| Literature DB >> 25370105 |
Xiang Li1, Zhi-Gang Wang1, Hou-He Chen2, Sheng-Gao Liu1.
Abstract
The title compound, C18H28O3, was prepared by the reaction of 2,6-di-tert-butylphenol with methyl acrylate under basic conditions using dimethyl sulfoxide as the promoter. The structure of this antioxidant indicates significant strain between the ortho tert-butyl substituents and the phenolic OH group. In spite of the steric crowding of the OH group, it participates in intermolecular hydrogen bonding with the ester carbonyl O atom.Entities:
Keywords: antioxidant; crystal structure; hindered phenol; hydrogen bonding
Year: 2014 PMID: 25370105 DOI: 10.1107/S2053229614021445
Source DB: PubMed Journal: Acta Crystallogr C Struct Chem ISSN: 2053-2296 Impact factor: 1.172