Literature DB >> 25610922

Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes.

Vasudevan Dhayalan1, Christoph Sämann, Paul Knochel.   

Abstract

Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.

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Year:  2015        PMID： 25610922     DOI： 10.1039/c4cc08846h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  PEt3-Mediated Deoxygenative C-N Coupling of Nitroarenes and Boronic Acids.

Authors:  Trevor V Nykaza; Junyu Yang; Alexander T Radosevich
Journal:  Tetrahedron       Date:  2019-03-25       Impact factor: 2.457

2.  P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C-N Coupling with Nitromethane as a Methylamine Surrogate.

Authors:  Gen Li; Ziyang Qin; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2020-09-11       Impact factor: 15.419

3.  Aryl amination using ligand-free Ni(II) salts and photoredox catalysis.

Authors:  Emily B Corcoran; Michael T Pirnot; Shishi Lin; Spencer D Dreher; Daniel A DiRocco; Ian W Davies; Stephen L Buchwald; David W C MacMillan
Journal:  Science       Date:  2016-06-23       Impact factor: 47.728

4.  Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis.

Authors:  Trevor V Nykaza; Julian C Cooper; Gen Li; Nolwenn Mahieu; Antonio Ramirez; Michael R Luzung; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2018-11-02       Impact factor: 15.419

5.  PIII /PV =O Catalyzed Cascade Synthesis of N-Functionalized Azaheterocycles.

Authors:  Trevor V Nykaza; Gen Li; Junyu Yang; Michael R Luzung; Alexander T Radosevich
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-29       Impact factor: 15.336

6.  Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles.

Authors:  Kento Taniguchi; Xiongjie Jin; Kazuya Yamaguchi; Kyoko Nozaki; Noritaka Mizuno
Journal:  Chem Sci       Date:  2016-12-01       Impact factor: 9.825

7.  Synthesis of Mono-N-Methyl Aromatic Amines from Nitroso Compounds and Methylboronic Acid.

Authors:  Silvia Roscales; Aurelio G Csákÿ
Journal:  ACS Omega       Date:  2019-08-12

8.  An Improved PIII/PV═O-Catalyzed Reductive C-N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps.

Authors:  Gen Li; Trevor V Nykaza; Julian C Cooper; Antonio Ramirez; Michael R Luzung; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2020-03-25       Impact factor: 15.419
  8 in total

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