Literature DB >> 25763935

A CH2Cl2 complex of a [Rh(pincer)](+) cation.

Gemma M Adams1, F Mark Chadwick, Sebastian D Pike, Andrew S Weller.   

Abstract

The CH2Cl2 complex [Rh((tBu)PONOP)(κ(1)-ClCH2Cl)][BAr(F)4] is reported, that also acts as a useful synthon for other complexes such as N2, CO and H2 adducts; while the analogous PNP complex undergoes C-Cl activation.

Entities:  

Year:  2015        PMID： 25763935     DOI： 10.1039/c5dt00481k

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen.

Authors:  Matthew R Gyton; Baptiste Leforestier; Adrian B Chaplin
Journal:  Organometallics       Date:  2018-10-09       Impact factor: 3.876

2.  A convenient method for the generation of {Rh(PNP)}+ and {Rh(PONOP)}+ fragments: reversible formation of vinylidene derivatives.

Authors:  Matthew R Gyton; Thomas M Hood; Adrian B Chaplin
Journal:  Dalton Trans       Date:  2019-02-26       Impact factor: 4.390

3.  Rhodium(I) Pincer Complexes of Nitrous Oxide.

Authors:  Matthew R Gyton; Baptiste Leforestier; Adrian B Chaplin
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-12       Impact factor: 15.336

4.  C-Cl Oxidative Addition and C-C Reductive Elimination Reactions in the Context of the Rhodium-Promoted Direct Arylation.

Authors:  Laura A de Las Heras; Miguel A Esteruelas; Montserrat Oliván; Enrique Oñate
Journal:  Organometallics       Date:  2022-03-17       Impact factor: 3.876
  4 in total

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