Literature DB >> 25595095

High production of small organic dicarboxylate dianions by DESI and ESI.

Yonghui Dong1, Graziano Guella, Fulvio Mattivi, Pietro Franceschi.   

Abstract

A significant production of gas-phase dicarboxylate dianions has been observed in standard ESI and DESI during the analysis of small organic dicarboxylic acids under moderate or highly alkaline conditions. In ESI, this can be attributed to an excess of hydroxyl ions (OH(-)) which favor the formation of an high amount of dianions in solution, contemporarily trapping the potential counter ions during the ESI process. The results obtained in DESI highlight the role of the surface in trapping the counter-ions during desorption process and determining the ultimate nature of the observed gas-phase ions.

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Year:  2015        PMID： 25595095     DOI： 10.1007/s13361-014-1065-y

Source DB:  PubMed          Journal:  J Am Soc Mass Spectrom        ISSN： 1044-0305            Impact factor:   3.109


  6 in total

1.  Solvent-mediated folding of a doubly charged anion.

Authors:  Xin Yang; You-Jun Fu; Xue-Bin Wang; Petr Slavícek; Martin Mucha; Pavel Jungwirth; Lai-Sheng Wang
Journal:  J Am Chem Soc       Date:  2004-01-28       Impact factor: 15.419

Review 2.  Ambient mass spectrometry using desorption electrospray ionization (DESI): instrumentation, mechanisms and applications in forensics, chemistry, and biology.

Authors:  Zoltán Takáts; Justin M Wiseman; R Graham Cooks
Journal:  J Mass Spectrom       Date:  2005-10       Impact factor: 1.982

3.  Simulation of atmospheric transport and droplet-thin film collisions in desorption electrospray ionization.

Authors:  Anthony B Costa; R Graham Cooks
Journal:  Chem Commun (Camb)       Date:  2007-08-13       Impact factor: 6.222

4.  Internal energy distributions in desorption electrospray ionization (DESI).

Authors:  Marcela Nefliu; Jonell N Smith; Andre Venter; R Graham Cooks
Journal:  J Am Soc Mass Spectrom       Date:  2007-12-04       Impact factor: 3.109

5.  Effects of solvent and counterion on ion pairing and observed charge states of diquaternary ammonium salts in electrospray ionization mass spectrometry.

Authors:  G Wang; R B Colecor
Journal:  J Am Soc Mass Spectrom       Date:  1996-10       Impact factor: 3.109

6.  Stability of gas-phase tartaric acid anions investigated by quantum chemistry, mass spectrometry, and infrared spectroscopy.

Authors:  Ralf Tonner; Peter Schwerdtfeger; Amanda L May; Jeffrey D Steill; Giel Berden; Jos Oomens; Shawn R Campagna; Robert N Compton
Journal:  J Phys Chem A       Date:  2012-05-02       Impact factor: 2.781
  6 in total
  2 in total

1.  Gas-Phase Stability of Negatively Charged Organophosphate Metabolites Produced by Electrospray Ionization and Matrix-Assisted Laser Desorption/Ionization.

Authors:  Daiki Asakawa; Hajime Mizuno; Toshimasa Toyo'oka
Journal:  J Am Soc Mass Spectrom       Date:  2017-09-05       Impact factor: 3.109

Review 2.  Sample Preparation for Mass Spectrometry Imaging of Plant Tissues: A Review.

Authors:  Yonghui Dong; Bin Li; Sergey Malitsky; Ilana Rogachev; Asaph Aharoni; Filip Kaftan; Aleš Svatoš; Pietro Franceschi
Journal:  Front Plant Sci       Date:  2016-02-10       Impact factor: 5.753
  2 in total

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