| Literature DB >> 25675511 |
Eva Arianna Aurelia Pogna1, Cristian Rodríguez-Tinoco2, Giulio Cerullo3, Carino Ferrante1, Javier Rodríguez-Viejo4, Tullio Scopigno5.
Abstract
Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down, rendering its experimental investigation impractically long, to the extent that a timescale divergence is taken for granted by many. We circumvent these limitations here, taking advantage of a wide family of glasses rapidly obtained by physical vapor deposition directly into the solid state, endowed with different "ages" rivaling those reached by standard cooling and waiting for millennia. Isothermally probing the mechanical response of each of these glasses, we infer a correspondence with viscosity along the equilibrium line, up to exapoise values. We find a dependence of the elastic modulus on the glass age, which, traced back to the temperature steepness index of the viscosity, tears down one of the cornerstones of several glass transition theories: the dynamical divergence. Critically, our results suggest that the conventional wisdom picture of a glass ceasing to flow at finite temperature could be wrong.Entities:
Keywords: aging; glass transition; inelastic scattering; supercooled liquid; vibrational properties
Year: 2015 PMID: 25675511 PMCID: PMC4345587 DOI: 10.1073/pnas.1423435112
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205