| Literature DB >> 25615322 |
Seung Kyu Min1, Ali Abedi2, Kwang S Kim3, E K U Gross2.
Abstract
We demonstrate that the molecular Berry phase and the corresponding nonanalyticity in the electronic Born-Oppenheimer wave function is, in general, not a true topological feature of the exact solution of the full electron-nuclear Schrödinger equation. For a numerically exactly solvable model we show that a nonanalyticity, and the associated geometric phase, only appear in the limit of infinite nuclear mass, while a perfectly smooth behavior is found for any finite nuclear mass.Year: 2014 PMID: 25615322 DOI: 10.1103/PhysRevLett.113.263004
Source DB: PubMed Journal: Phys Rev Lett ISSN: 0031-9007 Impact factor: 9.161