)	0.052 (4)	−0.005 (3)	0.013 (3)	−0.013 (3)
N1	0.035 (3)	0.035 (3)	0.100 (5)	−0.006 (2)	0.024 (3)	0.000 (3)
N2	0.035 (3)	0.049 (3)	0.057 (3)	−0.003 (2)	0.029 (3)	0.012 (3)
N3	0.134 (7)	0.078 (5)	0.185 (9)	−0.068 (5)	0.140 (7)	−0.066 (5)
C2	0.019 (2)	0.030 (3)	0.021 (2)	−0.002 (2)	0.006 (2)	0.000 (2)
N4	0.075 (4)	0.040 (3)	0.063 (3)	−0.011 (3)	0.059 (3)	−0.005 (3)
N5	0.038 (3)	0.029 (2)	0.035 (2)	−0.002 (2)	0.026 (2)	−0.003 (2)
N6	0.038 (3)	0.032 (3)	0.038 (3)	0.000 (2)	0.021 (2)	0.003 (2)
C3	0.034 (3)	0.030 (3)	0.028 (3)	0.004 (2)	0.019 (2)	0.005 (2)
N7	0.031 (2)	0.032 (2)	0.026 (2)	0.003 (2)	0.0069 (19)	0.0025 (19)
N8	0.038 (3)	0.044 (3)	0.036 (3)	0.005 (2)	0.006 (2)	0.010 (2)
N9	0.154 (7)	0.029 (3)	0.045 (3)	0.016 (4)	0.050 (4)	0.004 (3)
C4	0.022 (5)	0.039 (6)	0.031 (6)	−0.007 (4)	0.019 (5)	−0.002 (5)
N10	0.033 (4)	0.022 (3)	0.045 (4)	0.000	0.012 (3)	0.000
N11	0.042 (4)	0.019 (3)	0.083 (6)	0.000	0.033 (4)	0.000
N12	0.035 (8)	0.030 (6)	0.043 (7)	0.007 (5)	0.013 (6)	0.011 (7)
O1W	0.039 (2)	0.055 (3)	0.031 (2)	0.0063 (19)	0.0207 (19)	0.0038 (18)
O2W	0.051 (3)	0.037 (3)	0.091 (4)	0.000 (2)	0.032 (3)	0.006 (3)
O3W	0.069 (4)	0.072 (4)	0.097 (5)	0.027 (3)	0.048 (4)	0.009 (3)
O4W	0.025 (6)	0.034 (6)	0.050 (7)	−0.010 (4)	0.018 (5)	0.001 (6)

Pt1—O1C	1.995 (3)	O6C—O6Ci	2.532 (6)
Pt1—O2C	2.015 (3)	O6C—H6	1.266 (3)
Pt1—O3C	2.027 (3)	O11B—H11	0.95 (2)
Pt1—O4C	2.011 (3)	C1—N2	1.254 (8)
Pt1—O5C	1.997 (3)	C1—N1	1.451 (10)
Pt1—O6C	2.005 (3)	C1—N3	1.451 (10)
Mo1—O1C	2.150 (3)	N1—H1A	0.8800
Mo1—O6C	2.317 (3)	N1—H1B	0.8800
Mo2—O1C	2.248 (3)	N2—H2A	0.8800
Mo2—O2C	2.286 (3)	N2—H2B	0.8800
Mo3—O2C	2.307 (3)	N3—H3A	0.8800
Mo3—O3C	2.318 (3)	N3—H3B	0.8800
Mo4—O3C	2.287 (3)	C2—N4	1.304 (7)
Mo4—O4C	2.327 (3)	C2—N5	1.314 (6)
Mo5—O4C	2.289 (3)	C2—N6	1.317 (7)
Mo5—O5C	2.178 (3)	N4—H4A	0.8800
Mo6—O5C	2.123 (3)	N4—H4B	0.8800
Mo6—O6C	2.277 (3)	N5—H5A	0.8800
Mo1—O7B	1.965 (3)	N5—H5B	0.8800
Mo1—O12B	1.959 (3)	N6—H6A	0.8800
Mo2—O7B	1.978 (3)	N6—H6B	0.8800
Mo2—O8B	1.945 (3)	C3—N9	1.303 (7)
Mo3—O8B	1.934 (3)	C3—N8	1.310 (7)
Mo3—O9B	1.952 (3)	C3—N7	1.322 (6)
Mo4—O9B	1.941 (3)	N7—H7A	0.8800
Mo4—O10B	1.959 (3)	N7—H7B	0.8800
Mo5—O10B	1.895 (3)	N8—H8A	0.8800
Mo5—O11B	2.058 (3)	N8—H8B	0.8800
Mo6—O11B	2.075 (4)	N9—H9A	0.8800
Mo6—O12B	1.894 (4)	N9—H9B	0.8800
Mo1—O14T	1.706 (3)	C4—N12	1.320 (12)
Mo1—O13T	1.735 (3)	C4—N10	1.340 (10)
Mo2—O15T	1.702 (3)	C4—N11	1.387 (10)
Mo2—O16T	1.713 (3)	N10—H10A	0.893 (17)
Mo3—O17T	1.705 (4)	N11—H11A	0.898 (18)
Mo3—O18T	1.706 (4)	N12—H12A	0.90 (2)
Mo4—O19T	1.704 (3)	N12—H12B	0.90 (2)
Mo4—O20T	1.706 (3)	O1W—H1AW	0.94 (2)
Mo5—O22T	1.708 (3)	O1W—H1BW	0.95 (2)
Mo5—O21T	1.719 (3)	O2W—H2AW	0.94 (2)
Mo6—O23T	1.710 (3)	O2W—H2BW	0.95 (2)
Mo6—O24T	1.732 (3)	O3W—H3AW	0.93 (2)
O2C—H2	0.96 (2)	O3W—H3BW	0.94 (2)
O3C—H3	0.96 (2)	O4W—H4AW	0.95 (2)
O4C—H4	0.95 (2)	O4W—H4BW	0.95 (2)
Mo1—O1C—Mo2	95.79 (12)	O21T—Mo5—O4C	86.44 (14)
Mo2—O2C—Mo3	93.64 (11)	O10B—Mo5—O4C	72.56 (12)
Mo4—O3C—Mo3	93.75 (12)	O11B—Mo5—O4C	85.46 (12)
Mo5—O4C—Mo4	92.64 (11)	O5C—Mo5—O4C	72.30 (12)
Mo6—O5C—Mo5	102.87 (13)	O23T—Mo6—O24T	105.40 (16)
Mo6—O6C—Mo1	91.14 (12)	O23T—Mo6—O12B	101.61 (17)
Mo1—O7B—Mo2	111.71 (15)	O24T—Mo6—O12B	101.99 (16)
Mo3—O8B—Mo2	119.36 (16)	O23T—Mo6—O11B	96.50 (16)
Mo4—O9B—Mo3	119.39 (17)	O24T—Mo6—O11B	89.87 (15)
Mo5—O10B—Mo4	120.02 (16)	O12B—Mo6—O11B	154.72 (14)
Mo5—O11B—Mo6	108.97 (15)	O23T—Mo6—O5C	93.14 (14)
Mo6—O12B—Mo1	116.75 (17)	O24T—Mo6—O5C	155.73 (14)
O1C—Pt1—O5C	99.68 (14)	O12B—Mo6—O5C	89.14 (13)
O1C—Pt1—O6C	84.05 (13)	O11B—Mo6—O5C	72.28 (12)
O5C—Pt1—O6C	83.21 (12)	O23T—Mo6—O6C	166.99 (14)
O1C—Pt1—O4C	177.35 (12)	O24T—Mo6—O6C	87.60 (14)
O5C—Pt1—O4C	82.27 (13)	O12B—Mo6—O6C	75.67 (13)
O6C—Pt1—O4C	97.99 (13)	O11B—Mo6—O6C	82.71 (13)
O1C—Pt1—O2C	82.64 (13)	O5C—Mo6—O6C	74.21 (11)
O5C—Pt1—O2C	177.41 (13)	Pt1—O1C—Mo1	104.21 (13)
O6C—Pt1—O2C	98.20 (13)	Pt1—O1C—Mo2	103.95 (14)
O4C—Pt1—O2C	95.37 (13)	Pt1—O2C—Mo2	101.92 (13)
O1C—Pt1—O3C	95.12 (13)	Pt1—O2C—Mo3	103.51 (13)
O5C—Pt1—O3C	95.66 (12)	Pt1—O2C—H2	116 (4)
O6C—Pt1—O3C	178.46 (12)	Mo2—O2C—H2	113 (4)
O4C—Pt1—O3C	82.87 (13)	Mo3—O2C—H2	125 (4)
O2C—Pt1—O3C	82.96 (13)	Pt1—O3C—Mo4	103.59 (13)
O14T—Mo1—O13T	105.87 (16)	Pt1—O3C—Mo3	102.74 (13)
O14T—Mo1—O12B	99.01 (16)	Pt1—O3C—H3	108 (4)
O13T—Mo1—O12B	98.14 (15)	Mo4—O3C—H3	124 (4)
O14T—Mo1—O7B	100.03 (16)	Mo3—O3C—H3	122 (4)
O13T—Mo1—O7B	95.86 (15)	Pt1—O4C—Mo5	100.53 (13)
O12B—Mo1—O7B	152.25 (14)	Pt1—O4C—Mo4	102.74 (13)
O14T—Mo1—O1C	93.17 (14)	Pt1—O4C—H4	124 (5)
O13T—Mo1—O1C	160.02 (14)	Mo5—O4C—H4	109 (5)
O12B—Mo1—O1C	84.50 (12)	Mo4—O4C—H4	122 (5)
O7B—Mo1—O1C	74.48 (12)	Pt1—O5C—Mo6	103.69 (13)
O14T—Mo1—O6C	165.12 (14)	Pt1—O5C—Mo5	104.87 (14)
O13T—Mo1—O6C	88.14 (14)	Pt1—O6C—Mo6	98.17 (12)
O12B—Mo1—O6C	73.55 (13)	Pt1—O6C—Mo1	98.14 (13)
O7B—Mo1—O6C	83.11 (12)	Pt1—O6C—O6Ci	120.8 (2)
O1C—Mo1—O6C	73.54 (11)	Mo6—O6C—O6Ci	121.27 (19)
O15T—Mo2—O16T	107.06 (18)	Mo1—O6C—O6Ci	120.85 (19)
O15T—Mo2—O8B	98.04 (15)	Pt1—O6C—H6	120.8 (2)
O16T—Mo2—O8B	100.65 (16)	Mo6—O6C—H6	121.27 (19)
O15T—Mo2—O7B	100.70 (15)	Mo1—O6C—H6	120.85 (19)
O16T—Mo2—O7B	96.07 (16)	O6Ci—O6C—H6	0.00 (18)
O8B—Mo2—O7B	149.93 (14)	Mo5—O11B—H11	118 (7)
O15T—Mo2—O1C	94.74 (15)	Mo6—O11B—H11	125 (7)
O16T—Mo2—O1C	156.95 (15)	N2—C1—N1	123.5 (6)
O8B—Mo2—O1C	83.19 (13)	N2—C1—N3	119.2 (7)
O7B—Mo2—O1C	72.05 (12)	N1—C1—N3	117.0 (6)
O15T—Mo2—O2C	163.07 (14)	C1—N1—H1A	120.0
O16T—Mo2—O2C	88.12 (15)	C1—N1—H1B	120.0
O8B—Mo2—O2C	71.19 (12)	H1A—N1—H1B	120.0
O7B—Mo2—O2C	84.67 (12)	C1—N2—H2A	120.0
O1C—Mo2—O2C	71.47 (12)	C1—N2—H2B	120.0
O17T—Mo3—O18T	106.36 (19)	H2A—N2—H2B	120.0
O17T—Mo3—O8B	98.10 (16)	C1—N3—H3A	120.0
O18T—Mo3—O8B	102.14 (16)	C1—N3—H3B	120.0
O17T—Mo3—O9B	100.99 (16)	H3A—N3—H3B	120.0
O18T—Mo3—O9B	97.16 (16)	N4—C2—N5	119.7 (5)
O8B—Mo3—O9B	147.71 (13)	N4—C2—N6	120.0 (5)
O17T—Mo3—O2C	160.66 (16)	N5—C2—N6	120.3 (5)
O18T—Mo3—O2C	91.76 (16)	C2—N4—H4A	120.0
O8B—Mo3—O2C	70.90 (12)	C2—N4—H4B	120.0
O9B—Mo3—O2C	82.96 (12)	H4A—N4—H4B	120.0
O17T—Mo3—O3C	92.54 (15)	C2—N5—H5A	120.0
O18T—Mo3—O3C	159.28 (16)	C2—N5—H5B	120.0
O8B—Mo3—O3C	83.03 (13)	H5A—N5—H5B	120.0
O9B—Mo3—O3C	70.38 (13)	C2—N6—H6A	120.0
O2C—Mo3—O3C	70.78 (11)	C2—N6—H6B	120.0
O19T—Mo4—O20T	107.04 (16)	H6A—N6—H6B	120.0
O19T—Mo4—O9B	100.65 (15)	N9—C3—N8	121.1 (5)
O20T—Mo4—O9B	97.05 (15)	N9—C3—N7	118.8 (5)
O19T—Mo4—O10B	99.01 (15)	N8—C3—N7	120.1 (5)
O20T—Mo4—O10B	101.47 (15)	C3—N7—H7A	120.0
O9B—Mo4—O10B	147.60 (13)	C3—N7—H7B	120.0
O19T—Mo4—O3C	92.83 (14)	H7A—N7—H7B	120.0
O20T—Mo4—O3C	158.72 (14)	C3—N8—H8A	120.0
O9B—Mo4—O3C	71.24 (13)	C3—N8—H8B	120.0
O10B—Mo4—O3C	82.34 (13)	H8A—N8—H8B	120.0
O19T—Mo4—O4C	161.33 (14)	C3—N9—H9A	120.0
O20T—Mo4—O4C	90.53 (14)	C3—N9—H9B	120.0
O9B—Mo4—O4C	82.92 (12)	H9A—N9—H9B	120.0
O10B—Mo4—O4C	70.65 (12)	N12—C4—N10	120.6 (9)
O3C—Mo4—O4C	70.80 (11)	N12—C4—N11	126.3 (9)
O22T—Mo5—O21T	106.73 (18)	N10—C4—N11	112.7 (7)
O22T—Mo5—O10B	101.18 (15)	C4—N10—H10A	155 (2)
O21T—Mo5—O10B	103.69 (15)	C4—N12—H12A	113 (7)
O22T—Mo5—O11B	96.63 (15)	C4—N12—H12B	122 (8)
O21T—Mo5—O11B	90.77 (15)	H12A—N12—H4AW	106 (10)
O10B—Mo5—O11B	152.59 (14)	H12B—N12—H4AW	20 (10)
O22T—Mo5—O5C	95.73 (15)	H1AW—O1W—H1BW	100 (6)
O21T—Mo5—O5C	152.95 (14)	H2AW—O2W—H2BW	116 (8)
O10B—Mo5—O5C	86.07 (13)	H3AW—O3W—H3BW	92 (8)
O11B—Mo5—O5C	71.47 (12)	H4AW—O4W—H4BW	103 (10)
O22T—Mo5—O4C	166.58 (15)

D—H···A	D—H	H···A	D···A	D—H···A
O2C—H2···O24Ti	0.96 (2)	1.61 (2)	2.578 (5)	179 (6)
O3C—H3···O2W	0.96 (2)	1.69 (3)	2.622 (6)	164 (7)
O4C—H4···O13Ti	0.95 (2)	1.63 (2)	2.568 (5)	173 (9)
O6C—H6···O6Ci	1.27	1.27	2.532 (6)	180
O11B—H11···O7Bi	0.95 (2)	1.74 (2)	2.679 (5)	173 (10)
N1—H1B···O1C	0.88	2.05	2.864 (6)	154
N1—H1A···O3W	0.88	2.33	2.973 (9)	130
N2—H2A···O18Tii	0.88	2.08	2.940 (7)	165
N2—H2B···O19Tiii	0.88	2.22	3.043 (6)	155
N3—H3B···O8B	0.88	2.04	2.874 (7)	157
N3—H3A···O2Wiii	0.88	2.25	2.979 (9)	140
N4—H4B···O14Tiv	0.88	2.09	2.944 (6)	164
N4—H4A···O24Ti	0.88	2.48	3.006 (6)	119
N5—H5A···O16T	0.88	2.06	2.890 (6)	157
N5—H5B···O21Tv	0.88	2.18	2.973 (5)	149
N6—H6A···O15Tiv	0.88	2.19	2.894 (6)	136
N6—H6B···O21Tv	0.88	2.59	3.281 (6)	136
N7—H7B···O19T	0.88	2.40	2.936 (5)	119
N7—H7A···O1W	0.88	2.11	2.927 (6)	154
N8—H8B···O13Tvi	0.88	2.39	3.006 (6)	128
N8—H8A···O23Tvii	0.88	2.04	2.918 (6)	178
N9—H9A···O22Tvii	0.88	2.21	2.938 (7)	140
O1W—H1AW···O9B	0.94 (2)	2.20 (5)	2.916 (5)	132 (5)
O1W—H1BW···O17Tviii	0.95 (2)	1.85 (3)	2.783 (5)	166 (6)
O2W—H2BW···O4Wii	0.95 (2)	2.24 (7)	2.902 (12)	126 (6)
O3W—H3BW···O9Bii	0.94 (2)	2.35 (8)	3.029 (7)	128 (8)