Literature DB >> 25406546

Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.

Chao Feng1, Daming Feng, Teck-Peng Loh.   

Abstract

Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

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Year:  2014        PMID： 25406546     DOI： 10.1039/c4cc07597h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  J Org Chem       Date:  2018-09-21       Impact factor: 4.354

2.  An efficient method for the preparation of styrene derivatives via Rh(III)-catalyzed direct C-H vinylation.

Authors:  Kate D Otley; Jonathan A Ellman
Journal:  Org Lett       Date:  2015-02-25       Impact factor: 6.005

3.  Ruthenium(II)-Catalyzed Regio- and Stereoselective C-H Allylation of Indoles with Allyl Alcohols.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  Org Lett       Date:  2018-03-27       Impact factor: 6.005

4.  Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate.

Authors:  Liyuan Ding; Chunbing Yu; Zhenqiang Zhao; Feifei Li; Jian Zhang; Guofu Zhong
Journal:  J Vis Exp       Date:  2017-06-21       Impact factor: 1.355

5.  Carboxylate-directed C-H allylation with allyl alcohols or ethers.

Authors:  Xiao-Qiang Hu; Zhiyong Hu; A Stefania Trita; Guodong Zhang; Lukas J Gooßen
Journal:  Chem Sci       Date:  2018-05-21       Impact factor: 9.825
  5 in total

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