Literature DB >> 25757538

Tackling poison and leach: catalysis by dangling thiol-palladium functions within a porous metal-organic solid.

Bo Gui1, Ka-Kit Yee, Yan-Lung Wong, Shek-Man Yiu, Matthias Zeller, Cheng Wang, Zhengta Xu.   

Abstract

Self-standing thiol (-SH) groups within a Zr(IV)-based metal-organic framework (MOF) anchor Pd(II) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(II) center, while the strong Pd-S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed.

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Year:  2015        PMID： 25757538     DOI： 10.1039/c5cc00140d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework.

Authors:  Yonghe He; Jiahong Huang; Jun He; Zhengtao Xu
Journal:  J Vis Exp       Date:  2018-04-09       Impact factor: 1.355

2.  A palladium complex confined in a thiadiazole-functionalized porous conjugated polymer for the Suzuki-Miyaura coupling reaction.

Authors:  Yingjie Qian; Sang Yung Jeong; Sung-Hyeon Baeck; Myung-Jong Jin; Sang Eun Shim
Journal:  RSC Adv       Date:  2019-10-18       Impact factor: 4.036

3.  Porous aromatic framework with mesopores as a platform for a super-efficient heterogeneous Pd-based organometallic catalysis.

Authors:  Li-Ping Jing; Jin-Shi Sun; Fuxing Sun; Peng Chen; Guangshan Zhu
Journal:  Chem Sci       Date:  2018-03-02       Impact factor: 9.825

4.  Phenanthroline-based microporous organic polymer as a platform for an immobilized palladium catalyst for organic transformations.

Authors:  Chang-An Wang; Kun Nie; Guo-Dong Song; Yan-Wei Li; Yin-Feng Han
Journal:  RSC Adv       Date:  2019-03-13       Impact factor: 3.361

5.  Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes.

Authors:  Jie Luo; Yaoyu Liang; Michael Montag; Yael Diskin-Posner; Liat Avram; David Milstein
Journal:  J Am Chem Soc       Date:  2022-07-15       Impact factor: 16.383

6.  Organic radicals stabilization above 300 °C in Eu-based coordination polymers for solar steam generation.

Authors:  Xinhe Ye; Lai-Hon Chung; Kedi Li; Saili Zheng; Yan-Lung Wong; Zihao Feng; Yonghe He; Dandan Chu; Zhengtao Xu; Lin Yu; Jun He
Journal:  Nat Commun       Date:  2022-10-17       Impact factor: 17.694

7.  Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF.

Authors:  Alexios Grigoropoulos; George F S Whitehead; Noémie Perret; Alexandros P Katsoulidis; F Mark Chadwick; Robert P Davies; Anthony Haynes; Lee Brammer; Andrew S Weller; Jianliang Xiao; Matthew J Rosseinsky
Journal:  Chem Sci       Date:  2015-12-08       Impact factor: 9.825
  7 in total

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