Literature DB >> 25683559

The nucleoside uridine isolated in the gas phase.

Isabel Peña1, Carlos Cabezas, José L Alonso.   

Abstract

Herein we present the first experimental observation of the isolated nucleoside uridine, placed in the gas phase by laser ablation and characterized by Fourier transform (FT) microwave techniques. Free from the bulk effects of their native environments, anti/C2'-endo-g+ conformation has been revealed as the most stable form of uridine. Intramolecular hydrogen bonds involving uracil and ribose moieties have been found to play an important role in the stabilization of the nucleoside.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  conformational analysis; hydrogen bonds; laser ablation; microwave spectroscopy; nucleosides

Mesh：

Substances：

Year:  2015        PMID： 25683559      PMCID： PMC4892345          DOI： 10.1002/anie.201412460

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

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  7 in total

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