Monopotassium monosodium hexa-hydrogen α-hexa-molybdoplatinate(IV) undeca-hydrate.

The title compound, KNa[H(6)PtMo(6)O(24)]·11H(2)O, contains a discrete hexa-molybdoplatinate(IV) [H(6)PtMo(6)O(24)](2-) poly-anion (1 symmetry), which has the highest level of protonation. Five O atoms of the central PtO(6) octa-hedron (μ(3)-atoms, Oc) and one O atom of an outer edge-sharing MoO(6) octa-hedron (O bridging μ(2)-atom, Ob) are protonated. The polyanions are connected by almost linear O-H⋯O hydrogen bonds between protonated and unprotonated Ob atoms. Further consolidation of the crystal structure is accomplished by extensive O-H⋯O hydrogen bonding involving the uncoordinated water mol-ecules. The two independent K(+) cations are equally disordered about a twofold rotation axis.

Related literature

For other crystal structures containing the [H6PtMo6O24]6− anion, see: Lee & Sasaki (1994 ▶); Lee & Joo (2006a ▶,b ▶). For background to the bond-valence method, see: Brown & Altermatt (1985 ▶); Brese & O’Keeffe (1991 ▶).

Experimental

Crystal data

KNa[H6PtMo6O24]·11H2O

M = 1421.04

Monoclinic,

a = 20.935 (2) Å

b = 18.535 (3) Å

c = 17.775 (3) Å

β = 114.30 (2)°

V = 6286.2 (18) Å3

Z = 8

Mo Kα radiation

μ = 7.02 mm−1

T = 298 K

0.38 × 0.25 × 0.25 mm

Data collection

Stoe Stadi-4 diffractometer

Absorption correction: numerical (X-SHAPE; Stoe & Cie 1996 ▶) T min = 0.300, T max = 0.422

8235 measured reflections

7237 independent reflections

5972 reflections with I > 2σ(I)

R int = 0.028

3 standard reflections every 60 min intensity decay: 3.2%

Refinement

R[F 2 > 2σ(F 2)] = 0.035

wR(F 2) = 0.082

S = 1.14

7237 reflections

490 parameters

33 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.96 e Å−3

Δρmin = −1.26 e Å−3

Data collection: STADI4 (Stoe & Cie, 1996 ▶); cell refinement: STADI4; data reduction: X-RED (Stoe & Cie, 1996 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and DIAMOND (Brandenburg, 1998 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053681000228X/wm2298sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053681000228X/wm2298Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

KNa[H6PtMo6O24]·11H2O	F(000) = 5344
Mr = 1421.04	Dx = 3.003 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -C 2yc	Cell parameters from 25 reflections
a = 20.935 (2) Å	θ = 9.6–10.3°
b = 18.535 (3) Å	µ = 7.02 mm−1
c = 17.775 (3) Å	T = 298 K
β = 114.30 (2)°	Block, pale yellow
V = 6286.2 (18) Å3	0.38 × 0.25 × 0.25 mm
Z = 8

Stoe Stadi-4 diffractometer	5972 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.028
graphite	θmax = 27.5°, θmin = 1.5°
ω/2–θ scans	h = −2→27
Absorption correction: numerical (X-SHAPE; Stoe & Cie 1996)	k = −24→24
Tmin = 0.300, Tmax = 0.422	l = −23→21
8235 measured reflections	3 standard reflections every 60 min
7237 independent reflections	intensity decay: 3.2%

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.035	Hydrogen site location: difference Fourier map
wR(F2) = 0.082	H atoms treated by a mixture of independent and constrained refinement
S = 1.14	w = 1/[σ2(Fo2) + (0.0282P)2 + 43.9139P] where P = (Fo2 + 2Fc2)/3
7237 reflections	(Δ/σ)max = 0.001
490 parameters	Δρmax = 0.96 e Å−3
33 restraints	Δρmin = −1.26 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pt	0.755879 (11)	0.504087 (12)	0.501298 (14)	0.01487 (6)
Mo1	0.60877 (3)	0.60494 (3)	0.40899 (4)	0.02644 (13)
Mo2	0.64099 (3)	0.46279 (3)	0.31418 (3)	0.02522 (13)
Mo3	0.78857 (3)	0.36281 (3)	0.40922 (4)	0.02288 (12)
Mo4	0.90273 (3)	0.40566 (3)	0.60119 (4)	0.02459 (13)
Mo5	0.86645 (3)	0.54226 (3)	0.69946 (3)	0.02323 (12)
Mo6	0.71872 (3)	0.63908 (3)	0.60625 (4)	0.02426 (13)
K1	0.4929 (4)	0.7725 (2)	0.2195 (4)	0.092 (4)	0.50
K2	0.5123 (4)	0.7131 (4)	0.7936 (5)	0.114 (3)	0.50
Na	0.45373 (19)	0.66261 (18)	0.4760 (2)	0.0478 (8)
O1C	0.7062 (2)	0.5568 (2)	0.3956 (3)	0.0209 (9)
H1	0.726 (4)	0.583 (4)	0.381 (5)	0.02 (2)*
O2C	0.7085 (2)	0.4197 (2)	0.4330 (3)	0.0194 (9)
O3C	0.8374 (2)	0.4689 (2)	0.4811 (3)	0.0189 (9)
H3	0.866 (4)	0.501 (4)	0.471 (5)	0.03 (2)*
O4C	0.8038 (2)	0.4515 (2)	0.6085 (3)	0.0185 (9)
H4	0.781 (4)	0.429 (4)	0.626 (4)	0.022 (19)*
O5C	0.8043 (2)	0.5910 (2)	0.5715 (3)	0.0212 (9)
H5	0.830 (3)	0.624 (4)	0.551 (4)	0.025 (19)*
O6C	0.6747 (2)	0.5377 (2)	0.5240 (3)	0.0215 (9)
H6	0.654 (4)	0.509 (5)	0.542 (5)	0.04 (2)*
O7B	0.5858 (2)	0.5080 (3)	0.3625 (3)	0.0286 (10)
O8B	0.7364 (2)	0.4336 (3)	0.3155 (3)	0.0265 (10)
H8	0.747 (3)	0.435 (4)	0.277 (4)	0.016 (17)*
O9B	0.8324 (2)	0.3398 (2)	0.5227 (3)	0.0264 (10)
O10B	0.9231 (2)	0.5009 (3)	0.6477 (3)	0.0279 (10)
O11B	0.7729 (2)	0.5689 (3)	0.6895 (3)	0.0258 (10)
O12B	0.6770 (3)	0.6662 (3)	0.4900 (3)	0.0310 (11)
O13T	0.5397 (3)	0.6145 (3)	0.4351 (4)	0.0463 (15)
O14T	0.5911 (3)	0.6567 (3)	0.3234 (3)	0.0448 (14)
O15T	0.6253 (3)	0.5154 (4)	0.2295 (3)	0.0504 (16)
O16T	0.5949 (3)	0.3850 (3)	0.2793 (4)	0.0476 (15)
O17T	0.7403 (3)	0.2868 (3)	0.3706 (4)	0.0409 (13)
O18T	0.8564 (3)	0.3585 (3)	0.3792 (3)	0.0365 (12)
O19T	0.9696 (3)	0.3948 (3)	0.5710 (4)	0.0408 (13)
O20T	0.9220 (3)	0.3524 (3)	0.6861 (3)	0.0433 (14)
O21T	0.8880 (3)	0.4880 (3)	0.7839 (3)	0.0403 (13)
O22T	0.9118 (3)	0.6211 (3)	0.7340 (3)	0.0398 (13)
O23T	0.7642 (3)	0.7167 (3)	0.6445 (4)	0.0423 (14)
O24T	0.6480 (3)	0.6418 (3)	0.6303 (3)	0.0419 (14)
O1W	0.3734 (4)	0.6928 (4)	0.5338 (6)	0.072 (2)
H1A	0.357 (7)	0.658 (5)	0.547 (8)	0.108*
H1B	0.349 (6)	0.727 (5)	0.518 (9)	0.108*
O2W	0.5059 (4)	0.5835 (6)	0.5945 (5)	0.089 (3)
H2A	0.478 (6)	0.607 (9)	0.604 (9)	0.133*
H2B	0.541 (5)	0.582 (8)	0.636 (7)	0.133*
O3W	0.4069 (5)	0.7211 (5)	0.3363 (5)	0.075 (2)
H3A	0.394 (7)	0.761 (5)	0.306 (8)	0.113*
H3B	0.380 (7)	0.692 (6)	0.309 (8)	0.113*
O4W	0.6004 (9)	0.7658 (7)	0.6985 (7)	0.151 (6)
H4A	0.624 (11)	0.729 (7)	0.714 (14)	0.227*
H4B	0.624 (11)	0.802 (8)	0.726 (13)	0.227*
O5W	0.3899 (4)	0.5535 (5)	0.4228 (4)	0.085 (3)
H5A	0.4118	0.5270	0.3935	0.128*
H5B	0.3427	0.5653	0.3859	0.128*
O6W	0.5264 (4)	0.7653 (4)	0.5274 (6)	0.071 (2)
H6A	0.538 (7)	0.755 (7)	0.586 (5)	0.106*
H6B	0.501 (6)	0.803 (5)	0.526 (8)	0.106*
O7W	0.8968 (3)	0.5657 (3)	0.4306 (3)	0.0335 (12)
H7A	0.909 (4)	0.560 (5)	0.385 (4)	0.050*
H7B	0.929 (4)	0.582 (5)	0.465 (5)	0.050*
O8W	0.7388 (4)	0.3605 (4)	0.6632 (4)	0.0536 (18)
H8A	0.757 (6)	0.335 (6)	0.645 (7)	0.080*
H8B	0.749 (6)	0.367 (6)	0.711 (5)	0.080*
O9W	0.8666 (4)	0.6922 (3)	0.5311 (6)	0.068 (2)
H9A	0.904 (4)	0.694 (7)	0.537 (8)	0.102*
H9B	0.844 (6)	0.723 (6)	0.529 (9)	0.102*
O10W	0.7273 (3)	0.8572 (3)	0.6648 (3)	0.0384 (13)
H10A	0.729 (5)	0.819 (4)	0.639 (6)	0.058*
H10B	0.682 (4)	0.870 (5)	0.639 (6)	0.058*
O11W	0.9966 (3)	0.5975 (5)	0.5839 (4)	0.065 (2)
H11A	1.040 (4)	0.599 (7)	0.601 (7)	0.098*
H11B	0.982 (6)	0.581 (7)	0.613 (7)	0.098*

	U11	U22	U33	U12	U13	U23
Pt	0.01848 (11)	0.01434 (11)	0.01480 (10)	−0.00019 (9)	0.00989 (8)	−0.00024 (8)
Mo1	0.0277 (3)	0.0272 (3)	0.0253 (3)	0.0088 (2)	0.0118 (2)	0.0026 (2)
Mo2	0.0240 (3)	0.0335 (3)	0.0178 (3)	0.0001 (2)	0.0084 (2)	−0.0043 (2)
Mo3	0.0284 (3)	0.0189 (3)	0.0263 (3)	0.0011 (2)	0.0163 (2)	−0.0031 (2)
Mo4	0.0230 (3)	0.0280 (3)	0.0255 (3)	0.0061 (2)	0.0128 (2)	0.0037 (2)
Mo5	0.0232 (3)	0.0303 (3)	0.0176 (3)	−0.0037 (2)	0.0098 (2)	−0.0032 (2)
Mo6	0.0325 (3)	0.0199 (3)	0.0252 (3)	0.0021 (2)	0.0168 (2)	−0.0031 (2)
K1	0.041 (4)	0.039 (2)	0.183 (10)	−0.008 (2)	0.035 (6)	−0.025 (3)
K2	0.079 (4)	0.102 (5)	0.174 (8)	−0.040 (4)	0.067 (6)	−0.056 (5)
Na	0.055 (2)	0.0396 (18)	0.064 (2)	−0.0055 (16)	0.0407 (18)	−0.0080 (17)
O1C	0.026 (2)	0.020 (2)	0.019 (2)	0.0016 (19)	0.0117 (19)	0.0037 (18)
O2C	0.023 (2)	0.020 (2)	0.016 (2)	−0.0006 (17)	0.0089 (17)	−0.0009 (17)
O3C	0.021 (2)	0.018 (2)	0.024 (2)	−0.0002 (17)	0.0147 (18)	−0.0002 (18)
O4C	0.023 (2)	0.020 (2)	0.019 (2)	0.0016 (18)	0.0142 (18)	0.0068 (18)
O5C	0.027 (2)	0.018 (2)	0.024 (2)	−0.0026 (18)	0.0154 (19)	−0.0044 (18)
O6C	0.026 (2)	0.021 (2)	0.025 (2)	0.0018 (19)	0.0172 (19)	−0.0008 (19)
O7B	0.022 (2)	0.037 (3)	0.027 (2)	0.000 (2)	0.0098 (19)	−0.003 (2)
O8B	0.029 (2)	0.036 (3)	0.020 (2)	0.002 (2)	0.015 (2)	−0.002 (2)
O9B	0.035 (3)	0.017 (2)	0.029 (2)	0.0049 (19)	0.016 (2)	0.0032 (19)
O10B	0.020 (2)	0.038 (3)	0.026 (2)	−0.009 (2)	0.0107 (18)	−0.005 (2)
O11B	0.032 (2)	0.030 (3)	0.022 (2)	0.002 (2)	0.017 (2)	0.0037 (19)
O12B	0.041 (3)	0.022 (2)	0.032 (3)	0.007 (2)	0.017 (2)	0.006 (2)
O13T	0.039 (3)	0.054 (4)	0.052 (4)	0.012 (3)	0.025 (3)	−0.008 (3)
O14T	0.048 (3)	0.042 (3)	0.035 (3)	0.010 (3)	0.008 (3)	0.012 (3)
O15T	0.047 (3)	0.081 (5)	0.025 (3)	0.026 (3)	0.017 (3)	0.015 (3)
O16T	0.034 (3)	0.059 (4)	0.048 (3)	−0.015 (3)	0.016 (3)	−0.029 (3)
O17T	0.055 (4)	0.024 (3)	0.047 (3)	−0.008 (2)	0.024 (3)	−0.012 (2)
O18T	0.038 (3)	0.042 (3)	0.036 (3)	0.008 (2)	0.022 (2)	−0.001 (2)
O19T	0.030 (3)	0.047 (3)	0.055 (3)	0.006 (2)	0.027 (3)	−0.005 (3)
O20T	0.044 (3)	0.049 (4)	0.031 (3)	0.011 (3)	0.010 (2)	0.015 (3)
O21T	0.038 (3)	0.060 (4)	0.023 (2)	0.010 (3)	0.013 (2)	0.012 (3)
O22T	0.038 (3)	0.044 (3)	0.037 (3)	−0.018 (3)	0.015 (2)	−0.016 (3)
O23T	0.064 (4)	0.020 (3)	0.046 (3)	−0.008 (3)	0.025 (3)	−0.009 (2)
O24T	0.042 (3)	0.054 (4)	0.037 (3)	0.012 (3)	0.025 (3)	−0.001 (3)
O1W	0.085 (5)	0.031 (4)	0.139 (7)	0.015 (4)	0.086 (6)	0.021 (4)
O2W	0.040 (4)	0.134 (9)	0.067 (5)	−0.022 (5)	−0.005 (4)	0.044 (6)
O3W	0.091 (6)	0.064 (5)	0.063 (5)	0.017 (5)	0.025 (5)	0.004 (4)
O4W	0.278 (19)	0.086 (8)	0.088 (8)	0.070 (10)	0.074 (10)	−0.009 (6)
O5W	0.113 (6)	0.110 (7)	0.058 (4)	−0.082 (5)	0.062 (5)	−0.047 (4)
O6W	0.066 (5)	0.045 (4)	0.106 (6)	0.000 (4)	0.041 (5)	−0.011 (4)
O7W	0.033 (3)	0.040 (3)	0.034 (3)	−0.012 (2)	0.020 (2)	−0.003 (2)
O8W	0.077 (5)	0.052 (4)	0.047 (4)	−0.028 (4)	0.041 (4)	−0.012 (3)
O9W	0.074 (5)	0.030 (3)	0.140 (7)	0.012 (3)	0.084 (6)	0.022 (4)
O10W	0.049 (3)	0.034 (3)	0.037 (3)	−0.002 (3)	0.024 (3)	−0.003 (2)
O11W	0.033 (3)	0.113 (7)	0.042 (4)	−0.021 (4)	0.006 (3)	0.020 (4)

Mo1—Mo2	3.3426 (9)	Mo4—O20T	1.707 (5)
Mo1—Mo6	3.3690 (12)	Mo5—O4C	2.328 (5)
Mo2—Mo3	3.3968 (10)	Mo5—O5C	2.290 (5)
Mo3—Mo4	3.3577 (12)	Mo5—O10B	1.935 (5)
Mo4—Mo5	3.3363 (9)	Mo5—O11B	1.956 (4)
Mo5—Mo6	3.3635 (10)	Mo5—O21T	1.705 (5)
Pt—O1C	1.989 (4)	Mo5—O22T	1.713 (5)
Pt—O2C	1.978 (4)	Mo6—O5C	2.302 (4)
Pt—O3C	1.993 (4)	Mo6—O6C	2.326 (5)
Pt—O4C	2.003 (4)	Mo6—O11B	1.946 (5)
Pt—O5C	2.034 (4)	Mo6—O12B	1.949 (5)
Pt—O6C	2.001 (4)	Mo6—O23T	1.704 (5)
Mo1—O1C	2.327 (5)	Mo6—O24T	1.702 (5)
Mo1—O6C	2.306 (5)	K1—O14Ti	2.678 (8)
Mo1—O7B	1.954 (5)	K1—O14T	3.020 (8)
Mo1—O12B	1.927 (5)	K1—O22Tii	2.682 (9)
Mo1—O13T	1.701 (5)	K1—O22Tiii	2.683 (8)
Mo1—O14T	1.706 (5)	K1—O9Wii	3.368 (12)
Mo2—O1C	2.317 (5)	K1—O3W	3.396 (14)
Mo2—O2C	2.154 (4)	K1—O3Wi	2.831 (14)
Mo2—O7B	1.894 (5)	K2—O16Tiv	2.594 (10)
Mo2—O8B	2.060 (5)	K2—O16Tv	2.763 (8)
Mo2—O15T	1.708 (6)	K2—O20Tvi	2.878 (9)
Mo2—O16T	1.703 (6)	K2—O20Tvii	3.305 (10)
Mo3—O2C	2.163 (4)	K2—O1Wviii	3.039 (13)
Mo3—O3C	2.338 (4)	K2—O2Wviii	3.239 (14)
Mo3—O8B	2.047 (5)	K2—O4W	3.13 (2)
Mo3—O9B	1.889 (5)	K2—O4Wviii	2.61 (2)
Mo3—O17T	1.705 (5)	Na—O13T	2.374 (6)
Mo3—O18T	1.712 (5)	Na—O1W	2.371 (7)
Mo4—O3C	2.323 (4)	Na—O2W	2.425 (9)
Mo4—O4C	2.291 (4)	Na—O3W	2.510 (9)
Mo4—O9B	1.979 (5)	Na—O5W	2.393 (7)
Mo4—O10B	1.921 (5)	Na—O6W	2.373 (9)
Mo4—O19T	1.706 (5)
Mo2—Mo1—Mo6	118.66 (2)	O12B—Mo6—O5C	82.81 (18)
Mo1—Mo2—Mo3	120.68 (3)	O24T—Mo6—O6C	91.2 (2)
Mo4—Mo3—Mo2	119.85 (3)	O23T—Mo6—O6C	160.8 (2)
Mo5—Mo4—Mo3	119.43 (2)	O11B—Mo6—O6C	83.89 (18)
Mo4—Mo5—Mo6	120.55 (3)	O12B—Mo6—O6C	69.74 (18)
Mo5—Mo6—Mo1	120.55 (3)	O5C—Mo6—O6C	70.70 (15)
O2C—Pt—O1C	82.75 (18)	Pt—O1C—Mo2	99.52 (19)
O2C—Pt—O3C	83.14 (17)	Pt—O1C—Mo1	103.37 (19)
O1C—Pt—O3C	98.28 (18)	Pt—O2C—Mo2	105.61 (19)
O2C—Pt—O6C	96.73 (18)	Pt—O2C—Mo3	105.81 (18)
O1C—Pt—O6C	83.14 (19)	Pt—O3C—Mo4	102.91 (17)
O3C—Pt—O6C	178.53 (18)	Pt—O3C—Mo3	99.17 (17)
O2C—Pt—O4C	97.30 (17)	Pt—O4C—Mo4	103.71 (18)
O1C—Pt—O4C	178.52 (18)	Pt—O4C—Mo5	103.15 (18)
O3C—Pt—O4C	83.19 (17)	Pt—O5C—Mo5	103.48 (19)
O6C—Pt—O4C	95.39 (18)	Pt—O5C—Mo6	102.98 (18)
O2C—Pt—O5C	179.86 (18)	Pt—O6C—Mo1	103.74 (19)
O1C—Pt—O5C	97.20 (19)	Pt—O6C—Mo6	103.20 (19)
O3C—Pt—O5C	97.00 (17)	Mo2—O1C—Mo1	92.06 (17)
O6C—Pt—O5C	83.13 (18)	Mo2—O2C—Mo3	103.72 (16)
O4C—Pt—O5C	82.74 (18)	Mo4—O3C—Mo3	92.16 (16)
O13T—Mo1—O14T	106.8 (3)	Mo4—O4C—Mo5	92.48 (16)
O13T—Mo1—O12B	100.7 (3)	Mo5—O5C—Mo6	94.18 (16)
O14T—Mo1—O12B	99.0 (3)	Mo1—O6C—Mo6	93.33 (17)
O13T—Mo1—O7B	97.1 (3)	Mo2—O7B—Mo1	120.6 (2)
O14T—Mo1—O7B	102.4 (3)	Mo3—O8B—Mo2	111.6 (2)
O12B—Mo1—O7B	146.8 (2)	Mo3—O9B—Mo4	120.5 (2)
O13T—Mo1—O6C	94.6 (2)	Mo4—O10B—Mo5	119.8 (2)
O14T—Mo1—O6C	157.8 (2)	Mo6—O11B—Mo5	119.1 (2)
O12B—Mo1—O6C	70.55 (18)	Mo1—O12B—Mo6	120.7 (2)
O7B—Mo1—O6C	80.28 (18)	H1A—O1W—H1B	118 (10)
O13T—Mo1—O1C	161.4 (2)	H2A—O2W—H2B	107 (10)
O14T—Mo1—O1C	90.1 (2)	H3A—O3W—H3B	103 (10)
O12B—Mo1—O1C	83.76 (19)	H4A—O4W—H4B	110 (10)
O7B—Mo1—O1C	71.17 (18)	H5A—O5W—H5B	109.5
O6C—Mo1—O1C	69.71 (15)	H6A—O6W—H6B	93 (8)
O16T—Mo2—O15T	106.7 (3)	H7A—O7W—H7B	106 (7)
O16T—Mo2—O7B	100.3 (2)	H8A—O8W—H8B	126 (10)
O15T—Mo2—O7B	102.4 (2)	H9A—O9W—H9B	126 (10)
O16T—Mo2—O8B	100.5 (2)	H10A—O10W—H10B	103 (7)
O15T—Mo2—O8B	89.7 (2)	H11A—O11W—H11B	117 (10)
O7B—Mo2—O8B	151.67 (19)	O14Ti—K1—O22Tii	104.4 (4)
O16T—Mo2—O2C	95.1 (2)	O14Ti—K1—O22Tiii	174.0 (4)
O15T—Mo2—O2C	152.4 (2)	O22Tii—K1—O22Tiii	81.4 (3)
O7B—Mo2—O2C	89.79 (18)	O14Ti—K1—O3Wi	97.1 (3)
O8B—Mo2—O2C	69.47 (17)	O22Tii—K1—O3Wi	150.6 (4)
O16T—Mo2—O1C	164.6 (2)	O22Tiii—K1—O3Wi	77.9 (3)
O15T—Mo2—O1C	88.4 (3)	O14Ti—K1—O14T	78.8 (3)
O7B—Mo2—O1C	72.37 (18)	O22Tii—K1—O14T	139.7 (3)
O8B—Mo2—O1C	82.60 (18)	O22Tiii—K1—O14T	95.8 (3)
O2C—Mo2—O1C	71.70 (16)	O3Wi—K1—O14T	63.8 (3)
O17T—Mo3—O18T	105.4 (3)	O14Ti—K1—O9Wii	73.6 (2)
O17T—Mo3—O9B	100.9 (2)	O22Tii—K1—O9Wii	71.6 (2)
O18T—Mo3—O9B	102.8 (2)	O22Tiii—K1—O9Wii	110.1 (3)
O17T—Mo3—O8B	99.9 (2)	O3Wi—K1—O9Wii	96.2 (3)
O18T—Mo3—O8B	90.6 (2)	O14T—K1—O9Wii	143.5 (2)
O9B—Mo3—O8B	151.14 (19)	O14Ti—K1—O3W	59.9 (3)
O17T—Mo3—O2C	95.9 (2)	O22Tii—K1—O3W	68.4 (3)
O18T—Mo3—O2C	153.2 (2)	O22Tiii—K1—O3W	122.2 (3)
O9B—Mo3—O2C	88.67 (18)	O3Wi—K1—O3W	140.8 (4)
O8B—Mo3—O2C	69.52 (17)	O14T—K1—O3W	80.0 (2)
O17T—Mo3—O3C	165.5 (2)	O9Wii—K1—O3W	105.4 (3)
O18T—Mo3—O3C	88.7 (2)	O16Tiv—K2—O4Wviii	157.2 (4)
O9B—Mo3—O3C	72.29 (18)	O16Tiv—K2—O16Tv	86.4 (3)
O8B—Mo3—O3C	82.70 (18)	O4Wviii—K2—O16Tv	72.2 (3)
O2C—Mo3—O3C	71.54 (15)	O16Tiv—K2—O20Tvi	109.7 (3)
O19T—Mo4—O20T	106.5 (3)	O4Wviii—K2—O20Tvi	93.1 (3)
O19T—Mo4—O10B	100.3 (2)	O16Tv—K2—O20Tvi	154.7 (4)
O20T—Mo4—O10B	102.8 (3)	O16Tiv—K2—O1Wviii	74.5 (3)
O19T—Mo4—O9B	100.0 (2)	O4Wviii—K2—O1Wviii	110.2 (4)
O20T—Mo4—O9B	95.9 (2)	O16Tv—K2—O1Wviii	122.8 (3)
O10B—Mo4—O9B	147.10 (19)	O20Tvi—K2—O1Wviii	81.2 (2)
O19T—Mo4—O4C	160.1 (2)	O16Tiv—K2—O4W	66.4 (3)
O20T—Mo4—O4C	93.1 (2)	O4Wviii—K2—O4W	131.3 (5)
O10B—Mo4—O4C	71.40 (17)	O16Tv—K2—O4W	119.9 (4)
O9B—Mo4—O4C	80.87 (17)	O20Tvi—K2—O4W	55.2 (3)
O19T—Mo4—O3C	91.1 (2)	O1Wviii—K2—O4W	100.9 (3)
O20T—Mo4—O3C	160.0 (2)	O16Tiv—K2—O2Wviii	78.0 (3)
O10B—Mo4—O3C	82.77 (18)	O4Wviii—K2—O2Wviii	84.7 (3)
O9B—Mo4—O3C	71.18 (17)	O16Tv—K2—O2Wviii	61.4 (2)
O4C—Mo4—O3C	70.19 (14)	O20Tvi—K2—O2Wviii	139.4 (3)
O21T—Mo5—O22T	106.3 (3)	O1Wviii—K2—O2Wviii	62.0 (2)
O21T—Mo5—O10B	101.2 (2)	O4W—K2—O2Wviii	143.9 (4)
O22T—Mo5—O10B	98.7 (2)	O16Tiv—K2—O20Tvii	137.5 (3)
O21T—Mo5—O11B	96.9 (2)	O4Wviii—K2—O20Tvii	54.8 (3)
O22T—Mo5—O11B	101.8 (2)	O16Tv—K2—O20Tvii	94.7 (3)
O10B—Mo5—O11B	147.60 (19)	O20Tvi—K2—O20Tvii	60.1 (3)
O21T—Mo5—O5C	160.5 (2)	O1Wviii—K2—O20Tvii	134.9 (3)
O22T—Mo5—O5C	91.4 (2)	O4W—K2—O20Tvii	76.6 (3)
O10B—Mo5—O5C	83.82 (18)	O2Wviii—K2—O20Tvii	138.6 (3)
O11B—Mo5—O5C	70.87 (17)	O1W—Na—O6W	95.8 (3)
O21T—Mo5—O4C	93.1 (2)	O1W—Na—O13T	169.6 (3)
O22T—Mo5—O4C	159.4 (2)	O6W—Na—O13T	88.4 (3)
O10B—Mo5—O4C	70.36 (17)	O1W—Na—O5W	89.5 (3)
O11B—Mo5—O4C	82.08 (18)	O6W—Na—O5W	174.4 (3)
O5C—Mo5—O4C	70.60 (15)	O13T—Na—O5W	86.1 (3)
O24T—Mo6—O23T	106.0 (3)	O1W—Na—O2W	85.0 (3)
O24T—Mo6—O11B	97.1 (2)	O6W—Na—O2W	99.4 (4)
O23T—Mo6—O11B	101.9 (2)	O13T—Na—O2W	85.0 (3)
O24T—Mo6—O12B	101.6 (2)	O5W—Na—O2W	79.1 (3)
O23T—Mo6—O12B	97.9 (2)	O1W—Na—O3W	105.6 (3)
O11B—Mo6—O12B	147.71 (19)	O6W—Na—O3W	87.8 (3)
O24T—Mo6—O5C	158.8 (2)	O13T—Na—O3W	84.0 (3)
O23T—Mo6—O5C	93.7 (2)	O5W—Na—O3W	92.7 (3)
O11B—Mo6—O5C	70.77 (17)	O2W—Na—O3W	166.7 (4)

D—H···A	D—H	H···A	D···A	D—H···A
O1C—H1···O10Wiii	0.74 (7)	1.89 (7)	2.620 (7)	174 (8)
O3C—H3···O7W	0.91 (8)	1.66 (8)	2.547 (7)	163 (7)
O4C—H4···O8W	0.79 (7)	1.82 (8)	2.594 (8)	166 (7)
O5C—H5···O9W	0.97 (6)	1.60 (6)	2.551 (8)	165 (7)
O6C—H6···O5Wv	0.83 (8)	1.75 (9)	2.576 (8)	179 (9)
O8B—H8···O11Bix	0.80 (7)	1.85 (7)	2.648 (6)	175 (7)
O1W—H1A···O2Cv	0.81 (8)	2.12 (8)	2.909 (8)	166 (13)
O1W—H1B···O9Bvii	0.79 (8)	2.13 (9)	2.838 (8)	150 (14)
O2W—H2B···O24T	0.80 (8)	2.54 (14)	2.978 (9)	116 (13)
O3W—H3A···O18Tvii	0.88 (8)	2.54 (14)	2.975 (10)	111 (11)
O4W—H4B···O20Tvi	0.85 (10)	2.3 (2)	2.792 (12)	113 (19)
O4W—H4A···O24T	0.82 (10)	2.39 (19)	2.957 (12)	127 (20)
O5W—H5B···O8Wv	0.96	2.08	2.958 (13)	151
O5W—H5A···O15Ti	0.96	2.01	2.687 (8)	126
O6W—H6B···O19Tvii	0.88 (8)	2.09 (9)	2.921 (9)	158 (12)
O6W—H6A···O4W	0.98 (8)	1.90 (10)	2.788 (15)	148 (12)
O7W—H7B···O11W	0.75 (7)	2.03 (7)	2.730 (9)	155 (9)
O7W—H7A···O21Tix	0.96 (7)	1.88 (7)	2.727 (7)	146 (7)
O8W—H8B···O10Wx	0.80 (7)	2.05 (8)	2.840 (8)	167 (12)
O8W—H8A···O17Txi	0.76 (7)	2.27 (10)	2.867 (9)	136 (12)
O9W—H9B···O12Biii	0.73 (8)	2.09 (10)	2.752 (8)	150 (14)
O9W—H9A···O6Wiii	0.75 (8)	2.32 (11)	2.937 (10)	141 (13)
O10W—H10B···O7Wiii	0.90 (7)	1.99 (7)	2.835 (8)	155 (9)
O10W—H10A···O23T	0.85 (7)	2.02 (7)	2.782 (8)	149 (9)
O11W—H11B···O10B	0.77 (8)	2.18 (9)	2.880 (8)	153 (14)
O11W—H11A···O18Txii	0.84 (7)	2.18 (8)	2.983 (8)	159 (12)

Pt—O1C	1.989 (4)
Pt—O2C	1.978 (4)
Pt—O3C	1.993 (4)
Pt—O4C	2.003 (4)
Pt—O5C	2.034 (4)
Pt—O6C	2.001 (4)
Mo1—O1C	2.327 (5)
Mo1—O6C	2.306 (5)
Mo1—O7B	1.954 (5)
Mo1—O12B	1.927 (5)
Mo2—O1C	2.317 (5)
Mo2—O2C	2.154 (4)
Mo2—O7B	1.894 (5)
Mo2—O8B	2.060 (5)
Mo3—O2C	2.163 (4)
Mo3—O3C	2.338 (4)
Mo3—O8B	2.047 (5)
Mo3—O9B	1.889 (5)
Mo4—O3C	2.323 (4)
Mo4—O4C	2.291 (4)
Mo4—O9B	1.979 (5)
Mo4—O10B	1.921 (5)
Mo5—O4C	2.328 (5)
Mo5—O5C	2.290 (5)
Mo5—O10B	1.935 (5)
Mo5—O11B	1.956 (4)
Mo6—O5C	2.302 (4)
Mo6—O6C	2.326 (5)
Mo6—O11B	1.946 (5)
Mo6—O12B	1.949 (5)

Mo2—O1C—Mo1	92.06 (17)
Mo2—O2C—Mo3	103.72 (16)
Mo4—O3C—Mo3	92.16 (16)
Mo4—O4C—Mo5	92.48 (16)
Mo5—O5C—Mo6	94.18 (16)
Mo1—O6C—Mo6	93.33 (17)
Mo2—O7B—Mo1	120.6 (2)
Mo3—O8B—Mo2	111.6 (2)
Mo3—O9B—Mo4	120.5 (2)
Mo4—O10B—Mo5	119.8 (2)
Mo6—O11B—Mo5	119.1 (2)
Mo1—O12B—Mo6	120.7 (2)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1C—H1⋯O10Wi	0.74 (7)	1.89 (7)	2.620 (7)	174 (8)
O3C—H3⋯O7W	0.91 (8)	1.66 (8)	2.547 (7)	163 (7)
O4C—H4⋯O8W	0.79 (7)	1.82 (8)	2.594 (8)	166 (7)
O5C—H5⋯O9W	0.97 (6)	1.60 (6)	2.551 (8)	165 (7)
O6C—H6⋯O5Wii	0.83 (8)	1.75 (9)	2.576 (8)	179 (9)
O8B—H8⋯O11Biii	0.80 (7)	1.85 (7)	2.648 (6)	175 (7)
O1W—H1A⋯O2Cii	0.81 (8)	2.12 (8)	2.909 (8)	166 (13)
O1W—H1B⋯O9Biv	0.79 (8)	2.13 (9)	2.838 (8)	150 (14)
O2W—H2B⋯O24T	0.80 (8)	2.54 (14)	2.978 (9)	116 (13)
O3W—H3A⋯O18Tiv	0.88 (8)	2.54 (14)	2.975 (10)	111 (11)
O4W—H4B⋯O20Tv	0.85 (10)	2.3 (2)	2.792 (12)	113 (19)
O4W—H4A⋯O24T	0.82 (10)	2.39 (19)	2.957 (12)	127 (20)
O5W—H5B⋯O8Wii	0.96	2.08	2.958 (13)	151
O5W—H5A⋯O15Tvi	0.96	2.01	2.687 (8)	126
O6W—H6B⋯O19Tiv	0.88 (8)	2.09 (9)	2.921 (9)	158 (12)
O6W—H6A⋯O4W	0.98 (8)	1.90 (10)	2.788 (15)	148 (12)
O7W—H7B⋯O11W	0.75 (7)	2.03 (7)	2.730 (9)	155 (9)
O7W—H7A⋯O21Tiii	0.96 (7)	1.88 (7)	2.727 (7)	146 (7)
O8W—H8B⋯O10Wvii	0.80 (7)	2.05 (8)	2.840 (8)	167 (12)
O8W—H8A⋯O17Tviii	0.76 (7)	2.27 (10)	2.867 (9)	136 (12)
O9W—H9B⋯O12Bi	0.73 (8)	2.09 (10)	2.752 (8)	150 (14)
O9W—H9A⋯O6Wi	0.75 (8)	2.32 (11)	2.937 (10)	141 (13)
O10W—H10B⋯O7Wi	0.90 (7)	1.99 (7)	2.835 (8)	155 (9)
O10W—H10A⋯O23T	0.85 (7)	2.02 (7)	2.782 (8)	149 (9)
O11W—H11B⋯O10B	0.77 (8)	2.18 (9)	2.880 (8)	153 (14)
O11W—H11A⋯O18Tix	0.84 (7)	2.18 (8)	2.983 (8)	159 (12)

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) ; (viii) ; (ix) .