Literature DB >> 25675511

Probing equilibrium glass flow up to exapoise viscosities.

Eva Arianna Aurelia Pogna1, Cristian Rodríguez-Tinoco2, Giulio Cerullo3, Carino Ferrante1, Javier Rodríguez-Viejo4, Tullio Scopigno5.   

Abstract

Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down, rendering its experimental investigation impractically long, to the extent that a timescale divergence is taken for granted by many. We circumvent these limitations here, taking advantage of a wide family of glasses rapidly obtained by physical vapor deposition directly into the solid state, endowed with different "ages" rivaling those reached by standard cooling and waiting for millennia. Isothermally probing the mechanical response of each of these glasses, we infer a correspondence with viscosity along the equilibrium line, up to exapoise values. We find a dependence of the elastic modulus on the glass age, which, traced back to the temperature steepness index of the viscosity, tears down one of the cornerstones of several glass transition theories: the dynamical divergence. Critically, our results suggest that the conventional wisdom picture of a glass ceasing to flow at finite temperature could be wrong.

Entities:  

Keywords:  aging; glass transition; inelastic scattering; supercooled liquid; vibrational properties

Year:  2015        PMID: 25675511      PMCID: PMC4345587          DOI: 10.1073/pnas.1423435112

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  34 in total

1.  The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids.

Authors:  S Sastry
Journal:  Nature       Date:  2001-01-11       Impact factor: 49.962

2.  Is the fragility of a liquid embedded in the properties of its glass?

Authors:  Tullio Scopigno; Giancarlo Ruocco; Francesco Sette; Giulio Monaco
Journal:  Science       Date:  2003-10-31       Impact factor: 47.728

3.  Does the interaction potential determine both the fragility of a liquid and the vibrational properties of its glassy state?

Authors:  Patrice Bordat; Frédéric Affouard; Marc Descamps; K L Ngai
Journal:  Phys Rev Lett       Date:  2004-09-02       Impact factor: 9.161

4.  Organic glasses with exceptional thermodynamic and kinetic stability.

Authors:  Stephen F Swallen; Kenneth L Kearns; Marie K Mapes; Yong Seol Kim; Robert J McMahon; M D Ediger; Tian Wu; Lian Yu; Sushil Satija
Journal:  Science       Date:  2006-12-07       Impact factor: 47.728

Review 5.  Theory of structural glasses and supercooled liquids.

Authors:  Vassiliy Lubchenko; Peter G Wolynes
Journal:  Annu Rev Phys Chem       Date:  2007       Impact factor: 12.703

6.  Dynamics of the amorphous and crystalline alpha-, gamma-phases of indomethacin.

Authors:  L Carpentier; R Decressain; S Desprez; M Descamps
Journal:  J Phys Chem B       Date:  2006-01-12       Impact factor: 2.991

7.  Glassy properties and viscous slowing down: An analysis of the correlation between nonergodicity factor and fragility.

Authors:  Kristine Niss; Cécile Dalle-Ferrier; Valentina M Giordano; Giulio Monaco; Bernhard Frick; Christiane Alba-Simionesco
Journal:  J Chem Phys       Date:  2008-11-21       Impact factor: 3.488

8.  In situ nanocalorimetry of thin glassy organic films.

Authors:  E León-Gutierrez; G Garcia; A F Lopeandía; J Fraxedas; M T Clavaguera-Mora; J Rodríguez-Viejo
Journal:  J Chem Phys       Date:  2008-11-14       Impact factor: 3.488

9.  Formation of glasses from liquids and biopolymers.

Authors:  C A Angell
Journal:  Science       Date:  1995-03-31       Impact factor: 47.728

10.  Hiking down the energy landscape: progress toward the Kauzmann temperature via vapor deposition.

Authors:  Kenneth L Kearns; Stephen F Swallen; M D Ediger; Tian Wu; Ye Sun; Lian Yu
Journal:  J Phys Chem B       Date:  2008-04-03       Impact factor: 2.991

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  2 in total

1.  Relaxation dynamics of glasses along a wide stability and temperature range.

Authors:  C Rodríguez-Tinoco; J Ràfols-Ribé; M González-Silveira; J Rodríguez-Viejo
Journal:  Sci Rep       Date:  2016-10-21       Impact factor: 4.379

2.  Ultrastable glasses portray similar behaviour to ordinary glasses at high pressure.

Authors:  C Rodríguez-Tinoco; M González-Silveira; M Barrio; P Lloveras; J Ll Tamarit; J-L Garden; J Rodríguez-Viejo
Journal:  Sci Rep       Date:  2016-10-03       Impact factor: 4.379

  2 in total

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